D-(+)-Glucose D-(+)-葡萄糖

CAS 50-99-7 MFCD00063774

化学结构图

50-99-7
SMILES: O=C[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO

化学属性

Mol. FormulaC6H12O6
Mol. Weight180.16
Melting Point150-152°C
Refractive indexn20/D 1.362
TSCAYes
Density1.544
Stability对湿度敏感
Appearance 无色或白色结晶状粉末,无臭,味甜。 溶于水,微溶于乙醇,不溶于乙醚和芳香烃。 solution
SolubilitySoluble in water (0.9 g/ml at 25 °C), alcohol (slightly), methanol ( at 20 °C), absolute alcohol (very sparingly), ether (very sparingly), acetone (very sparingly), hot glacial acetic acid, pyridine, aniline, ethanol (<1 mg/mL at 25 °C), and DMSO (36 m
Boiling Point527.1°C at 760 mmHg
Danger-Level-
pH-:-
Redox-

别名和识别编码

Chemical NameD-(+)-Glucose
MDL NumberMFCD00148912
CAS Number50-99-7
Synonym D-Glucose {LY} D-Glucose {} {LY} D-Glucose {} {} {LY} D-Glucose {} {} {} {LY} D-Glucose {} {} {} {} {LY} D-Glucose {} {} {} {} {} {LY} D-Glucose {} {} {} {} {} {} {LY} D-Glucose {} {} {} {} {} {} {} {LY} D-Glucose {} {} {} {} {} {} {} {} {LY} D-Glucose {} {} {} {} {} {} {} {} {} {LY} D-Glucose {} {} {} {} {} {} {} {} {} {} {LY} D-Glucose {} {} {} {} {} {} {} {} {} {} {} {LY} D-Glucose {} {} {} {} {} {} {} {} {} {} {} {} {LY} D-Glucose {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} D-Glucose {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} D-Glucose {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} D-Glucose {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} D-Glucose {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} D-Glucose {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} D-Glucose {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID107526
Beilstein Registry Number1724615
EC Number200-075-1
Merck Number4459
Chemical Name TranslationD-(+)-葡萄糖
InChIKeyGZCGUPFRVQAUEE-SLPGGIOYSA-N
Wiswesser Line NotationT6OTJ BQ CQ DQ EQ F1Q -D,GLU
Reaxys-RN1281604
LabNetwork Molecule IDLN00196767
InChIInChI=1S/C6H12O6/c7-1-3(9)5(11)6(12)4(10)2-8/h1,3-6,8-12H,2H2/t3-,4+,5+,6+/m0/s1
Canonical SMILESO=C[C@@H]([C@H]([C@@H]([C@@H](CO)O)O)O)O
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分类

  • {SNA} Analytical Standards, Carbohydrates, Chromatography, Food & Beverage Standards, Monosaccharides, Neat Components, Pharmaceutical Secondary Standards, Pharmaceutical Standards, 分析/色谱
  • {SNA} Bioactive Small Molecules, Cell Biology, Cell Culture, G,
  • {SNA} Acacia,
  • {SNA} Carbohydrate Chemistry,

产品应用

  • A primary source of energy for living organisms

相关文献及参考

  • Merck: 14,4459
  • Ono, A., Separation behaviour of some isomeric organic compounds on sugars, sugar alcohols and their mixed phases by gas-liquid chromatography. J. Chromatogr. 197 , 251, (1980)
  • [1]. Jin Jiaojiao, et al. D-glucose, D-galactose, and D-lactose non-enzyme quantitative and qualitative analysis method based on Cu foam electrode. Food Chem. 2015 May 15;175:485-93.

安全信息

Personal Protective Equipment Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US) Eyeshields, Gloves, half-mask respirator (EU), half-mask respirator (US), multi-purpose combination respirator cartridge (US) Eyeshields, Gloves Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
RTECSLZ6600000
WGK Germany1
GHS Symbol
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
Precautionary statements
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Codes Xi
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 15400 gm/kg/22W-C
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Tumorigenic - tumors at site of application
REFERENCE :
   GANNA2 Gann.  Japanese Journal of Cancer Research.  (Tokyo, Japan)  V.1-75,
   1907-84.  For publisher information, see JJCREP.  Volume(issue)/page/year:
   30,419,1936

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 25800 mg/kg
TOXIC EFFECTS :
   Behavioral - coma
   Lungs, Thorax, or Respiration - cyanosis
   Gastrointestinal - hypermotility, diarrhea
REFERENCE :
   85AIAL "Toxicity of Pure Foods," Boyd, E.M., Cleveland, OH, CRC Press, 1973
   Volume(issue)/page/year: -,39,1973

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 20 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HBTXAC "Handbook of Toxicology," 4 vols., Philadelphia, W.B. Saunders Co.,
   1956-59  Volume(issue)/page/year: 1,150,1955

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 18 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PSEBAA Proceedings of the Society for Experimental Biology and Medicine.
   (Academic Press, Inc., 1 E. First St., Duluth, MN 55802)  V.1-    1903/04-
   Volume(issue)/page/year: 35,98,1936

