(S)-(+)-Methoxyphenylacetic acid (S)-(+)-Α-甲氧基苯基乙酸

CAS 26164-26-1 MFCD00064216

化学结构图

26164-26-1
SMILES: CO[C@H](C(O)=O)C1C=CC=CC=1

化学属性

Mol. FormulaC9H10O3
Mol. Weight166
Melting Point64-66
TSCANo
Boiling Point130°C/0.7mmHg(lit.)
Density1.422

别名和识别编码

Chemical Name(S)-(+)-Methoxyphenylacetic acid
CAS Number26164-26-1
Synonym (S)-(+)-O-Methylmandelic Acid (S)-(+)-α-甲氧基苯乙酸 (S)-2-Methoxy-2-(phenyl)ethanoic Acid ?-Methoxy-benzeneacetic Acid L-?-Methoxyphenylacetic Acid O-Methyl-L-mandelic acid O-甲基-L-扁桃酸
MDL NumberMFCD00064216
Beilstein Registry Number2361718
EC Number247-492-5
PubChem Substance ID87572827
Reaxys-RN2209197
Chemical Name Translation(S)-(+)-Α-甲氧基苯基乙酸
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分类

  • Chiral Reagents
  • {SNA} Asymmetric Synthesis, Carboxylic Acids, Chemical Synthesis, Chiral Building Blocks, Chiral Resolution Reagents, Chiral Resolving Reagents, Organic Building Blocks
  • {SNA} Chiral, Chiral Derivatization Reagents, Chiral LC Derivatization Reagents, Derivatization Reagents, Derivatization Reagents HPLC, 分析/色谱, 分析试剂
  • {SNA} Analytical Reagents, Analytical/Chromatography, Chiral, Chiral Derivatization Reagents, Chiral LC Derivatization Reagents, Derivatization Reagents, Derivatization Reagents HPLC

相关文献及参考

  • With chiral amines, forms diastereomeric amides which have been used to establish absolute configuration by 1 H NMR: J. Org. Chem., 59, 4202 (1994); 60, 1538 (1995).

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Hazard Codes Xi

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Chiral Derivatization Reagents - Derivatization Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Resolution Reagents - Asymmetric Synthesis
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Derivatization Reagents HPLC - Derivatization Reagents
  5. Chiral - Derivatization Reagents HPLC
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Resolution Reagents - Asymmetric Synthesis
  4. Chiral Resolving Reagents - Chiral Resolution Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Carboxylic Acids - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Aromatic acids
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  1. Analytical & Chromatography 分析化学与色谱
  2. HPLC
  3. Derivatization Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carboxylic Acid Salts 羧酸盐
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents HPLC
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Chiral Derivatization
  4. Chiral GC Derivatization Reagents

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