Dimethyl L-(+)-Tartrate L-(+)-酒石酸二甲酯

CAS 608-68-4 MFCD00064437

化学结构图

608-68-4
SMILES: COC(=O)[C@H](O)[C@@H](O)C(=O)OC

化学属性

Mol. FormulaC6H10O6
Mol. Weight178.14
Density1.238
Boiling Point163 °C at 23 mmHg
Melting Point58 °C
Flash Point>170°(338°F)
TSCAYes
Refractive index21 ° (C=2.5, H2O)

别名和识别编码

Chemical NameDimethyl L-(+)-Tartrate
Synonym L-(+)-Tartaric acid dimethyl ester {LY} L-(+)-Tartaric acid dimethyl ester {} {LY} L-(+)-Tartaric acid dimethyl ester {} {} {LY} L-(+)-Tartaric acid dimethyl ester {} {} {} {LY} L-(+)-Tartaric acid dimethyl ester {} {} {} {} {LY} L-(+)-Tartaric acid dimethyl ester {} {} {} {} {} {LY} L-(+)-Tartaric acid dimethyl ester {} {} {} {} {} {} {LY} L-(+)-Tartaric acid dimethyl ester {} {} {} {} {} {} {} {LY} L-(+)-Tartaric acid dimethyl ester {} {} {} {} {} {} {} {} {LY} L-(+)-Tartaric acid dimethyl ester {} {} {} {} {} {} {} {} {} {LY} L-(+)-Tartaric acid dimethyl ester {} {} {} {} {} {} {} {} {} {} {LY} L-(+)-Tartaric acid dimethyl ester {} {} {} {} {} {} {} {} {} {} {} {LY} L-(+)-Tartaric acid dimethyl ester {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-(+)-Tartaric acid dimethyl ester {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-(+)-Tartaric acid dimethyl ester {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Beilstein Registry Number1726253
PubChem Substance ID87576032
CAS Number608-68-4
EC Number210-166-8
MDL NumberMFCD00064437
Reaxys-RN1726253
Chemical Name TranslationL-(+)-酒石酸二甲酯
InChIKeyPVRATXCXJDHJJN-QWWZWVQMSA-N
LabNetwork Molecule IDLN00153964
Canonical SMILESO=C([C@H](O)[C@@H](O)C(OC)=O)OC
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分类

  • {uni_hamburg} no charge; ester; alcohol; chiral; 1fragment
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Catalysts, Ligands, and Reagents, Epoxidation, Esters, Organic Building Blocks
  • Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Catalysts, Ligands, and Reagents, Epoxidation, Esters, Organic Building Blocks

相关文献及参考

  • Short: IV/18B
  • Short: IV/1b
  • Short: EINECS
  • Has been used in Sharpless epoxidation of allylic alcohols; see tert-Butyl­ hydroperoxide, A13926.
  • Cyclic ketals formed with dimethyl tartrate as the diol component undergo highly selective bromination: Angew. Chem. Int. Ed., 25, 259 (1986).

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word Warning
GHS Symbol
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • L-(+)-酒石酸二甲酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0006 L-(+) -酒石酸二甲酯 Dimethyl L-(+)-Tartrate 25G 247元 2010/06/21 172490250 L-(+)-酒石酸二甲酯 (+)-Dimethyl L-tartrate 99% 25 GR 322元 2010/06/21 172491000 L-(+)-酒石酸二甲酯 (+)-Dimethyl L-tartrate 99% 100 GR 879元
  • 海关编码:29181300
  • Acros Organics:L-酒石酸二甲酯 (+)-Dimethyl L-tartrate, 99%(608-68-4)
  • MSDS 信息:L-(+)-Tartaric acid dimethyl ester(608-68-4).msds
  • TCI Shanghai:L-(+) -酒石酸二甲酯 Dimethyl L-(+)-Tartrate,>;98.0%(GC)(608-68-4)
  • 用途一:主要用于手性药物、手性中间体的合成及不对称催化领域
  • Sigma Aldrich:608-68-4(sigmaaldrich)
  • MOL 文件:608-68-4.mol
  • Alfa Aesar:L-(+)酒石酸二甲酯,99% Dimethyl L-tartrate, 99%(608-68-4)
  • 图谱信息:L-(+)-酒石酸二甲酯(608-68-4)核磁图( 13 CNMR) L-(+)-酒石酸二甲酯(608-68-4)红外图谱(IR2) L-(+)-酒石酸二甲酯(608-68-4)红外图谱(IR3) L-(+)-酒石酸二甲酯(608-68-4)红外图谱(IR1) L-(+)-酒石酸二甲酯(608-68-4)Raman光谱 L-(+)-酒石酸二甲酯(608-68-4)核磁图( 1 HNMR) L-(+)-酒石酸二甲酯(608-68-4)质谱(MS)
  • 比旋光度:21 ° (c=10, H2O)
  • 下游产品:

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Deprotonation - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Epoxidation - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Carboxylic Acids - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Esters - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Epoxides 环氧化物

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