Thiophanate-Methyl 甲基托布津

CAS 23564-05-8 MFCD00055294

化学结构图

23564-05-8
SMILES: COC(=O)NC(=S)NC1C=CC=CC=1NC(=S)NC(=O)OC

化学属性

Mol. FormulaC12H14N4O4S2
Mol. Weight342.42
Melting Point172 ºC
Solubility<0.1 G/100 ML AT 20 ºC

别名和识别编码

Chemical NameThiophanate-Methyl
CAS Number23564-05-8
Synonym Dimethyl ((1,2-phenylene)bis-(iminocarbonothioyl))bis(carbamate) Topsin turf and ornamentals Carbamic acid, (1,2-phenylenebis(iminocarbonothioyl))bis-, dimethyl ester Topsin WP methyl 1,2-Bis(3-(methoxycarbonyl)-2-thioureido)benzene Sipcaplant ######## Enovit methyl Methyl topsin Enovit M Trevin BAS 32500F Fungo 50 Cycosin Methylthiofanate Metoben Tiofanate metile Fungo Cercobin methyl Sipcavit Topsin M Thiophanate methyl PELT-44 Easout Enovit Super Mildothane Cercobin M Caligran Dimethyl-4,4'-o-phenylene-bis-(3-thioallophanate) 1,2-Bis(3-(methoxycarbonyl)-2-thioureido)benzene; Dimethyl (1,2-phenylenebis(iminocarbonothioyl))bis(carbamate) 1,2-Bis(methoxycarbonylthioureido)benzene Fungitox TD 1771 甲基硫菌灵 Topsin NF-44 Sipcasan Ditek Thiophanate M o-Bis(3-methoxycarbonyl-2-thioureido)benzene PELT 14 Neotopsin Methyl thiophanate Frumidor
MDL NumberMFCD00055294
PubChem Substance ID24869253
Beilstein Registry Number0937942
EC Number245-740-7
Chemical Name Translation甲基托布津
Wiswesser Line Notation1OVMYUS&MR BMYUS&MVO1
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分类

  • {SNA} All Fungicides, Analytical Standards, Benzimidazoles, Carbamates, Food and Cosmetic Component Standards, Fungicides, Q-Z, Standards for Personal Care and Cosmetic Products, Thiophanate metabolites, neats, prohibited substances (EU-REGULATION No 1223/2009), 代谢物, 农残和代谢标准品, 分析/色谱, 按照字母排序
  • {SNA} Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Benzimidazoles, Carbamates, Chromatography, Environmental Standards, Fungicides, Metabolites,
  • Alpha sort, Alphabet

产品应用

  • Thiophanate-Methyl is a systematic fungicide of the thiophanate class. Thiophanate-Methyl is commonly used in agriculture to protect against powdery mildew, rot and other fungal diseases in fruits, ve

相关文献及参考

  • Vonk, J.W. et al.: Pest. Sci., 2, 160 (1971); Burchill, R.T. et al.: Plant Pathol., 20, 173 (1971); Fuchs, A. et al.: Pest. Biochem. Physiol., 2, 191 (1972); Frossard, P. et al.: Fruits, 28, 195 (1973
  • Merck 14 ,9352

安全信息

RTECSBA3675000
GHS Symbol
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
Hazard Codes Xn;N Xn,N
WGK Germany2
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Signal word Warning
Safety Statements
  • S46 If swallowed, seek medical advice immediately and show this container or label 食入时，立即求医并出示容器/标签；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
  • R20 Harmful by inhalation 吸入有害
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R50/53
UN Number 3077 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3400 mg/kg
TOXIC EFFECTS :
   Sense Organs and Special Senses (Olfaction) - olfactory nerve change
   Behavioral - tremor
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   23,606,1972

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 6640 mg/kg
TOXIC EFFECTS :
   Sense Organs and Special Senses (Olfaction) - olfactory nerve change
   Sense Organs and Special Senses (Eye) - lacrimation
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   23,606,1972

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >10 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERE

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1140 mg/kg
TOXIC EFFECTS :
   Sense Organs and Special Senses (Olfaction) - olfactory nerve change
   Sense Organs and Special Senses (Eye) - lacrimation
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   23,606,1972

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 5 ppm
REFERENCE :
   RSTUDV Rivista di Scienza e Technologia degli Alimenti e di Nutrizione
   Umana.  Review of Science and Technology of Food and Human Nutrition.
   (Bologna, Italy)  V.5-6, 1975-76.  Discontinued.  Volume(issue)/page/year:
   6,161,1976

TYPE OF TEST            : Micronucleus test
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 1 gm/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 300,15,1993

TYPE OF TEST            : Sex chromosome loss and nondisjunction
TEST SYSTEM             : Mold - Aspergillus nidulans
DOSE/DURATION           : 14 umol/L
REFERENCE :
   EVHPAZ EHP, Environmental Health Perspectives.  (U.S. Government Printing
   Office, Supt of Documents, Washington, DC 20402)  No.1-    1972-
   Volume(issue)/page/year: 31,81,1979

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Rodent - mouse Fibroblast
DOSE/DURATION           : 20 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 394,29,1997

TYPE OF TEST            : Sex chromosome loss and nondisjunction
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 1 gm/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 300,15,1993

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 960 mg/kg
SEX/DURATION            : male 5 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - prostate, seminal vesicle, Cowper's gland,
   accessory glands
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   30,129,1974

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 15 gm/kg
SEX/DURATION            : female 1-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - litter size (e.g. # fetuses per litter; measured
   before birth)
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   24,206,1973

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides &amp; Metabolites - Environmental Standards
  6. Alpha sort - Pesticides &amp; Metabolites
  7. Q-Z - Alpha sort
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. T - Alphabetic
  5. TF - TO - T

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