Silane, trimethyl(phenylethynyl) 1-苯基-2-(三甲基硅)乙炔

CAS 2170-06-1 MFCD00054860

化学结构图

2170-06-1
SMILES: C[Si](C)(C)C#Cc1ccccc1

化学属性

Mol. FormulaC11H14Si
Mol. Weight174.31
Refractive index1.5270 to 1.5310
Boiling Point87-88
Density0.886
Flash Point73°C(lit.)

别名和识别编码

Chemical NameSilane, trimethyl(phenylethynyl)
Synonym Trimethyl(phenylethynyl)silane {LY} Trimethyl(phenylethynyl)silane {} {LY} Trimethyl(phenylethynyl)silane {} {} {LY} Trimethyl(phenylethynyl)silane {} {} {} {LY} Trimethyl(phenylethynyl)silane {} {} {} {} {LY} Trimethyl(phenylethynyl)silane {} {} {} {} {} {LY} Trimethyl(phenylethynyl)silane {} {} {} {} {} {} {LY} Trimethyl(phenylethynyl)silane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethyl(phenylethynyl)silane {} {} {} {} {} {} {} {} {LY} Trimethyl(phenylethynyl)silane {} {} {} {} {} {} {} {} {} {LY} Trimethyl(phenylethynyl)silane {} {} {} {} {} {} {} {} {} {} {LY} Trimethyl(phenylethynyl)silane {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethyl(phenylethynyl)silane {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethyl(phenylethynyl)silane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethyl(phenylethynyl)silane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethyl(phenylethynyl)silane {} {} {} {} {} {} {} {} {}
CAS Number2170-06-1
PubChem Substance ID137464
Beilstein Registry Number16(4)1416
MDL NumberMFCD00054860
Reaxys-RN606659
Chemical Name Translation1-苯基-2-(三甲基硅)乙炔
InChIKeyUZIXCCMXZQWTPB-UHFFFAOYSA-N
LabNetwork Molecule IDLN00195616
Canonical SMILESC[Si](C#CC1=CC=CC=C1)(C)C
InChIInChI=1S/C11H14Si/c1-12(2,3)10-9-11-7-5-4-6-8-11/h4-8H,1-3H3
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分类

  • Alkynes, Building Blocks, Chemical Synthesis, Internal, Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Alkynes, Building Blocks, Chemical Synthesis, Internal, Organic Building Blocks

相关文献及参考

  • Beil. 16 ,IV,1416
  • FT-IR 2 (3), 4437:D / FT-NMR 1 (3), 720:C / RegBook 1 (2), 3007:J
  • Short: III/35D2 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Carbon-13, Part 2: Aromatic Compounds Author: Mikhova, B. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35D2 Year: 2005 Keyword: aromatic compounds; carbon-13; chemical shift; coupling constant; molecular structure ISBN: 978-3-540-20189-2 ISBN: 3-540-20189-0 Internet Resource: DOI:10.1007/b83345 RefComment: VIII, 291 p., Hardcover RefComment: Written for Science and engineers in the fields of physics, chemistry and physical chemistry who inted to use NMR to study the structure and the binding of molecules Abstract: Nuclear Magnetic Resonance (NMR) is based on the fact that certain nuclei exhibit a magnetic moment, orient by a magnetic field, and absorb characteristic frequencies in the radiofrequency part of the spectrum. The spectral lines of the nuclei are highly influenced by the chemical environment i.e. the structure and interaction of the molecules. NMR is now the leading technique and a powerful tool for the investigation of the structure and interaction of molecules. The present Landolt-Börnstein volume III/35 Nuclear Magnetic Resonance (NMR) Data is therefore of major interest to all scientists and engineers who intend to use NMR to study the structure and the binding of molecules. Volume III/35 "NMR-Data" is divided into several subvolumes and parts. Subvolume III/35A contains the nuclei 11B and 31P, subvolume III/35B contains the nuclei 19F and 15N, subvolume III/35C contains the nucleus 1H, subvolume III/35D contains the nucleus 13C, subvolume III/35E contains the nucleus 17O, and subvolume III/35G contains the nucleus 77Se. More nuclei will be presented later.

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
UN Number
Packing GroupIII

其他信息

  • 苯基乙炔基三甲基硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P1398 1-苯基-2-(三甲基硅)乙炔 1-Phenyl-2-(trimethylsilyl)acetylene 5ML 487元
  • F:8
  • MOL 文件:2170-06-1.mol
  • 图谱信息:苯基乙炔基三甲基硅烷(2170-06-1)质谱(MS)
  • TSCA:No
  • Sigma Aldrich:2170-06-1(sigmaaldrich)
  • TCI Shanghai:1-苯基-2-(三甲基硅)乙炔 1-Phenyl-2-(trimethylsilyl)acetylene,>;98.0%(GC)(2170-06-1)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Alkynes 炔
  5. Internal - Alkynes
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Acetylenes 炔烃

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