Methyl 2-mercaptobenzoate 硫代水杨酸甲酯

CAS 4892-02-8 MFCD00060678

化学结构图

4892-02-8
SMILES: COC(=O)c1ccccc1S

化学属性

Mol. FormulaC8H8O2S
Mol. Weight168.21
Boiling Point98-100°C at 2 mmHg
Density1.223
Refractive index1.5920 to 1.5960
Flash Point98.9°C
TSCANo
Stability对空气敏感

别名和识别编码

Chemical NameMethyl 2-mercaptobenzoate
CAS Number4892-02-8
Alfabeta NameMETHYLTHIOSALICYLATE
MDL NumberMFCD00060678
Synonym Methyl 2-mercaptobenzoate {LY} Methyl 2-mercaptobenzoate {} {LY} Methyl 2-mercaptobenzoate {} {} {LY} Methyl 2-mercaptobenzoate {} {} {} {LY} Methyl 2-mercaptobenzoate {} {} {} {} {LY} Methyl 2-mercaptobenzoate {} {} {} {} {} {LY} Methyl 2-mercaptobenzoate {} {} {} {} {} {} {LY} Methyl 2-mercaptobenzoate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl 2-mercaptobenzoate {} {} {} {} {} {} {} {} {LY} Methyl 2-mercaptobenzoate {} {} {} {} {} {} {} {} {} {LY} Methyl 2-mercaptobenzoate {} {} {} {} {} {} {} {} {} {} {LY} Methyl 2-mercaptobenzoate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl 2-mercaptobenzoate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl 2-mercaptobenzoate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl 2-mercaptobenzoate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl 2-mercaptobenzoate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl 2-mercaptobenzoate {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID21009
Reaxys-RN956859
Beilstein Registry Number10(4)280
Chemical Name Translation硫代水杨酸甲酯
Wiswesser Line Notation1SVR
InChIKeyBAQGCWNPCFABAY-UHFFFAOYSA-N
LabNetwork Molecule IDLN00116965
InChIInChI=1S/C8H8O2S/c1-10-8(9)6-4-2-3-5-7(6)11/h2-5,11H,1H3
Canonical SMILESO=C(OC)C1=CC=CC=C1S
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分类

  • Sulfur & Selenium Compounds
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfur Compounds, Thiols/Mercaptans

相关文献及参考

  • Beilstein:10(4)280

安全信息

Warnings IRRITANT
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R22 Harmful if swallowed 吞咽有害
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
Storage condition 2-8°C {LY} 2-8°C Air Sensitive {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
GHS Symbol
WGK Germany3
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H302+H312+H332
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSDH3500000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P312+P330
  • P302+P352
  • P302+P352+P312+P362+P364
  • P304+P312
  • P304+P340
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Hazard Codes Xn Xn,Xi
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 50 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

其他信息

  • Acros Organics:硫代水杨酸甲酯 Methyl thiosalicylate, 97%(4892-02-8)
  • Sigma Aldrich:4892-02-8(sigmaaldrich)
  • MOL 文件:4892-02-8.mol
  • 硫代水杨酸甲酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M1881 硫代水杨酸甲酯 Methyl Thiosalicylate 5G 859元 2014/06/02 M1881 硫代水杨酸甲酯 Methyl Thiosalicylate 25G 2310元 2010/06/21 369600050 硫代水杨酸甲酯 Methyl thiosalicylate 97% 5 GR 856元
  • 敏感性:Air Sensitive
  • Alfa Aesar:甲基硫代水杨酸盐,97% Methyl thiosalicylate, 97%(4892-02-8)
  • TCI Shanghai:2-巯基苯甲酸甲酯 Methyl Thiosalicylate,>;97.0%(GC)(4892-02-8)

系列性分类


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