(2S)-(+)-Glycidyl tosylate (2S)-(+)-缩水甘油基对甲苯磺酸酯
CAS 70987-78-9 MFCD00064489
化学结构图
SMILES: CC1=CC=C(C=C1)S(=O)(=O)OC[C@@H]1CO1
化学属性
| Mol. Formula | C10H12O4S |
|---|---|
| Mol. Weight | 228 |
| Melting Point | 46-49 |
| Flash Point | 113°(235°F) |
| TSCA | No |
| Density | 1.31 |
别名和识别编码
| Chemical Name | (2S)-(+)-Glycidyl tosylate |
|---|---|
| CAS Number | 70987-78-9 |
| Synonym | (2S)-(+)-Glycidyl tosylate (2S)-(+)-缩水甘油对甲苯磺酸酯 (S)-(+)-Glycidyl p-toluenesulfonate, (S)-(+)-Oxirane-2-methanol p-toluenesulfonate (S)-(+)-对甲苯磺酸缩水甘油酯 (S)-(+)-对甲苯磺酸缩水甘油酯 (S)-(+)-环氧乙烷-2-甲醇对甲苯磺酸酯 |
| PubChem Substance ID | 24878443 |
| EC Number | 417-210-7 |
| Beilstein Registry Number | 3592143 |
| MDL Number | MFCD00064489 |
| Reaxys-RN | 3592143 |
| Chemical Name Translation | (2S)-(+)-缩水甘油基对甲苯磺酸酯 |
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分类
- Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Epoxides, Organic Building Blocks
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Epoxides, Organic Building Blocks
产品应用
- Protected Glycidol, used as an intermediate in the preparation of neurochemicals.
相关文献及参考
- Beilstein:17(5)3,47
- Qian, L., et al.: ChemMedChem, 1, 376 (2006),
- Wang, J., et al.: J. Med. Chem., 48, 6271 (2005),
安全信息
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H350 May cause cancer 可能致癌
- H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
- H317 May cause an allergic skin reaction 可能导致皮肤过敏
- H318 Causes serious eye damage 严重伤害眼睛
- H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P350
- P302+P352+P333+P313+P362+P364
- P305+P351+P338
- P305+P351+P338+P310
- P308+P313
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
- R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
- R45 May cause cancer 可能致癌
- R51/53
- R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
TYPE OF TEST : Mutation test systems - not otherwise specified ROUTE OF EXPOSURE : Intraperitoneal TEST SYSTEM : Rodent - mouse DOSE/DURATION : 100 mg/kg REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 298,197,1993
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Bacteria - Salmonella typhimurium DOSE/DURATION : 100 nmol/plate REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 298,197,1993
TYPE OF TEST : Cytogenetic analysis ROUTE OF EXPOSURE : Intraperitoneal TEST SYSTEM : Rodent - mouse DOSE/DURATION : 100 mg/kg REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 298,197,1993
TYPE OF TEST : Sister chromatid exchange ROUTE OF EXPOSURE : Intraperitoneal TEST SYSTEM : Rodent - mouse DOSE/DURATION : 100 mg/kg REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 298,197,1993
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