Tetrabutylammonium phosphate monobasic 四丁基磷酸氢铵

CAS 5574-97-0 MFCD00064526

化学结构图

5574-97-0
SMILES: CCCC[N+](CCCC)(CCCC)CCCC.O=P([O-])(O)O

化学属性

Mol. FormulaC16H38NO4P
Mol. Weight339.45
TSCAYes
Melting Point151-154 °C
SolubilitySoluble in acetonitrile, ethanol, water
Density1.037 g/mL at 25 °C
Boiling Point81-82 °C at 760 mmHg
Refractive indexn20/D 1.369
Flash Point43 °F
Stability易吸潮

别名和识别编码

Chemical NameTetrabutylammonium phosphate monobasic
Synonym Tetrabutylammonium Phosphate,for IPC,≥99% {LY} Tetrabutylammonium Phosphate,for IPC,≥99% {} {LY} Tetrabutylammonium Phosphate,for IPC,≥99% {} {} {LY} Tetrabutylammonium Phosphate,for IPC,≥99% {} {} {} {LY} Tetrabutylammonium Phosphate,for IPC,≥99% {} {} {} {} {LY} Tetrabutylammonium Phosphate,for IPC,≥99% {} {} {} {} {} {LY} Tetrabutylammonium Phosphate,for IPC,≥99% {} {} {} {} {} {} {LY} Tetrabutylammonium Phosphate,for IPC,≥99% {} {} {} {} {} {} {} {LY} Tetrabutylammonium Phosphate,for IPC,≥99% {} {} {} {} {} {} {} {} {LY} Tetrabutylammonium Phosphate,for IPC,≥99% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrabutylammonium Phosphate,for IPC,≥99% {} {} {} {} {} {} {} {} {} {} {LY} Tetrabutylammonium Phosphate,for IPC,≥99% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrabutylammonium Phosphate,for IPC,≥99% {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrabutylammonium Phosphate,for IPC,≥99% {} {} {} {} {} {} {} {} {} {}
Beilstein Registry Number5196532
PubChem Substance ID2735142
CAS Number5574-97-0
EC Number226-947-1
MDL NumberMFCD00064526
Reaxys-RN5196532
Chemical Name Translation四丁基磷酸氢铵
InChIKeyARRNBPCNZJXHRJ-UHFFFAOYSA-M
LabNetwork Molecule IDLN02220052
InChIInChI=1S/C16H36N.H3O4P/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-5(2,3)4/h5-16H2,1-4H3;(H3,1,2,3,4)/q+1;/p-1
Canonical SMILESCCCC[N+](CCCC)(CCCC)CCCC.O=P(O)([O-])O
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分类

  • Acidic Ion Pair Reagents (Anionic), Analytical Reagents, Analytical/Chromatography, Buffers & Reagents, Chromatography Reagents & Solvents, HPLC, Ion Pair Reagents, Ion Pair Reagents - Anionic
  • {SNA} Ammonium Salts, Chemical Synthesis, Phase Transfer Catalysts, Synthetic Reagents
  • {SNA} Acidic Ion Pair Reagents (Anionic), Buffers & Reagents, Chromatography Reagents & Solvents, HPLC, Ion Pair Reagents, Ion Pair Reagents - Anionic, 分析/色谱, 分析试剂

产品应用

  • 离子对色谱试剂。

相关文献及参考

  • 1. W.E. Ladner, G.M. Whitesides J. Org. Chem. 50 , 1076, (1985)
  • 2. C.F. Harrington et al. J. Liq. Chromatogr. Relat. Technol 20 , 1773, (1997)
  • 3. K. Makino et al. J. Chromatogr. 400 , 271, (1987) 摘要
  • Corp MSDS 1 (2), 3236:D / RegBook 1 (1), 415:A / Structure Index 1 , 60:D:5

安全信息

Signal word Danger
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H332 Harmful if inhaled 吸入有害
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H302+H332
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P332+P313
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P305+P351+P338
  • P302+P350
  • P337+P313
  • P305+P351+P338+P337+P313
  • P302+P352+P332+P313+P362+P364
Safety Statements
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US) Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter Eyeshields, Gloves, half-mask respirator (EU), half-mask respirator (US), multi-purpose combination respirator cartridge (US)
GHS Symbol
Hazard Codes Xn F,Xn
Storage condition Store at room temperature, keep dry and cool {LY} Store at room temperature, keep dry and cool {} {LY} Store at room temperature, keep dry and cool {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store
UN Number UN 1648 3/PG 2

其他信息

  • 用途一:离子对色谱试剂。
  • 四丁基磷酸氢铵价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 K8683301 四丁基磷酸二氢铵;磷酸二氢四丁铵;磷酸四丁铵 5g 1987元 2011/04/16 I0367 四丁基磷酸氢铵(0.5mol/L的水溶液)[离子对色谱用试剂] Tetrabutylammonium Phosphate (0.5mol/L in Water) [Reagent for Ion-Pair Chromatography] 10ML 350元 2011/04/16 I0367 四丁基磷酸氢铵(0.5mol/L的水溶液)[离子对色谱用试剂] Tetrabutylammonium Phosphate (0.5mol/L in Water) [Reagent for Ion-Pair Chromatography] 100ML 1940元
  • MSDS 信息:Tetrabutylammonium phosphate(5574-97-0).msds
  • 溶解于水
  • 存储注意事项:空气敏感;光敏感
  • Acros Organics:四丁基磷酸铵(HPLC)/四丁基磷酸二氢铵 Tetrabutylammonium phosphate, HPLC grade, 99%(5574-97-0)
  • MOL 文件:5574-97-0.mol
  • 上游原料:磷酸 --> 四丁基氢氧化铵
  • TCI Shanghai:四丁基磷酸氢铵(0.5mol/L的水溶液)[离子对色谱用试剂] Tetrabutylammonium Phosphate (0.5mol/L in Water) [Reagent for Ion-Pair Chromatography](5574-97-0)
  • F:8-10-23
  • Alfa Aesar:四正丁基磷酸铵,99+% Tetra-n-butylammonium phosphate, 99+%(5574-97-0)
  • Sigma Aldrich:5574-97-0(sigmaaldrich)

系列性分类


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