Bis(2,2,6,6-Tetramethyl-3,5-Heptanedionato)Calcium(II) 双(2,2,6,6-四甲基-3,5-庚二酮)钙

CAS 118448-18-3 MFCD00064757

化学结构图

118448-18-3
SMILES:

化学属性

Mol. FormulaCa(C11H19O2)2
Mol. Weight406.61
Melting Point220-223 °C
TSCANo
Boiling Point205°/0.1mm subl.
Appearance white pwdr.

别名和识别编码

Chemical NameBis(2,2,6,6-Tetramethyl-3,5-Heptanedionato)Calcium(II)
Synonym 双(2,2,6,6-四甲基-3,5-庚二酸)钙 (Ca(TMHD)2) 3,5-Heptanedione, 2,2,6,6-tetramethyl-, ion(1-), calcium Bis(tetramethylheptanedionato)calcium Ca(TMHD)2 Bis(2,2,6,6-tetramethyl-3,5-heptanedionato-κO,κO')calcium Calcium(2+), bis(2,2,6,6-tetramethyl-3,5-heptanedione-O3,O5)-, (T-4)- Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)calcium (II) Calcium-DPM Bis(dipivaloylmethanato)calcium Calcium bis(dipivaloylmethanate) 双(2,2,6,6-四甲基-3,5-庚二酮酸)钙 Calcium(2+), bis(2,2,6,6-tetramethyl-3,5-heptanedione-kO,kO')-, (T-4)- (Ca(TMHD)2) Calcium bis(dipivaloylmethanate) Calcium dipivaloylmethanate Calcium bis(2,2,6,6-tetramethyl-3,5-heptanedionate)
MDL NumberMFCD00064757
PubChem Substance ID329762183
CAS Number118448-18-3
Chemical Name Translation双(2,2,6,6-四甲基-3,5-庚二酮)钙
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分类

  • {SNA} Calcium, Catalysis and Inorganic Chemistry, Chemical Synthesis
  • {SA} CVD and ALD Precursors by Metal, Calcium, Materials Science, Micro/NanoElectronics, Vapor Deposition Precursors
  • {SNA} CVD and ALD Precursors by Metal, Calcium, Micro/NanoElectronics, Vapor Deposition Precursors, 材料科学
  • {SNA} Calcium Catalysts, Catalysis and Inorganic Chemistry, Chemical Synthesis

相关文献及参考

  • 1. Aldrichimica Acta 23 , 54, (1990)
  • FT-IR 2 (3), 4530:A / FT-NMR 1 (3), 755:A / RegBook 1 (2), 3091:D / Structure Index 1 , 489:D:8
  • Short: II/2 Title: Magnetic Properties of Coordination and Organometallic Transition Metal Compounds Author: König, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/2 Year: 1966 ISBN: 3-540-03593-1 ISBN: 978-3-540-03593-0 Internet Resource: DOI:10.1007/b19948 RefComment: 170 figs., XII, 578 pages. Hardcover Abstract: The data compiled refer to susceptibility measurements (susceptibility, Curie-constants, magnetic moments, transition temperatures) and ESR-measurements (g-factors and other parameters of the applied spin Hamiltonian). In volume II/2 the literature from 1899 up to 1964 has been considered. Volume II/8 supplements volume II/2, taking into account the data on magnetic susceptibilities and ESR parameters published in the p eriod 1964 to 1968. The following subvolumes II/10,II/11, II/12 supplement data up to 1974.

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Signal word Warning
Storage condition Hygroscopic
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类


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