Bis(1,5-Cyclooctadiene)Nickel(0) 双-(1,5-环辛二烯)镍(0)

CAS 1295-35-8 MFCD00058902

化学结构图

1295-35-8
SMILES: C1=C\CC/C=C\CC/1.C1=C\CC/C=C\CC/1.[Ni]

化学属性

Mol. FormulaC16H24Ni
Mol. Weight275.06
Density1.18
Melting Point60
TSCANo
Stability对光、空气和湿度敏感
Appearance yellow xtl.
Danger-Level-
pH-:-
Redox-

别名和识别编码

Chemical NameBis(1,5-Cyclooctadiene)Nickel(0)
MDL NumberMFCD00058902
CAS Number1295-35-8
EC Number215-072-0
Beilstein Registry Number2384789
Synonym Ni(COD)2 {LY} Ni(COD)2 {} {LY} Ni(COD)2 {} {} {LY} Ni(COD)2 {} {} {} {LY} Ni(COD)2 {} {} {} {} {LY} Ni(COD)2 {} {} {} {} {} {LY} Ni(COD)2 {} {} {} {} {} {} {LY} Ni(COD)2 {} {} {} {} {} {} {} {LY} Ni(COD)2 {} {} {} {} {} {} {} {} {LY} Ni(COD)2 {} {} {} {} {} {} {} {} {} {LY} Ni(COD)2 {} {} {} {} {} {} {} {} {} {} {LY} Ni(COD)2 {} {} {} {} {} {} {} {} {} {} {} {LY} Ni(COD)2 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ni(COD)2 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ni(COD)2 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ni(COD)2 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ni(COD)2 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ni(COD)2 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ni(COD)2
PubChem Substance ID6433264
Chemical Name Translation双-(1,5-环辛二烯)镍(0)
LabNetwork Molecule IDLN00155226
InChIKeyJRTIUDXYIUKIIE-KZUMESAESA-N
InChIInChI=1S/2C8H12.Ni/c2*1-2-4-6-8-7-5-3-1;/h2*1-2,7-8H,3-6H2;/b2*2-1-,8-7-;
Canonical SMILESC1=C\CC/C=C\CC/1.C2=C\CC/C=C\CC/2.[Ni]
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, New Products for Chemical Synthesis, Nickel, Non-Precious Metal Catalysis
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Nickel
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Nickel, Non-Precious Metal Catalysis

产品应用

  • 用于催化 1,3-二烯类化合物的环加成反应

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S53 Avoid exposure - obtain special instructions before use 避免接触,使用前获得特别指示说明;
Risk Statements
  • R11 Highly flammable 非常易燃
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R45 May cause cancer 可能致癌
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P203
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P285 In case of inadequate ventilation wear respiratory protection. 在通风不足的情况下,戴呼吸防护。
  • P302+P352
  • P304+P340
  • P304+P341
  • P308+P313
  • P318
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P333+P313
  • P342+P311
  • P342+P316
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H228 Flammable solid 易燃固体
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
  • H350 May cause cancer 可能致癌
  • H351 Suspected of causing cancer 怀疑致癌
RTECSQR6135000
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Packing GroupII
UN Number 1325 UN1325
Storage condition -20°C, protect from light, stored under nitrogen {LY} -20°C, protect from light, stored under nitrogen 0-6°C Air & Light Sensitive Air Sensitive {} {LY} -20°C, protect from light, stored under nitrogen {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light,
Hazard Codes 4.1 F,Xn F;T
Hazard Class4.2
TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 1 mg/plate
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   19(Suppl 21),2,1992

Restrict 危险品

其他信息

  • Sigma Aldrich:1295-35-8(sigmaaldrich)
  • 敏感性:Air Sensitive
  • 存储注意事项:湿度敏感;光敏感;空气敏感
  • Acros Organics:双(1,5-环辛二烯)镍(O) Bis(1,5-cyclooctadiene)nickel(0)(1295-35-8)
  • Alfa Aesar:双(1,5-环辛二烯)镍(0),95+% Bis(1,5-cyclooctadiene)nickel(0), 96%(1295-35-8)
  • MOL 文件:1295-35-8.mol
  • 双-(1,5-环辛二烯)镍价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 223970050 双-(1,5-环辛二烯)镍 Bis(1,5-cyclooctadiene)nickel(0) 5 GR 1444元 2010/06/21 223970010 双-(1,5-环辛二烯)镍 Bis(1,5-cyclooctadiene)nickel(0) 1 GR 422元 2010/05/25 39234 双(1,5-环辛二烯)镍(0) Bis(1,5-cyclooctadiene)nickel(0) 2g 791元

系列性分类


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