nn-diethyl-112333-hexafluoropylamine N,N-二乙基-1,1,2,3,3,3-六氟丙胺
CAS 309-88-6 MFCD00054683
化学结构图
SMILES: CCN(CC)C(F)(F)C(F)C(F)(F)F
化学属性
| Mol. Formula | C7H11F6N |
|---|---|
| Mol. Weight | 223.16 |
| Density | 1.230 g/mL at 25 °C(lit.) |
| Refractive index | n20/D 1.3460(lit.) |
| Flash Point | 14°(57°F) |
| TSCA | No |
| Boiling Point | 56-57 °C at 760 mmHg |
别名和识别编码
| Chemical Name | nn-diethyl-112333-hexafluoropylamine |
|---|---|
| MDL Number | MFCD00054683 |
| CAS Number | 309-88-6 |
| Synonym | N,N-Diethyl-1,1,2,3,3,3-hexafluoropropan-1-amine {LY} N,N-Diethyl-1,1,2,3,3,3-hexafluoropropan-1-amine {} {LY} N,N-Diethyl-1,1,2,3,3,3-hexafluoropropan-1-amine {} {} {LY} N,N-Diethyl-1,1,2,3,3,3-hexafluoropropan-1-amine {} {} {} {LY} N,N-Diethyl-1,1,2,3,3,3-hexafluoropropan-1-amine {} {} {} {} {LY} N,N-Diethyl-1,1,2,3,3,3-hexafluoropropan-1-amine {} {} {} {} {} {LY} N,N-Diethyl-1,1,2,3,3,3-hexafluoropropan-1-amine {} {} {} {} {} {} {LY} N,N-Diethyl-1,1,2,3,3,3-hexafluoropropan-1-amine {} {} {} {} {} {} {} {LY} N,N-Diethyl-1,1,2,3,3,3-hexafluoropropan-1-amine {} {} {} {} {} {} {} {} {LY} N,N-Diethyl-1,1,2,3,3,3-hexafluoropropan-1-amine {} {} {} {} {} {} {} {} {} {LY} N,N-Diethyl-1,1,2,3,3,3-hexafluoropropan-1-amine {} {} {} {} {} {} {} {} {} {} {LY} N,N-Diethyl-1,1,2,3,3,3-hexafluoropropan-1-amine {} {} {} {} {} {} {} {} {} {} {} {LY} N,N-Diethyl-1,1,2,3,3,3-hexafluoropropan-1-amine {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N-Diethyl-1,1,2,3,3,3-hexafluoropropan-1-a |
| PubChem Substance ID | 136149 |
| Chemical Name Translation | N,N-二乙基-1,1,2,3,3,3-六氟丙胺 |
| Merck Number | 5108 |
| LabNetwork Molecule ID | LN00197276 |
| InChI | InChI=1S/C7H11F6N/c1-3-14(4-2)7(12,13)5(8)6(9,10)11/h5H,3-4H2,1-2H3 |
| Canonical SMILES | FC(F)(C(C(F)(N(CC)CC)F)F)F |
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分类
- {SNA} Chemical Synthesis, Fluorination, Fluorination Reagents, Synthetic Reagents
相关文献及参考
- For use in conversion, in ether or THF, of alcohols to alkyl fluorides, see: Bull. Chem. Soc. Jpn., 52, 3377 (1979); J. Fluorine Chem., 31, 135 (1986); 38, 243 (1988). Addition of NaF as a scavenger of the HF liberated in the reaction gives improved results: J. Fluorine Chem., 23, 383 (1983). Carboxylic acids are converted to acyl fluorides: Bull. Chem. Soc. Jpn., 52, 3377 (1979).
- A mixture of N,N-Diethyl-1,1,2,3,3,3-hexafluoropropylamine and N,N-Diethyl-1,2,3,3,3-pentafluoropropenamine, both of which are active fluorinating agents.
- Merck: 14,5108
安全信息
- R34 Causes burns 会导致灼伤
- R10 Flammable 易燃
- R11 Highly flammable 非常易燃
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H226 Flammable liquid and vapour 易燃液体和蒸气
GHS Symbol
其他信息
- Alfa Aesar:石川试剂,tech.90% Ishikawa's Reagent, 90+%(309-88-6)
- N,N-二乙基-1,1,2,3,3,3-六氟丙胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0598 石川试剂[氟化试剂] Ishikawa's Reagent [Fluorinating Reagent] 500G 5490元 2014/06/02 H0598 石川试剂[氟化试剂] Ishikawa's Reagent [Fluorinating Reagent] 25G 743元 2010/06/21 389210250 N,N-二乙基-1,1,2,3,3,3-六氟丙胺 N,N-Diethyl-1,1,2,3,3,3-hexafluoropropylamine 90% 25 GR 1034元
- MSDS 信息:N,N-Diethyl-1,1,2,3,3,3-hexafluoropropylamine(309-88-6).msds
- Hazard Note:Corrosive
- Sigma Aldrich:309-88-6(sigmaaldrich)
- Acros Organics:N,N-二乙基-1,1,2,3,3,3-六氟丙胺 N,N-Diethyl-1,1,2,3,3,3-hexafluoropropylamine, 90%(309-88-6)
- TCI Shanghai:N,N-二乙基-1,1,2,3,3,3-六氟丙胺[氟化试剂] Ishikawa's Reagent [Fluorinating Reagent],>;95.0%(T)(309-88-6)
- MOL 文件:309-88-6.mol
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