Thionazin 硫磷嗪

CAS 297-97-2 MFCD00055349

化学结构图

297-97-2
SMILES: CCOP(=S)(OCC)Oc1cnccn1

化学属性

Mol. FormulaC8H13N2O3PS
Mol. Weight248.26
Density1.278
Refractive index1.5080~1.5105
Melting Point-1.7°C
Flash Point100 °C
Solubility微溶于水,可混溶于多数有机溶剂。

别名和识别编码

Chemical NamePhosphorothioic acid, O,O-diethyl O-pyrazinyl ester
Synonym 0,0-二乙基-0-吡嗪基硫代磷酸酯 AC 18133 Ac 18133 Acc 18133 American cyanamid 18133 CL 18133 CYNEM(R) Cl 18133 Cynem Cynophos Diethyl O-2-pyrazinyl phosphorothionate EN 18133 ENT 25,580 Ethyl pyrazinyl phosphorothioate Experimental nematocide 18,133 NAMAFOS(R) Nemafos Nemaphos Nematocide GR O, O-DIETHYL O-(2-PYRAZINYL) PHOSPHOROTHIOATE O,O-DIETHYL-2-PYRAZINYL PHOSPHOROTHIOATE O,O-Diaethyl-O-(2-pyrazinyl)-thionophosphat O,O-Diaethyl-O-(pyrazin-2-yl)-monothiophosphat O,O-Diethyl O,2-pyrazinyl phosphorothioate O,O-Diethyl O-2-pyrazinyl phosphorothionate O,O-Diethyl O-pyrazinyl thiophosphate O,O-diethyl O-2-py
MDL NumberMFCD00055349
CAS Number297-97-2
EC Number206-049-6
PubChem Substance ID9272
Beilstein Registry Number0884916
Chemical Name Translation硫磷嗪
Wiswesser Line NotationT6N DNJ BOPS&O2&O2
InChIInChI=1S/C8H13N2O3PS/c1-3-11-14(15,12-4-2)13-8-7-9-5-6-10-8/h5-7H,3-4H2,1-2H3
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分类

  • Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Baby Food Directives 13/2003 EC & 14/2003 EC, Chromatography, Cyclodienes, Environmental Standards, European Community: ISO, DIN and DL 152, Insecticides, Method Specific, Nematicides, Pesticides, Pesticides & Metabolites, Q-Z, T, TF - TO
  • {SA} Alphabetic, Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards, Nematicides, Pesticides, Pesticides & Metabolites,
  • {SNA} Alphabetical Index of Analytical

安全信息

RTECSTF5775000
GHS Symbol
WGK Germany2
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P316
  • P302+P350
  • P302+P352
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P316
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P361+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
Hazard Codes F,Xn T+ T+,Xn,F
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S38 In case of insufficient ventilation wear suitable respiratory equipment 通风不良时,佩带适当的呼吸器;
Risk Statements
  • R11 Highly flammable 非常易燃
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R36 Irritating to eyes 刺激眼睛
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R27/28 Very toxic in contact with skin and if swallowed 皮肤接触及吞食都有剧毒
Storage condition 2-8°C
UN Number 3018
Restrict 剧毒化学品
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - pigeon
DOSE/DURATION           : 2370 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ASTTA8 ASTM Special Technical Publication.  (American Soc. for Testing
   Materials, 1916 Race St., Philadelphia, PA 19103)  No.1-    1911-
   Volume(issue)/page/year: (680),157,1979

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Bird - duck
DOSE/DURATION           : 7 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   47,451,1979

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Ocular
SPECIES OBSERVED

{

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 8 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   SPEADM Special Publication of the Entomological Society of America.  (4603
   Calvert Rd., College Park, MD 20740)  Volume(issue)/page/year: 78-1,46,1978

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 5 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JDAH "Organophosphorus Pesticides: Organic and Biological Chemistry," Eto,
   M., Cleveland, OH, CRC Press, Inc.,  1974  Volume(issue)/page/year:
   -,197,1974

其他信息

  • 外观性质:琥珀色液体。
  • RTECS号:TF5775000
  • PackingGroup:I
  • HazardClass:6.1(a)
  • MOL 文件:297-97-2.mol
  • 黄色液体,与有机溶剂混溶。大鼠急性经口LD5012mg/kg。由O,O-二乙基硫代磷酰氯与吡嗪-2-羟基钠反应制得。用于防治土壤害虫和线虫,如金龟子、叶甲、叩甲、花蝇、种蝇、异皮线虫、黄麻,根疣线虫等。制剂有46%乳油,5%、10%颗粒剂。

系列性分类


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