S-Ethyl dipropylthiocarbamate 苯基硫代氨基甲酸乙酯/丙草丹

CAS 759-94-4 MFCD00053780

化学结构图

759-94-4
SMILES: CCCN(CCC)C(=O)SCC

化学属性

Mol. FormulaC9H19NOS
Mol. Weight189.32
Boiling Point127 °C at 20 mmHg
Density0.7915
Solubility0.375 G/100 ML
Flash Point116°C
Melting Point25 °C

别名和识别编码

Chemical NameEPTC
Synonym S-Ethyl dipropylthiocarbamate {LY} S-Ethyl dipropylthiocarbamate S-ethyl dipropylthiocarbamate {} {LY} S-Ethyl dipropylthiocarbamate {} {} {LY} S-Ethyl dipropylthiocarbamate {} {} {} {LY} S-Ethyl dipropylthiocarbamate {} {} {} {} {LY} S-Ethyl dipropylthiocarbamate {} {} {} {} {} {LY} S-Ethyl dipropylthiocarbamate {} {} {} {} {} {} {LY} S-Ethyl dipropylthiocarbamate {} {} {} {} {} {} {} {LY} S-Ethyl dipropylthiocarbamate {} {} {} {} {} {} {} {} {LY} S-Ethyl dipropylthiocarbamate {} {} {} {} {} {} {} {} {} {LY} S-Ethyl dipropylthiocarbamate {} {} {} {} {} {} {} {} {} {} {LY} S-Ethyl dipropylthiocarbamate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} S-Ethyl dipropylthiocarbamate {} {} {} {} {} {} {} {} {} {} {} {} {LY} S-Ethyl dipropylthiocarbamate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} S-Ethyl dipropylthiocarbamate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} S-Ethyl dipropylthiocar
MDL NumberMFCD00053780
PubChem Substance ID12968
Beilstein Registry Number1762751
CAS Number759-94-4
EC Number212-073-8
Chemical Name Translation苯基硫代氨基甲酸乙酯/丙草丹
Merck Number13,3669
Wiswesser Line Notation3N3&VS2
InChIInChI=1S/C9H19NOS/c1-4-7-10(8-5-2)9(11)12-6-3/h4-8H2,1-3H3
Canonical SMILESCCSC(N(CCC)CCC)=O
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分类

  • {SNA} Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Bioactive Small Molecules, Cell Biology, Chromatography, E, E-G, EP, Environmental Standards, Herbicides, Pesticides & Metabolites, Thiocarbamates
  • {SNA} All alphabetically sorted, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Bioactive Small Molecules, Chromatography, E, E-G, EP, Environmental Standards, Herbicides, Pesticides & Metabolites,

相关文献及参考

  • Merck: 14,3640

安全信息

RTECSFA4550000
GHS Symbol
WGK Germany1
Hazard statements
  • H302 Harmful if swallowed 吞食有害
Hazard Codes Xn
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Signal word Warning
Safety Statements
  • S2 Keep out of the reach of children 避免儿童触及；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
Storage condition 0-6°C 室温储存
UN Number 2902 
TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Human
DOSE/DURATION           : 135 mg/m3/90M
TOXIC EFFECTS :
   Behavioral - headache
   Behavioral - withdrawal
   Gastrointestinal - nausea or vomiting
REFERENCE :
   HYSAAV Hygiene and Sanitation (USSR).  English translation of GISAAA.
   (Springfield, VA)  1964-71. Discontinued.  Volume(issue)/page/year:
   36(1-3),196,1971

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 200 mg/m3/4H
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - lacrimation
   Behavioral - somnolence (general depressed activity)
   Gastrointestinal - changes in structure or function of salivary glands
REFERENCE :
   HYSAAV Hygiene and Sanitation (USSR).  English translation of GISAAA.
   (Springfield, VA)  1964-71. Discontinued.  Volume(issue)/page/year:
   36(1-3),196,1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 320 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#03907

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 58 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JAFCAU Journal of Agricultural and Food Chemistry.  (American Chemical Soc.,
   Distribution Office Dept. 223, POB 57136, West End

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 5 mg/L
REFERENCE :
   GNKAA5 Genetika (Moscow).  For English translation, see SOGEBZ.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  No.1-    1965-
   Volume(issue)/page/year: 22,2416,1986

Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P203
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P312
  • P301+P317
  • P308+P313
  • P318
  • P330 Rinse mouth. 漱口
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....

其他信息

  • 稳定性:Stable. Incompatible with strong oxidizing agents.
  • 生产方法:光气与二丙胺作用生成二丙基氨基甲酰氯，再与乙硫醇反应生成茵草敌。也可在NaOH存在下，采用二丙胺与乙硫基甲酰氯反应制得茵草敌，或采用二丙胺与硫酸二乙酯和COS作用制得。
  • 用途:选择性芽前土壤处理剂。经根或幼茎吸收、传导而起作用。作用机制为抑制核酸代谢和蛋白质合成。主要用于玉米、棉花、苜蓿、菜豆、豌豆、亚麻、马铃薯、甜菜、向日葵、柑橘、菠萝、草莓、葡萄及观赏植物，防除阿拉伯高梁、匐匍冰草、稗、野燕麦、莎草、狗尾草等一年生杂草及马齿苋、藜、繁缕等部分阔叶杂草，推荐用药量10～30g/100m 2 。为防药剂挥发损失，可利用机械将药拌入土内，并进行灌溉。
  • 杀虫剂单一组分标准液
  • RTECS号:FA4550000
  • NIST化学物质信息:Carbamothioic acid, dipropyl-, s-ethyl ester(759-94-4)
  • MOL 文件:759-94-4.mol
  • EPA化学物质信息:Carbamothioic acid, dipropyl-, S-ethyl ester(759-94-4)
  • 外观性质:透明液体,有香味。
  • PackingGroup:III
  • HazardClass:6.1(b)
  • 毒害物质数据:759-94-4(Hazardous Substances Data)

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. E - Alphabetic
  5. EQ - EZ - E
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides & Metabolites - Environmental Standards
  6. Alpha sort - Pesticides & Metabolites
  7. E-G - Alpha sort
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. E - Alphabetic
  5. EP - E
  1. Functional Group 官能团索引
  2. thiocarbamic acid ester

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