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 9 gm/kg
TOXIC EFFECTS :
   Details of toxic

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 12 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HBTXAC "Handbook of Toxicology," 4 vols., Philadelphia, W.B. Saunders Co.,
   1956-59  Volume(issue)/page/year:

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 179 mmol/L
REFERENCE :
   MUTAEX Mutagenesis. (Oxford Univ. Press, Pinkhill House, Southfield Road,
   Eynsham, Oxford OX8 1JJ, UK) V.1- 1986-  Volume(issue)/page/year: 3,193,1988

TYPE OF TEST            : DNA damage
TEST SYSTEM             : Microorganism - not otherwise specified
DOSE/DURATION           : 150 mmol/L
REFERENCE :
   PNASA6 Proceedings of the National Academy of Sciences of the United States
   of America.  (National Academy of Sciences, Printing & Pub. Office, 2101
   Constitution Ave., Washington, DC 20418) V.1-    1915-
   Volume(issue)/page/year: 81,105,1984

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 25 mg/plate
REFERENCE :
   NARHAD Nucleic Acids Research. (Oxford Univ. Press, Pinkhill House,
   Southfield Road, Eynsham, Oxford OX8 1JJ, UK)  V.1-  1974-
   Volume(issue)/page/year: 12,2127,1984

TYPE OF TEST            : DNA damage
TEST SYSTEM             : Human Cells - not otherwise specified
DOSE/DURATION           : 30 mmol/L
REFERENCE :
   JCINAO Journal of Clinical Investigation.  (Rockefeller Univ. Press, 1230
   York Ave., New York, NY 10021)  V.1-    1924-  Volume(issue)/page/year:
   77,322,1986

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Microorganism - not otherwise specified
DOSE/DURATION           : 1 mol/L
REFERENCE :
   ARMKA7 Archiv fuer Mikrobiologie.  (Berlin, Fed. Rep. Ger.)  V.1-94,
   1930-73.  For publisher information, see AMICCW.  Volume(issue)/page/year:
   91,305,1973

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - hamster
DOSE                    : 20 gm/kg
SEX/DURATION            : female 6-8 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - eye/ear
REFERENCE :
   TJADAB Teratology, The International Journal of Abnormal Development. (Alan
   R. Liss, Inc., 41 E. 11th St., New York, NY 10003)  V.1-    1968-
   Volume(issue)/page/year: 33,74C,1986

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Human - woman
DOSE                    : 2 gm/kg
SEX/DURATION            : female 28 week(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - craniofacial
   (including nose and tongue)
   Reproductive - Specific Developmental Abnormalities - other developmental
   abnormalities
REFERENCE :
   NEJMAG New England Journal of Medicine.  (Massachusetts Medical Soc., 10
   Shattuck St., Boston, MA 02115)  V.198-    1928-  Volume(issue)/page/year:
   315,989,1986

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Multiple routes
SPECIES OBSERVED        : Rodent - hamster
DOSE                    : 20 mg/kg
SEX/DURATION            : female 6-8 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
   Reproductive - Specific Developmental Abnormalities - urogenital system
REFERENCE :
   TJADAB Teratology, The International Journal of Abnormal Development. (Alan
   R. Liss, Inc., 41 E. 11th St., New York, NY 10003)  V.1-    1968-
   Volume(issue)/page/year: 44,193,1991

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES O

Restrict -

其他信息

  • MOL 文件:492-62-6.mol
  • a-无水葡萄糖酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 170080250 a-无水葡萄糖酯 alpha-D(+)-Glucose 99+%, anhydrous 25 KG 4584元 2010/06/21 170080010 a-无水葡萄糖酯 alpha-D(+)-Glucose 99+%, anhydrous 1 KG 388元 2010/06/21 170080025 a-无水葡萄糖酯 alpha-D(+)-Glucose 99+%, anhydrous 2.5 KG 822元
  • Sigma Aldrich:492-62-6(sigmaaldrich)
  • 下游产品:D-(-)-果糖 --> 麦芽糖醇 --> 4,6-亚乙基-alpha-D-葡萄糖
  • F:3
  • 用途一:用作糖果等糖食品的基本配料和各种相关食品、饮料的甜味剂
  • 用途二:医药上可配成口服液或静脉注射液作为营养补给,食品工业用作甜味料
  • 检测方法:HPLC
  • 方法一:由食用玉米淀粉用食品级酸和/或酶部分水解后所得的糖类水溶液,经净化、浓缩而成。由于水解程度的不同,所含D-葡萄糖的量,可相差很大。由玉米淀粉制得者,示称“玉米糖浆”。
  • 上游原料:淀粉
  • D(+)Glucose, Anhydrous is a granular monosaccharide.
  • 用途三:营养性甜味剂。
  • Acros Organics:alpha-D-葡萄糖 alpha-D(+)-Glucose, anhydrous, 99+%(492-62-6)
  • 味甜,易溶于水,微溶于醇和丙酮,不溶于醚。甜度是蔗糖的0.74倍。1g溶于约1ml水,约60ml乙醇。

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