Vamidothion 蚜灭磷

CAS 2275-23-2 MFCD00055442

化学结构图

2275-23-2
SMILES: CNC(=O)C(C)SCCSP(=O)(OC)OC

化学属性

Mol. FormulaC8H18NO4PS2
Mol. Weight287.34
Flash Point2 °C
Density1.0
Stability对光线敏感
Melting Point35.5 °C
Boiling Point72.8 °C at 760 mmHg

别名和识别编码

Chemical NameVamidothion
CAS Number2275-23-2
Synonym Vamidothion {LY} Vamidothion {} {LY} Vamidothion {} {} {LY} Vamidothion {} {} {} {LY} Vamidothion {} {} {} {} {LY} Vamidothion {} {} {} {} {} {LY} Vamidothion {} {} {} {} {} {} {LY} Vamidothion {} {} {} {} {} {} {} {LY} Vamidothion {} {} {} {} {} {} {} {} {LY} Vamidothion {} {} {} {} {} {} {} {} {} {LY} Vamidothion {} {} {} {} {} {} {} {} {} {} {LY} Vamidothion {} {} {} {} {} {} {} {} {} {} {} {LY} Vamidothion {} {} {} {} {} {} {} {} {} {} {} {} {LY} Vamidothion {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Vamidothion {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Vamidothion {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Vamidothion {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Vamidothion {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Vamidothion {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00055442
EC Number200-835-2
Chemical Name Translation 蚜灭磷
Wiswesser Line Notation1OPO&O1&S2SY1&VM1
Beilstein Registry Number2651123
PubChem Substance ID560193
InChIInChI=1S/C8H18NO4PS2/c1-7(8(10)9-2)15-5-6-16-14(11,12-3)13-4/h7H,5-6H2,1-4H3,(H,9,10)
Canonical SMILESO=C(C(C)SCCSP(OC)(OC)=O)NC
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分类

  • {SNA} Acaricides, All alphabetically sorted, Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards,
  • {SNA} Acaricides, Analytical Standards, Insecticides, Organophorous, Q-Z, 农残和代谢标准品, 农残标准品, 分析/色谱, 按照字母排序
  • {SNA} Analytical Standards, Insecticides, Organophorous, Q-Z, 农残和代谢标准品, 分析/色谱, 按照字母排序
  • {SNA} Acaricides, All alphabetically sorted, Analytical Standards, Analytical/Chromatography, Chromatography,

产品应用

  • Vamidothion is a phosphorothioic insecticide for apples and potatoes.

相关文献及参考

  • Erney, D., et al.: J. High Resolut. Chromatogr., 18, 59 (1998),
  • Ragnarsdottir, K., et al.: Geol. Soc., 157, 859 (2000),
  • Salas, J., et al.: J. Agric. Food Chem., 51, 4468 (2003),

安全信息

GHS Symbol
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Hazard statements
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302+H312+H332
  • H332 Harmful if inhaled 吸入有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H302 Harmful if swallowed 吞食有害
WGK Germany2
Signal word Danger
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes F,Xn T;N,N,T,Xn,F T;N
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R25 Toxic if swallowed 吞咽有毒
  • R50 Very toxic to aquatic organisms 对水生生物极毒
  • R21 Harmful in contact with skin 与皮肤接触有害
  • R11 Highly flammable 非常易燃
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R36 Irritating to eyes 刺激眼睛
UN Number 2811 UN 2811
Packing GroupIII
Hazard Class6.1(b)
Storage condition 0-6°C 储存温度 2-8℃
RTECSTF7900000 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 1160 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   WRPCA2 World Review of Pest Control.  (London, UK)  V.1-10, 1962-71.
   Discontinued.  Volume(issue)/page/year: 9,119,1970

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 110 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GUCHAZ Guide to the Chemicals Used in Crop Protection.  (Information Canada,
   171 Slater St., Ottawa, Ont., Canada)  Volume(issue)/page/year: 6,530,1973

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1460 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   YKYUA6 Yakkyoku.  Pharmacy.  (Nanzando, 4-1-11, Yushima, Bunkyo-ku, Tokyo,
   Japan)  V.1-    1950-  Volume(issue)/page/year: 37,1621,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROU

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - wild bird species
DOSE/DURATION           : 35 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PEMNDP Pesticide Manual.  (The British Crop Protection Council, 20 Bridport
   Rd., Thornton Heath CR4 7QG, UK)  V.1-    1968-  Volume(issue)/page/year:
   9,856,1991

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Or

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 5 mmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 78,177,1980

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Bacillus subtilis
DOSE/DURATION           : 25 pph
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 40,19,1976

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 25 pph
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 40,19,1976

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 25 pph
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 40,19,1976

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 1 mmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 78,177,1980

其他信息

  • 灭火剂:砂土、干粉、泡沫
  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • 急救治疗:[1]用阿托品1～5mg皮下或静脉注射(按中毒轻重而定) [2]用解磷定0.4－1.2g 静脉注射(按中毒轻重而定) [3]禁用吗啡、茶硷、吩噻嗪、利血平。 [4]误服立即引吐、洗胃、导泻(清醒时才能引吐)。
  • 类别:农药
  • 用途二:广谱性杀虫剂，用于防治各种蚜、螨、稻飞虱、叶蝉等，对苹果绵蚜有特效
  • MOL 文件:2275-23-2.mol
  • Sigma Aldrich:2275-23-2(sigmaaldrich)
  • 毒性分级:剧毒
  • 急性毒性:口服-大鼠 LD50: 64 毫克/公斤; 口服-小鼠 LD50: 40 毫克/公斤
  • 可燃性危险特性:受热分解有毒氧化磷、氧化硫、氧化氮气体
  • 中毒症状:急性中毒多在12小时内发病，口服立即发病。轻度：头痛、头昏、恶心、呕吐、多汗、无力、胸闷、视力模糊、胃口不佳等，全血胆碱酯酶活力一般降 至正常值的70－50%。中度：除上述症状外,还出现轻度呼吸困难、肌肉震颤 、瞳孔缩小、精神恍惚、行走不稳、大汗、流涎、腹疼、腹泻。重者还会出现昏迷、抽搐、呼吸困难、口吐白沫、大小便失禁，惊厥，呼吸麻痹。
  • MSDS 信息:Dimethyl phosphorothioate 2-((2-mercaptoethyl)thio)-N-methylpropionamide S-ester(2275-23-2).msds
  • 用途一:广谱性杀虫剂，对杀灭苹果绵蚜虫有特效
  • 注意事项:不可与碱性农药或碱性物质混

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides & Metabolites - Environmental Standards
  6. Pesticides - Pesticides & Metabolites
  7. Acaricides - Pesticides

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