L-Leucinol (S)-(+)-亮氨醇

CAS 7533-40-6 MFCD00063676

化学结构图

7533-40-6
SMILES: CC(C)C[C@H](N)CO

化学属性

Mol. FormulaC6H15NO
Mol. Weight117.19
Refractive index1.4490 to 1.4520
Boiling Point198-200°C at 760 mmHg
Density0.92
Flash Point91°C
TSCANo
Appearance 白色或几乎白色结晶粉末。
Melting Point208-210 °C

别名和识别编码

Chemical NameL-Leucinol
CAS Number7533-40-6
Alfabeta NameLEUCINOL S+(())--
MDL NumberMFCD00063676
Synonym L-Leucinol {LY} L-Leucinol leucinol {} {LY} L-Leucinol {} {} {LY} L-Leucinol {} {} {} {LY} L-Leucinol {} {} {} {} {LY} L-Leucinol {} {} {} {} {} {LY} L-Leucinol {} {} {} {} {} {} {LY} L-Leucinol {} {} {} {} {} {} {} {LY} L-Leucinol {} {} {} {} {} {} {} {} {LY} L-Leucinol {} {} {} {} {} {} {} {} {} {LY} L-Leucinol {} {} {} {} {} {} {} {} {} {} {LY} L-Leucinol {} {} {} {} {} {} {} {} {} {} {} {LY} L-Leucinol {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-Leucinol {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-Leucinol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-Leucinol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-Leucinol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-Leucinol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-Leucinol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-Leucinol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-Leucinol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID111307
EC Number231-400-5
Beilstein Registry Number1719240
Chemical Name Translation(S)-(+)-亮氨醇
Reaxys-RN1719240
InChIKeyVPSSPAXIFBTOHY-LURJTMIESA-N
LabNetwork Molecule IDLN00173225
InChIInChI=1S/C6H15NO/c1-5(2)3-6(7)4-8/h5-6,8H,3-4,7H2,1-2H3/t6-/m0/s1
Canonical SMILESCC(C)C[C@H](N)CO
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分类

  • {SNA} Amino Acid Derivatives, Amino Alcohols, Chemical Biology, Chemical Synthesis, Peptide Chemistry
  • {SNA} Amino Acids & Derivatives, Amino Alcohols, Chemical Biology, Chemical Synthesis, Peptide Chemistry

产品应用

  • 用于合成氨基肽酶 N 和磷脂酶 A2抑制剂的原料。

相关文献及参考

  • Beil. 4 ,IV,1797
  • Beilstein:4(4)1797
  • 2. J. Med. Chem. 35 , 2939, (1992) 摘要

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes Xi
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P370+P378
  • P403+
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S37 Wear suitable gloves 戴适当手套；
Storage condition 2-8°C {LY} 2-8°C Air Sensitive Store at 0°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 上游原料:四氢呋喃 --> 氢化铝锂 --> L-亮氨酸
  • TCI Shanghai:L-(+)-亮氨醇 L-(+)-Leucinol,>;96.0%(GC)(T)(7533-40-6)
  • 图谱信息:L-亮氨醇(7533-40-6)核磁图( 1 HNMR) L-亮氨醇(7533-40-6)红外图谱(IR1) L-亮氨醇(7533-40-6)质谱(MS) L-亮氨醇(7533-40-6)核磁图( 13 CNMR)
  • Alfa Aesar:L-亮氨醇,97% L-Leucinol, 97%(7533-40-6)
  • 敏感性:Air Sensitive
  • Acros Organics:L-亮氨醇 L(+)-Leucinol, 98%(7533-40-6)
  • L-亮氨醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 62016380 L-白氨醇 1ml 41.8元 2011/04/16 L0137 L-(+)-亮氨醇 L-(+)-Leucinol 5ML 873元 2011/04/16 L0137 L-(+)-亮氨醇 L-(+)-Leucinol 25ML 2930元
  • MOL 文件:7533-40-6.mol
  • 用途一:用作有机合成原料
  • Sigma Aldrich:7533-40-6(sigmaaldrich)
  • F:2-10
  • MSDS 信息:L(+)-Leucinol(7533-40-6).msds
  • 比旋光度:3 ° (589nm, c=9, ethanol)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Peptide Chemistry 多肽化学
  4. Amino Acid Derivatives 氨基酸及其衍生物
  5. Amino Alcohols - Amino Acid Derivatives
  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Peptide Chemistry 多肽化学
  4. Amino Acid Derivatives 氨基酸及其衍生物
  5. Amino Alcohols - Amino Acid Derivatives
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Amino Acids 氨基酸
  4. Modified Amino Acids - Amino Acids
  5. Amino alcohols

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