Tetrasulfanediylbis(piperidin-1-ylmethanethione) 1,1’-(四硫代二碳硫基)双哌啶

CAS 120-54-7 MFCD00047474

化学结构图

120-54-7
SMILES: S=C(SSSSC(=S)N1CCCCC1)N1CCCCC1

化学属性

Mol. FormulaC12H20N2S6
Mol. Weight385
Appearance 四硫化双五亚甲基秋兰姆(120-54-7)为白色或灰黄色粉末。熔点115℃，相对密度1.50。溶于二硫化碳、氯仿和四氯化碳，不溶于水。
Melting Point118.0 to 122.0 deg-C

别名和识别编码

Chemical NameTetrasulfanediylbis(piperidin-1-ylmethanethione)
MDL NumberMFCD00047474
CAS Number120-54-7
Reaxys-RN298051
PubChem Substance ID87566977
EC Number204-406-0
Synonym 1,1'-(Tetrathiodicarbonothioyl)-bis-piperidine 1,1'-(tetrathiodicarbonothioyl)-bis-piperidine 1,1’-(tetrathiodicarbonothioyl)bis-piperidin 1,1’-(四硫代二碳硫基)双哌啶 Accelerator DPTT Accelerator(tra) BIS(PENTAMETHYLENETHIOCARBAMOYL) TETRASULFIDE BIS(PIPERIDINOTHIOCARBONYL) TETRASULFIDE Bis(pentamethylene)thiuram tetrasulfide Bis(pentamethylenethiuram)-tetrasulfide Bis(piperidinothiocarbonyl) tetrasulfide DIPENTAMETHYLENETHIURAM TETRASULFIDE DPTT Dipentamethylenethiram Tetrasulfide Dipentamethylenethiuram tetrasulfide Nocceler TRA Soxinol TRA Sulfads Tetrasulfide, bis(pentamethylenethiuram)- Tetron A Tetrone A Thiuram MT Thiuram tetrasulfide, bis(piperidinothiocarbonyl) USAF B-31 bis(pentamethylenethiuram)-tetrasulfid noccelertra sancelertra soxinoltra tetrasulfide,bis(piperidinothiocarbonyl) tetrona tetronea thiurammt thiuramtetrasulfide,bis(piperidinothiocarbonyl) usafb-31 二哌啶基秋兰姆-硫化物 促进剂 TRA 促进剂DPTT 促进剂TRA 四硫化双五亚甲基秋兰姆 四硫化双五亚甲基秋蓝姆 四硫化双五甲亚基秋兰姆 四硫化双五甲撑秋兰姆 四硫化双硫羰基五亚甲胺 四硫化雙(五亞甲硫醯胺基) 四硫化雙(五亞甲胺硫醯基) 四硫化雙五亞甲硫醯胺基 橡胶促进剂 DPTT 母胶粒DPTT-70 母胶粒TRA-70 药胶DPTT-7O 药胶TRA-7O 预分散TRA-70
Chemical Name Translation1,1’-(四硫代二碳硫基)双哌啶
Wiswesser Line NotationT6NTJ AYUS&SS 2
Beilstein Registry Number0298051
LabNetwork Molecule IDLN00201703
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分类

  • {SA} Building Blocks, C12, Chemical Synthesis, Heterocyclic Building Blocks, New Products for Chemical Synthesis, Piperidines
  • {SNA} Building Blocks, C12, Chemical Synthesis, Heterocyclic Building Blocks, Piperidines

安全信息

RTECSTN4221000
Signal word
Hazard statements
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P302+P352+P333+P313+P362+P364
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P333+P313
  • P302+P350
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R51/53
GHS Symbol 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

WGK Germany2
Hazard Codes N

其他信息

  • 用途一:用作天然、丁苯、丁腈、丁基、氯丁、异戊二烯、氯磺化聚乙烯等橡胶的促进剂
  • MOL 文件:120-54-7.mol
  • 方法一:由六氢吡啶、碳酸钠和二硫化碳反应制得五亚甲基二硫代氨基甲酸钠，再用一氯化硫处理即得四硫化双五亚甲基秋蓝姆。
  • 图谱信息:四硫化双五亚甲基秋兰姆(120-54-7)核磁图( 13 CNMR) 四硫化双五亚甲基秋兰姆(120-54-7)红外图谱(IR1) 四硫化双五亚甲基秋兰姆(120-54-7)红外图谱(IR2) 四硫化双五亚甲基秋兰姆(120-54-7)质谱(MS)
  • 上游原料:过氧化氢 --> 二硫化碳 --> 六氢吡啶 --> 二氯化二硫 --> 甲基二硫代氨基甲酸钠
  • 用途二:本品为秋蓝姆类硫化促进剂，可用于天然橡胶、二烯类合成橡胶、丁基橡胶、三元乙丙橡胶、氯磺化聚乙烯和胶乳。加热能分解出游离硫，亦可作为硫化剂，有效含硫量为其重量的25%。本品作硫化剂时在操作温度下比较安全，硫化胶耐热、耐老化性能优良。本品易分散于干橡胶中，亦易分散于水中。不污染。一般用于制造耐热制品、电缆等。
  • 四硫化双五亚甲基秋兰姆价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0279 四硫化二五亚甲基秋兰姆(俗称)[硫化加速剂] Dipentamethylenethiuram Tetrasulfide (so called) [Vulcanization Accelerator] 500G 1830元 2014/06/02 D0279 四硫化二五亚甲基秋兰姆(俗称)[硫化加速剂] Dipentamethylenethiuram Tetrasulfide (so called) [Vulcanization Accelerator] 25G 218元
  • TCI Shanghai:二哌啶基秋兰姆-硫化物(俗称)[硫化加速剂] Dipentamethylenethiuram Tetrasulfide (so called) [Vulcanization Accelerator](120-54-7)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Piperidines 哌啶
  5. C12 - Piperidines
  1. Functional Group 官能团索引
  2. disulfide
  1. Functional Group 官能团索引
  2. thiocarbamic acid

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