6-Oxa-3-thiabicyclo[3.1.0]hexane 3,3-dioxide 3,4-环氧四氢噻吩-1,1-二氧化物

CAS 4509-11-9 MFCD00065014

化学结构图

4509-11-9
SMILES: O=S1(=O)CC2OC2C1

化学属性

Mol. FormulaC4H6O3S
Mol. Weight134.15364
Melting Point145-150 °C(lit.)

别名和识别编码

Chemical Name6-Oxa-3-Thiabicyclo[3.1.0]Hexane 3,3-Dioxide
MDL NumberMFCD00065014
PubChem Substance ID20597
CAS Number4509-11-9
EC Number224-827-3
Synonym 3,4-Epoxytetrahydrothiophene-1,1-dioxide {LY} 3,4-Epoxytetrahydrothiophene-1,1-dioxide {} {LY} 3,4-Epoxytetrahydrothiophene-1,1-dioxide {} {} {LY} 3,4-Epoxytetrahydrothiophene-1,1-dioxide {} {} {} {LY} 3,4-Epoxytetrahydrothiophene-1,1-dioxide {} {} {} {} {LY} 3,4-Epoxytetrahydrothiophene-1,1-dioxide {} {} {} {} {} {LY} 3,4-Epoxytetrahydrothiophene-1,1-dioxide {} {} {} {} {} {} {LY} 3,4-Epoxytetrahydrothiophene-1,1-dioxide {} {} {} {} {} {} {} {LY} 3,4-Epoxytetrahydrothiophene-1,1-dioxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3,4-Epoxytetrahydrothiophene-1,1-dioxide {} {} {} {} {} {} {} {} {} {LY} 3,4-Epoxytetrahydrothiophene-1,1-dioxide {} {} {} {} {} {} {} {} {} {} {LY} 3,4-Epoxytetrahydrothiophene-1,1-dioxide {} {} {} {} {} {} {} {} {} {} {} {LY} 3,4-Epoxytetrahydrothiophene-1,1-dioxide {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3,4-Epoxytetrahydrothiophene-1,1-dioxide {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3,4-Epoxytetrahydrothiophene-1,1-diox
Chemical Name Translation3,4-环氧四氢噻吩-1,1-二氧化物
InChIKeySZAIAWVGWTXVMB-UHFFFAOYSA-N
Wiswesser Line NotationT35 BO ESWTJ
Beilstein Registry Number0113462
LabNetwork Molecule IDLN00603693
InChIInChI=1S/C4H6O3S/c5-8(6)1-3-4(2-8)7-3/h3-4H,1-2H2
Canonical SMILESO=S1(CC2C(O2)C1)=O
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Epoxides, Organic Building Blocks, Oxygen Compounds
  • {SNA} Epoxide Monomers, Monomers, Polymer Science, 材料科学
  • {SNA} Epoxide Monomers, Materials Science, Monomers, Polymer Science
  • {uni_hamburg} no charge; oxygen heterocycle; sulfur heterocycle; alicycle; fused rings; 3ring; 5ring; 6ring; ether; sulfone; racemate; 1fragment

相关文献及参考

  • 1. J. Chem. Soc. Perkin Trans. I , 1335, (1972)
  • 2. J. Chem. Soc., Chem. Commun. , 114, (1991)
  • 3. Tetrahedron Lett. , 2609, (1971)
  • Beil. 19 ,IV,111
  • FT-IR 2 (1), 1498:B / FT-NMR 1 (1), 1423:B / IR-Spectra (2), 471:D / IR-Spectra (3), 531:E / RegBook 1 (1), 1045:L / Sax 6 , 1291 / Structure Index 1 , 162:B:7
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
  • Short: III/10a Title: Structure Data of Organic Crystals: C ... C 15 Author: Schudt-Weitz, G.; Strell, I. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/10a Year: 1985 ISBN: 3-540-07834-7 ISBN: 978-3-540-07834-0 Internet Resource: DOI:10.1007/b19984 RefComment: XXII, 634 pages. Hardcover Abstract: The volume includes an alphabetical index of all substances and a separate "ring index" with all cyclic compounds.

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P302+P352
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H302+H312+H332
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xn
RTECSRP3850000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 88 mg/kg/22W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Tumorigenic - tumors at site of application
REFERENCE :
   JNCIAM Journal of the National Cancer Institute.  (Washington, DC)  V.1-60,
   1940-78.  For publisher information, see JJIND8.  Volume(issue)/page/year:
   46,143,1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 5500 mg/kg
TOXIC EFFECTS :
   Biochemical - Metabolism (Intermediary) - effect on inflammation or
   mediation of inflammation
REFERENCE :
   RPTOAN Russian Pharmacology and Toxicology (English Translation).
   Translation of FATOAO.  (Euromed Pub., 33, Woodlands Rd., Surbiton, Surrey,
   UK)  V.30-    1967-  Volume(issue)/page/year: 41,257,1978

Storage condition

系列性分类

  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Monomers - Polymer Science
  4. Epoxide Monomers - Monomers
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Epoxides - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Epoxides - Oxygen Compounds

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