Cupric Citrate 柠檬酸铜
CAS 866-82-0 MFCD00050820
化学结构图
SMILES: O=C([O-])CC(O)(CC(=O)[O-])C(=O)[O-].O=C([O-])CC(O)(CC(=O)[O-])C(=O)[O-].[Cu+2].[Cu+2].[Cu+2]
化学属性
| Mol. Formula | C12H10Cu3O14 |
|---|---|
| Mol. Weight | 568.84 |
| Appearance | 蓝绿色粉末。 微溶于水、冷的柠檬酸钠溶液，溶于氨水、酸和热的硫酸铜溶液与适量柠檬酸钠溶液作用而得。 |
| Melting Point | 239-244 °C |
别名和识别编码
| Chemical Name | Cupric Citrate |
|---|---|
| CAS Number | 866-82-0 |
| Synonym | Copper citrate {LY} Copper citrate {} {LY} Copper citrate {} {} {LY} Copper citrate {} {} {} {LY} Copper citrate {} {} {} {} {LY} Copper citrate {} {} {} {} {} {LY} Copper citrate {} {} {} {} {} {} {LY} Copper citrate {} {} {} {} {} {} {} {LY} Copper citrate {} {} {} {} {} {} {} {} {LY} Copper citrate {} {} {} {} {} {} {} {} {} {LY} Copper citrate {} {} {} {} {} {} {} {} {} {} {LY} Copper citrate {} {} {} {} {} {} {} {} {} {} {} {LY} Copper citrate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Copper citrate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Copper citrate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Copper citrate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Copper citrate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Copper citrate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { |
| EC Number | 212-752-9 |
| MDL Number | MFCD00050820 |
| Chemical Name Translation | 柠檬酸铜 |
| Wiswesser Line Notation | OV1XO&VO&1VO &-CU- 2 |
| PubChem Substance ID | 120942 |
| InChI | InChI=1S/C6H8O7.2Cu/c7-3(8)1-6(13,5(11)12)2-4(9)10;;/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12);;/q;2*+2 |
| Canonical SMILES | OC(C([O-])=O)(CC([O-])=O)CC([O-])=O.OC(C([O-])=O)(CC([O-])=O)CC([O-])=O.[Cu+2].[Cu+2].[Cu+2] |
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安全信息
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 1580 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : MarJV# Personal Communication from J.V. Marhold, VUOS, 539-18, Pardubice, Czechoslavakia, Mar. 29, 1977 Volume(issue)/page/year: 29MAR1977
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - hamster DOSE : 1800 ug/kg SEX/DURATION : female 8 day(s) after conception TOXIC EFFECTS : Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants) Reproductive - Specific Developmental Abnormalities - musculoskeletal system REFERENCE : BIREBV Biology of Reproduction. (Soc. for the Study of Reproduction, 309 W. Clark St., Champaign, IL 61820) V.1- 1969- Volume(issue)/page/year: 11,97,1974
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - hamster DOSE : 2700 ug/kg SEX/DURATION : female 8 day(s) after conception TOXIC EFFECTS : Reproductive - Specific Developmental Abnormalities - cardiovascular (circulatory) system Reproductive - Specific Developmental Abnormalities - homeostasis REFERENCE : TJADAB Teratology, The International Journal of Abnormal Development. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.1- 1968- Volume(issue)/page/year: 21,89,1980
其他信息
- MOL 文件:866-82-0.mol
- 中毒症状:误食引起急性中毒，表现为头痛、头晕、乏力、口腔粘膜呈蓝色，口内有金属味，齿龈，舌发青，腹泻，腹绞痛，黑大便，重者昏迷、痉挛，血压下降等。
- 储运特性:库房低温, 通风, 干燥
- 类别:农药
- 毒性分级:中毒
- 图谱信息:枸橼酸铜(866-82-0)红外图谱(IR1) 枸橼酸铜(866-82-0)红外图谱(IR2)
- 急救治疗:经口中毒，立即催吐、洗胃。解毒剂为依地酸二钠钙，并配合对症治疗。
- 急性毒性:口服- 大鼠 LD50: 1580 毫克/ 公斤
- 灭火剂:水, 二氧化碳, 干粉, 砂土
- 注意事项:在我国未登记。
- 可燃性危险特性:不可燃烧; 火场产生有毒含铜化物烟雾;
- 用途二:用作分析试剂及防腐剂
- 用途一:用作防腐剂、杀虫剂、收敛剂等
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