BARBAN N(3-氯苯基)氨基甲酸(4-氯丁炔-2-基)脂

CAS 101-27-9 MFCD00045297

化学结构图

101-27-9
SMILES: O=C(Nc1cccc(Cl)c1)OCC#CCCl

化学属性

Mol. FormulaC11H9Cl2NO2
Mol. Weight258
Solubility微溶于水、己烷，溶于苯、二氯乙烷。
Density1.394
Melting Point75-76°C

别名和识别编码

Chemical NameBarban
CAS Number101-27-9
PubChem Substance ID7551
EC Number202-930-4
Beilstein Registry Number2376181
MDL NumberMFCD00045297
Synonym (3-Chlorophenyl)carbamic acid 4-chloro-2-butynyl ester {uni_hamburg} {Chemicalbook} 4-Chloro-2-butynylm-chlorocarbanilate {Chem 4-chlorobut-2-ynyl 3-chlorophenylcarbamate BARBAN 4-Chloro-2-butynyl m-chlorocarbanilate 氯苯胺基甲酸-4-氯-2-丁炔基酯 2-Butynyl 4-chloro-m-chlorocarbanilate carbanilic acid, m-chloro-, 4-chloro-2-butynyl ester 4-[N-(3-Chlorophenyl)carbamoyloxy]-1-chloro-2-butyne 3-CHLOROCARBANILIC ACID 4-CHLORO-2-BUTYNYL ESTER S847 A 980 Karbin {Chemi carbyne carbamic acid, (3-chlorophenyl)-, 4-chloro-2-butynyl ester 4-Chloro-2-butynyl (3-chlorophenyl)carbamate A-980 2-Butynyl 4-ch m-Chlorocarbanilic acid, 4- 4-Chloro-2-butynyl 3-chlorocarbanilate C-847 {uni_hambur 4-CHLOROBUT-2-YNYL-3-CHLOROPHENYLCARBAMATE chlorinat 4-Chlorobut-2-ynyl-m-chlorocarbanilate (4-Cloro-but-2-in-il)-N-(3- ENT 28201 Car Barbane {uni_hamburg 2-Butynyl-4-chloro-m-chlorocarbanilate 4-氯丁炔-2-基-3′-氯苯氨基甲酸酯 氯炔草灵 Carbyne (4-Chlorbut-2-inyl)-3-chlorphenylcarbamat 4-chlorbut-2-ynyl N-(3-chlorophenyl)carbamate {uni 4-Chloro-2-butyn-1-yl N-(3-chlorophenyl)carbamate BARBANATE 燕麦灵 4-Chlorobut-2-ynyl 3-chlorocarbanilate (4-Chloor-but-2-yn-yl)-N-(3-chloor-fenyl)-carbamaat N-(3-Chloro phenyl) carbamate de 4-chloro 2-butynyle Carbamic acid, (3-chlorophenyl)-, 4-chloro-2-butynyl ester 2-Butyn-1-ol, 4-chloro-, m-chlorocarbanilate {Chemicalbook 4
Chemical Name TranslationN(3-氯苯基)氨基甲酸(4-氯丁炔-2-基)脂
Merck Number13,962
Wiswesser Line NotationG2UU2OVMR CG
InChIInChI=1S/C11H9Cl2NO2/c12-6-1-2-7-16-11(15)14-10-5-3-4-9(13)8-10/h3-5,8H,6-7H2,(H,14,15)
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分类

  • Alphabetic, Analytical Standards, Analytical/Chromatography, B, BA - BH, Carbanilate, Chromatography, Environmental Standards, Herbicides, Pesticides & Metabolites
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; carbamate; 1fragment

产品应用

  • 用作除草剂，主要用于芽后防除野燕麦

相关文献及参考

  • Merck:13,962
  • Short: EINECS
  • Short: IV/8A

安全信息

GHS Symbol
WGK Germany3
Hazard Codes Xn,N
Hazard statements
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H302 Harmful if swallowed 吞食有害
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
RTECSFD7700000
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
Signal word Warning
Safety Statements
  • S24 Avoid contact with skin 避免皮肤接触；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Storage condition 0-6°C
Risk Statements
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R22 Harmful if swallowed 吞咽有害
  • R50/53
UN Number UN3077 9/PG 3
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 240 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PAREAQ Pharmacological Reviews.  (Williams & Wilkins, 428 E. Preston St.,
   Baltimore, MD 21202) V.1-    1949-  Volume(issue)/page/year: 14,225,1962

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOS

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >1600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   WRPCA2 World Review of Pest Control.  (London, UK)  V.1-10, 1962-71.
   Discontinued.  Volume(issue)/page/year: 9,119,1970

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PAREAQ Pharmacological Reviews.  (Williams & Wilkins, 428 E. Preston St.,
   Baltimore, MD 21202) V.1-    1949-  Volume(issue)/page/year: 14,225,1962

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 527 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,35,1982

TYPE

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Bacillus subtilis
DOSE/DURATION           : 20 ug/disc
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 40,19,1976

其他信息

  • RTECS号:FD7700000
  • 外观性质:纯品为白色结晶，原药为棕色固体。
  • 生产方法:以丁炔二醇、间氯苯胺、光气、氯化亚砜为原料精酯化、缩合，氯化、反应而得。
  • MOL 文件:101-27-9.mol
  • 用途:用作除草剂，主要用于芽后防除野燕麦。
  • 易溶于苯、甲苯、二甲苯、二氯乙烯，溶于正己烷，不溶于水。能被碱分解，在酸性条件下水解生成3-氯丙烯酸，高于熔点分解出盐酸。

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. B - Alphabetic
  5. BA - BH - B

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