(4S)-4-(2-Chlorophenyl)-2-Hydroxy-5,5-Dimethyl-1,3,2-Dioxaphosphinane 2-Oxide (S)-(-)-4-(2-氯苯基)-5,5-二甲基-2-羟基-1,3,2-二氧磷杂环己烷-2-氧化物

CAS 98674-86-3 MFCD00055615

化学结构图

98674-86-3
SMILES: CC1(C)COP(=O)(O)O[C@@H]1c1ccccc1Cl

化学属性

Mol. FormulaC11H14ClO4P
Mol. Weight277
Melting Point228-234 °C(lit.)

别名和识别编码

Chemical Name(4S)-4-(2-Chlorophenyl)-2-Hydroxy-5,5-Dimethyl-1,3,2-Dioxaphosphinane 2-Oxide
CAS Number98674-86-3
Alfabeta NameCHLOCYPHOS S(())---
MDL NumberMFCD00055615
PubChem Substance ID24870176
Chemical Name Translation(S)-(-)-4-(2-氯苯基)-5,5-二甲基-2-羟基-1,3,2-二氧磷杂环己烷-2-氧化物
Synonym (S)-(-)-4-(2-氯苯基)-2-羟基-5,5-二甲基-1,3,2-二氧磷杂环己烷 2-氧化物
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Organic Phosphates/Phosphites
  • {KO} Misc
  • {SA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Organic Phosphates/Phosphites

相关文献及参考

  • 1. ten Hoeve, W. and Wynberg, H. J. Org. Chem. 50 , 4508, (1985)
  • 2. ten Hoeve, W., and Wynberg, H. Synth. Commun. 24 , 899, (1994)
  • 3. Van der Haest, A.D. et al. Rec. Trav. Chim. 109 , 523, (1990)

安全信息

Warnings IRRITANT
WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Organic Phosphates/Phosphites - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Organic Phosphates/Phosphites - Organic Building Blocks

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