Silver Mesylate 甲烷磺酸银

CAS 2386-52-9 MFCD00064795

化学结构图

2386-52-9
SMILES: CS(=O)(=O)[O-].[Ag+]

化学属性

Mol. FormulaCH4AgO3S
Mol. Weight203.97
TSCAYes
Melting Point252-256 °C
Stability对光敏感

别名和识别编码

Chemical NameSilver Mesylate
MDL NumberMFCD00064795
CAS Number2386-52-9
EC Number219-199-2
Synonym Silver methanesulfonate {LY} Silver methanesulfonate {} {LY} Silver methanesulfonate {} {} {LY} Silver methanesulfonate {} {} {} {LY} Silver methanesulfonate {} {} {} {} {LY} Silver methanesulfonate {} {} {} {} {} {LY} Silver methanesulfonate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Silver methanesulfonate {} {} {} {} {} {} {} {LY} Silver methanesulfonate {} {} {} {} {} {} {} {} {LY} Silver methanesulfonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Silver methanesulfonate {} {} {} {} {} {} {} {} {} {} {LY} Silver methanesulfonate {} {} {} {} {} {} {} {} {} {} {} {LY} Silver methanesulfonate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Silver methanesulfonate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Silver methanesulfonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Silver methanesulfonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Silver methanesulfonate {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID159658
Chemical Name Translation甲烷磺酸银
InChIKeyMLKQJVFHEUORBO-UHFFFAOYSA-M
Wiswesser Line NotationWS1&O &-AG- &9/5
LabNetwork Molecule IDLN00224085
InChIInChI=1S/CH4O3S.Ag/c1-5(2,3)4;/h1H3,(H,2,3,4);/q;+1/p-1
Canonical SMILESCS(=O)(O)=O.[Ag]
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Silver, Silver Additives, Silver Complexes
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Silver Additives, Silver Catalysts, Silver Complexes

产品应用

  • Gold Catalysts-21st Century'Gold Rush'
  • Catalyst for:
  • .Heterocyclization reactions
  • . CO2-mediated rearrangement of propargyl alcohols for the synthesis of a,?-unsaturated ketones and esters

安全信息

RTECSPB2685000
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Packing GroupIII
UN Number UN3077 1759
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr
Hazard Codes Xn Xi Xi,Xn
WGK Germany3
GHS Symbol
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P330+P331
  • P302+P352
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P333+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Class8
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 18 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#00622

其他信息

  • Sigma Aldrich:2386-52-9(sigmaaldrich)
  • MSDS 信息:Silver mesylate(2386-52-9).msds
  • 甲烷磺酸银价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 419340250 甲烷磺酸银 Methanesulfonic acid, silver salt 99% 25 GR 1849元 2010/06/21 419340050 甲烷磺酸银 Methanesulfonic acid, silver salt 99% 5 GR 537元 2010/05/25 18641 甲烷磺酸银 Silver methanesulfonate 50g 7028元
  • Alfa Aesar:甲烷磺酸银 Silver methanesulfonate(2386-52-9)
  • MOL 文件:2386-52-9.mol
  • Acros Organics:甲基磺酸银 Methanesulfonic acid, silver salt, 99%(2386-52-9)

系列性分类


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