Chlorobenzilate 乙酯杀螨醇

CAS 510-15-6 MFCD00055312

化学结构图

510-15-6
SMILES: CCOC(=O)C(O)(C1C=CC(Cl)=CC=1)C1C=CC(Cl)=CC=1

化学属性

Mol. FormulaC16H14Cl2O3
Mol. Weight325.20
Solubility微溶于水，溶于多数有机溶剂。
Density0.7915

别名和识别编码

Chemical NameChlorobenzilate
Synonym {uni_hamburg} Chlorobenzylate 4,4'-Dichlorobenzilate 4-chloro-alpha-(4-chlorophenyl)-alpha-hydroxy-benzeneaceticaciethylester Compound 338 Ethyl p,p'-dichlorobenzilate Ethyl-4,4'-dich ethyl 4-chloro-α-(4-chlorophenyl)-α-hydroxybenzeneacetate Ethyl 4,4'-dichlorobenzilate 4,4'-Dichlorbenzilsäureethylester Chl 4,4'-Dichlorbenzilsäureaethylester chlorobenzilate 4,4`-二氯二苯基乙醇酸乙酯 4,4'-Dichlor-benzilsäure-ethylester Ethyl-4,4'-dichlorbenzilat Acar Chlorbenzilat (ISO) chlorobenzilate (ISO) CHLOROBENZ Ethyl ester of 4,4'-dichlorobenzilic acid 4,4’-dichloro-benzilicaciethylester 4,4’-dichlorobenzilicacidethylester {u {uni_hamburg ECB 4,4’-dichlorbenzilsaeureaethylester 2-羟基-2,2-双(4-氯苯基)乙酸乙酯 G 23992 CHLORBENZILAT Acaraben G 338 Ethyl-2-hydroxy-2,2-bis(4-chlorophenyl)acetate 4,4'-Dichlorobenzilic Acid ethyl ester Ethyl 4,4'-dichlorodiphenyl glycollate 4,4'-Dichlorobenzilic acid ethyl ester benzilic acid, 4,4'-dichloro-, ethyl ester Akar 338 Folbex 4-氯-Α-(4-氯苯基)-Α-羟基苯乙酸乙酯 Kop-Mite 乙酯杀螨醇 Akar {Chemicalbook 4-chloro-alpha-(4-chloroph 乙醇杀螨酯 Benzeneacetic acid, 4-chloro-α-(4-chlorophenyl)-α-hydroxy-, ethyl ester 4,4'-Dichlorbenzilsaeureaethylester Ethyl 4,4'-dichlorophenyl glycollate 4,4`-二氯苯乙酸乙酯 4，4′-二氯二苯乙醇酸乙酯
MDL NumberMFCD00055312
CAS Number510-15-6
PubChem Substance ID24868851
EC Number208-110-2
Chemical Name Translation乙酯杀螨醇
Merck Number13,2141
Wiswesser Line NotationGR DXQR DG&VO2
Beilstein Registry Number2755859
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分类

  • {SNA} Acaricides,
  • {SNA} Acaricides, Analytical Standards, C, 农残和代谢标准品, 分析/色谱, 按照字母排序
  • {SNA} Acaricides, Analytical Standards, C, 农残和代谢标准品, 农残标准品, 分析/色谱, 按照字母排序
  • {SNA} Acaricides, All alphabetically sorted, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, C, CH, Chromatography, Environmental Standards, Pesticides, Pesticides & Metabolites
  • {SNA} Acaricides, Alphabetical Index of Analytical Standards, Analytical Standards,

相关文献及参考

  • Short: IV/8A Title: Enthalpies of Fusion and Transition of Organic Compounds Author: Zhang, Z.-Y.; Frenkel, M.; March, K.N.; Wilhoit, R.C. Editor: Marsh, K.N. Source: Landolt-Börnstein, New Series Volume: IV/8A Year: 1995 Keyword: organic compounds; enthaly of fusion; melting point; phase transition ISBN: 3-540-58854-X ISBN: 978-3-540-58854-2 Internet Resource: DOI:10.1007/b55145 RefComment: VIII, 588 pages.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

