Methyltriphenylphosphonium iodide 甲基三苯基碘化磷

CAS 2065-66-9 MFCD00066175

化学结构图

2065-66-9
SMILES: C[P+](c1ccccc1)(c1ccccc1)c1ccccc1.[I-]

化学属性

Mol. FormulaC19H18IP
Mol. Weight404.22
Melting Point183-185°C
Density1.422
TSCANo
Solubility可溶
Stability对光敏感

别名和识别编码

Chemical Name(Methyl)triphenylphosphonium Iodide
MDL NumberMFCD00066175
PubChem Substance ID638159
CAS Number2065-66-9
EC Number218-178-5
Reaxys-RN3599430
Beilstein Registry Number2384789
Synonym Methyltriphenylphosphonium iodide {LY} Methyltriphenylphosphonium iodide {} {LY} Methyltriphenylphosphonium iodide {} {} {LY} Methyltriphenylphosphonium iodide {} {} {} {LY} Methyltriphenylphosphonium iodide {} {} {} {} {LY} Methyltriphenylphosphonium iodide {} {} {} {} {} {LY} Methyltriphenylphosphonium iodide {} {} {} {} {} {} {LY} Methyltriphenylphosphonium iodide {} {} {} {} {} {} {} {LY} Methyltriphenylphosphonium iodide {} {} {} {} {} {} {} {} {LY} Methyltriphenylphosphonium iodide {} {} {} {} {} {} {} {} {} {LY} Methyltriphenylphosphonium iodide {} {} {} {} {} {} {} {} {} {} {LY} Methyltriphenylphosphonium iodide {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Methyltriphenylphosphonium iodide {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyltriphenylphosphonium iodide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyltriphenylphosphonium iodide {} {} {
Chemical Name Translation甲基三苯基碘化磷
LabNetwork Molecule IDLN00188683
InChIKeyJNMIXMFEVJHFNY-UHFFFAOYSA-M
InChIInChI=1S/C19H18P.HI/c1-20(17-11-5-2-6-12-17,18-13-7-3-8-14-18)19-15-9-4-10-16-19;/h2-16H,1H3;1H/q+1;/p-1
Canonical SMILESC[P+](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.[I-]
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分类

  • {SA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents

相关文献及参考

  • 4. S. B. Jones, et al., Nature 475 , 183-188, (2011) 摘要
  • 5. S. Fuku-en, et al., J. Phys. Org. Chem. 24 , 1009-1017, (2011)
  • Beilstein: 16,760
  • Ylide precursor. Effective catalyst for addition of Trimethyl­silyl­ cyanide, A19598 to aldehydes: Tetrahedron Lett., 44, 6157 (2003).

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P316
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi,T T Xi
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Signal word
UN Number UN3464
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Packing GroupIII
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Light Sensitive & Hygroscopic {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C,

其他信息

  • 图谱信息:甲基三苯基碘化(2065-66-9)红外图谱(IR2) 甲基三苯基碘化(2065-66-9)红外图谱(IR1) 甲基三苯基碘化(2065-66-9)核磁图( 13 CNMR) 甲基三苯基碘化(2065-66-9)质谱(MS) 甲基三苯基碘化(2065-66-9)核磁图( 1 HNMR)
  • 用途一:加氢促进剂,环氧树脂硬化促进剂;链烯烃聚合催化剂,聚脲催化剂,加氢重整催化剂等;芳香族聚酯树脂的耐热性改进剂;聚碳酸酯的热稳定剂;塑料加工性能改进剂;脱重油中金属等;橡胶制品相转换剂;长效高效杀虫剂合成的中间体等。
  • Sigma Aldrich:2065-66-9(sigmaaldrich)
  • Alfa Aesar:三苯基甲基碘化磷,98% Methyltriphenylphosphonium iodide, 98%(2065-66-9)
  • Acros Organics:甲基三苯基碘化磷 Methyltriphenylphosphonium iodide, 97%(2065-66-9)
  • 甲基三苯基碘化价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0253 甲基三苯基碘化磷 Methyltriphenylphosphonium Iodide 500G 4790元 2014/06/02 M0253 甲基三苯基碘化磷 Methyltriphenylphosphonium Iodide 25G 568元 2010/06/21 224031000 甲基三苯基碘化 Methyltriphenylphosphonium iodide 97% 100 GR 2462元
  • 敏感性:Light Sensitive & Hygroscopic
  • MOL 文件:2065-66-9.mol
  • TCI Shanghai:甲基三苯基碘化磷 Methyltriphenylphosphonium Iodide,>;98.0%(T)(2065-66-9)
  • MSDS 信息:Methyltriphenylphosphonium iodide(2065-66-9).msds

系列性分类


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