Samarium(III) Isopropoxide 异丙氧基钐(III)

CAS 3504-40-3 MFCD00058820

化学结构图

3504-40-3
SMILES: CC(C)O[Sm](OC(C)C)OC(C)C

化学属性

Mol. FormulaSm[OCH(CH3)2]3
Mol. Weight327.62
TSCANo
Boiling Point210-30 °C at 0.01 mmHg
Appearance cream colored pwdr.
Stabilitymoisture sensitive

别名和识别编码

Chemical NameSamarium(III) Isopropoxide
MDL NumberMFCD00058820
PubChem Substance ID2734138
CAS Number3504-40-3
Chemical Name Translation异丙氧基钐(III)
Synonym Samarium(iii) propan-2-olate {LY} Samarium(iii) propan-2-olate {} {LY} Samarium(iii) propan-2-olate {} {} {LY} Samarium(iii) propan-2-olate {} {} {} {LY} Samarium(iii) propan-2-olate {} {} {} {} {LY} Samarium(iii) propan-2-olate {} {} {} {} {} {LY} Samarium(iii) propan-2-olate {} {} {} {} {} {} {LY} Samarium(iii) propan-2-olate {} {} {} {} {} {} {} {LY} Samarium(iii) propan-2-olate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Samarium(iii) propan-2-olate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Samarium(iii) propan-2-olate {} {} {} {} {} {} {} {} {} {} {LY} Samarium(iii) propan-2-olate {} {} {} {} {} {} {} {} {} {} {} {LY} Samarium(iii) propan-2-olate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Samarium(iii) propan-2-olate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Samarium(iii) propan-2-olate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Samarium(iii) propan-2-olate {} {} {} {} {} {} {} {} {} {} {}
InChIInChI=1S/3C3H7O.Sm/c3*1-3(2)4;/h3*3H,1-2H3;/q3*-1;+3
Canonical SMILESCC(C)[O-].CC(C)[O-].CC(C)[O-].[Sm+3]
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Micro/NanoElectronics, Samarium, Samarium Catalysts, Solution Deposition Precursors, 材料科学
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Micro/NanoElectronics, Samarium, Solution Deposition Precursors,

相关文献及参考

  • 1. J. Am. Chem. Soc. 129 , 4900, (2007) 摘要
  • Structure Index 1 , 484:D:7

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Hazard statements
  • H228 Flammable solid 易燃固体
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes F,Xi
Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Signal word Warning
Safety Statements
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
UN Number UN 1325 4.1/PG 3 UN3274
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R11 Highly flammable 非常易燃
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
  • R48/20
  • R34 Causes burns 会导致灼伤
Storage condition Moisture Sensitive
Packing GroupII
Hazard Class3

其他信息

  • Alfa Aesar:异丙醇钐5%w/vintoluene-isopropanol,99%(REO) Samarium(III) isopropoxide, 99% (REO), 5% w/v in toluene/isopropanol(3504-40-3)
  • 异丙氧基钐 安剖瓶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 41311 异丙醇钐 5% w/v in toluene-isopropanol, 99% (REO) Samarium(III) isopropoxide, 99% (REO), 5% w/v in toluene/isopropanol 25ml 1141元 2010/05/25 41311 异丙醇钐 5% w/v in toluene-isopropanol, 99% (REO) Samarium(III) isopropoxide, 99% (REO), 5% w/v in toluene/isopropanol 100ml 3836元
  • Sigma Aldrich:3504-40-3(sigmaaldrich)
  • MOL 文件:3504-40-3.mol
  • TSCA:No
  • 敏感性:Moisture Sensitive

系列性分类

  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Solution Deposition Precursors - Micro/NanoElectronics
  4. Samarium - Solution Deposition Precursors
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Samarium 钐
  1. Alkoxide
  2. Samarium

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