RTECSDD2275000
GHS Symbol
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P273 Avoid release to the environment. 避免释放到环境中。
Hazard statements
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H302 Harmful if swallowed 吞食有害
WGK Germany3
Signal word Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Hazard Codes Xn,N,T Xn,N
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R50/53
  • R45 May cause cancer 可能致癌
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
Storage condition 室温储存 0-6°C
UN Number UN 1593 6.1/PG 3
Warnings 危化品目录(2015) 危险化学品 
{haz

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 71 gm/kg/82W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
   Blood - lymphoma, including Hodgkin's disease
REFERENCE :
   JNCIAM Journal of the National Cancer Institute.  (Washington, DC)  V.1-60,
   1940-78.  For publisher information, see JJIND8.  Volume(issue)/page/year:
   42,1101,1969

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 5475 mg/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Blood - lymphoma, including Hodgkin's disease
   Skin and Appendages - tumors
REFERENCE :
   CTOXAO Clinical Toxicology.  (New York, NY)  V.1-18, 1968-81.  For publisher
   information, see JTCTDW.  Volume(issue)/page/year

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 17520 mg/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Blood - lymphoma, including Hodgkin's disease
   Skin and Appendages - tumors
REFERENCE :
   CTOXAO Clinical Toxicology.  (New York, NY)  V.1-18, 1968-81.  For publisher
   information, see JTCTDW.  Volume(issue)/page/year: 16,67,1980

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 72 gm/kg/78W-C
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Liver - tumors
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Volume(issue)/page/year: NCI-TR-75,1978

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >1 gm

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 700 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   WRPCA2 World Review of Pest Control.  (London, UK)  V.1-10, 1962-71.
   Discontinued.  Volume(issue)/page/year: 9,119,1970

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >5 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   14,515,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - hamster
DOSE/DURATION           : 700 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   48,A192,1979

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 729 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   30ZDA9 "Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag
   New York, Inc., 1971  Volume(issue)/page/year: -,141,1971

{hazard_co

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 80 mg/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   12,85,1988

TYPE OF TEST            : Mutation test systems - not otherwise specified
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 360 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 343,157,1995

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 12010 nmol/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   19,98,1992

TYPE OF TEST            : Morphological transformation
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 4620 mg/kg/77D (Continuous)
REFERENCE :
   CRNGDP Carcinogenesis (London). (Oxford Univ. Press, Pinkhill House,
   Southfield Road, Eynsham, Oxford OX8 1JJ, UK)  V.1-    1980-
   Volume(issue)/page/year: 11,1413,1990

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 70 mg/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   12,85,1988

其他信息

  • 可燃性危险特性:受热分解有毒氯化物气体
  • 灭火剂:砂土、干粉、泡沫
  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • 类别:农药
  • 毒性分级:中毒
  • 急性毒性:口服-大鼠 LD50: 700 毫克/公斤; 口服-小鼠 LD50: 729 毫克/公斤
  • 急救治疗:[1]无特殊解毒剂，如经口摄入要催吐。 [2]尽可能保持病人安静，控制病人激动，清醒时可给予常用剂量的巴比妥与其它镇静剂。 [3]注意维持呼吸，如有衰竭使用人工呼吸。 [4]禁忌用肾上腺素或阿托品。
  • 杀虫剂单一组分标准液
  • 图谱信息:丁酰肼(510-15-6)核磁图( 1 HNMR) 丁酰肼(510-15-6)红外图谱(IR2) 丁酰肼(510-15-6)质谱(MS) 丁酰肼(510-15-6)核磁图( 13 CNMR) 丁酰肼(510-15-6)红外图谱(IR1)
  • MSDS 信息:4,4'-二氯二苯乙醇酸乙酯(510-15-6).msds
  • Sigma Aldrich:510-15-6(sigmaaldrich)
  • 注意事项:由于该品毒性大，有致癌危险。在我国无登记产品
  • 外观性质:微黄色固体，工业品为棕色液体。
  • MOL 文件:510-15-6.mol
  • 刺激数据:眼睛-兔子 25 毫克 中度; 皮肤-兔子 125 毫克 轻度
  • 中毒症状:症状与体征是其对神经系统的刺激作用所致，如头痛、眩晕、忧虑烦恼、情绪激动，也有呕吐、四肢软弱、双手震颤、失去时间和空间的定向，随后出现阵发痉挛。

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides & Metabolites - Environmental Standards
  6. Pesticides - Pesticides & Metabolites
  7. Acaricides - Pesticides
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. C - Alphabetic
  5. CH - C

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