1,8,8-Trimethyl-3-oxabicyclo[3.2.1]octane-2,4-dione (+/-)-无水合成樟脑酸酐

CAS 76-32-4 MFCD00067307

化学结构图

76-32-4
SMILES: CC12CCC(C(=O)OC1=O)C2(C)C

化学属性

Mol. FormulaC10H14O3
Mol. Weight182.22
TSCANo
Boiling Point269-271°
Melting Point222-225 °C
Flash Point269-271°C

别名和识别编码

Chemical Name1,8,8-Trimethyl-3-oxabicyclo[3.2.1]octane-2,4-dione
Synonym {uni_hamburg} 莰二酸酐 (+/-)-CAMPHORIC ANHYDRIDE (±)-1,8,8-三甲基-3-氧杂二环[3.2.1]辛烷-2,4-二酮 (±)-樟脑酸酐,98% 1,8,8-Trimethyl-3-oxabicyclo[3,2,1]octan-2,4-dion 3-oxabicyclo[3.2.1]octane-2,4-dione, 1,8,8-trimethyl-, (±)- 3-Oxabicyclo[3.2.1]octane-2,4-dione, 1,8,8-trimethyl- (±)-camphoric anhydride 樟腦二酸酐 DL-Camphersäureanhydrid (±)-樟脑酸酐 (±)-1,8,8-trimethyl-3-oxabicyclo[3.2.1]octane-2,4-dione DL-Camphoric anhydride DL-CAMPHORIC ANHYDRIDE d-Camphoric anhydride (n)-camphoric anhydride (±)-1,8,8-trimethyl-3-oxabicyclo [3.2.1]octane-2,4-dione 樟脑酸酐 (+/-)-1,8,8-TRIMETHYL-3-OXABICYCLO[3.2.1]OCTANE-2,4-DIONE (+/-)-樟脑酸酐 DL-CAMPHOR ANHYDRIDE 3-oxabicyclo[3.2.1]octane-2,4-dione, 1,8,8-trimethyl- 1,2,2-三甲基环戊酸-1,3-二羧酸酐 3-oxabicyclo[3.2.1]octane-2,4-dione,1,8,8-trimethyl- (±)-Camphoricanhydride,98% 1,8,8-trimethyl-3-oxabicyclo[3.2.1]octane-2,4-dione dl camphoric anhydride (+/-)-CAMPHORIC ACID ANHYDRIDE 1,3-Cyclopentanedicarboxylic anhydride, 1,2,2-trimethyl- 1,8,8-TRIMETHYL-3-OXABICYCLO[3.2.1]OCTANE-2,4-DIONE DL-樟脑酸 (+/-)-无水合成樟脑酸酐 camphoric anhydride 3-oxabicyclo[3.2.1]octane-2,4-dione,1,8,8-trimethyl-,(±)-
MDL NumberMFCD00067307
CAS Number76-32-4
EC Number200-952-9
Beilstein Registry Number6582434
PubChem Substance ID94834
Chemical Name Translation(+/-)-无水合成樟脑酸酐
InChIKeyVFZDNKRDYPTSTP-UHFFFAOYSA-N
InChIInChI=1S/C10H14O3/c1-9(2)6-4-5-10(9,3)8(12)13-7(6)11/h6H,4-5H2,1-3H3
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分类

  • {SNA} Building Blocks, Carbonyl Compounds, Carboxylic Acid Anhydrides, Chemical Synthesis, Organic Building Blocks
  • {uni_hamburg} no charge; oxygen heterocycle; carbocycle; alicycle; large ring; fused rings; 5ring; 6ring; 7ring; carbo-anhydride; racemate; 1fragment

相关文献及参考

  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the Europ
  • Short: II/27B Title: Diamagnetic Susceptibility of Organic Compounds, Oils, Paraffins and Polyethylenes Author: Kumar, M.; Gupta, R. Editor: Gupta, Radha Raman Source: Landolt-Börnstein, New Series Volume: II/27B Year: 2008 Keyword: diamagnetic susceptibility; organic compounds ISBN: 978-3-540-44359-9 (print) ISBN: 978-3-540-45860-9 (online) Internet Resource: doi:10.1007/978-3-540-45860-9 RefComment: VIII, 503 p. With CD-ROM., Hardcover RefComment: Written for: Scientists and researchers in the fields of physics, chemistry, materials science RefComment: Supplement and Revised Editon to II/16 Abstract: The volume II/27 has been divided into three subvolumes according to the classes of compounds: Subvolume A: Diamagnetic susceptibility and magnetic anisotropy of inorganic and organometallic compounds; Subvolume B: Diamagnetic susceptibility of organic compounds, oils, paraffins and polyethylenes; Subvolume C: Diamagnetic susceptibility and magnetic anisotropy of organic compounds. The data presented in this volume are based on the literature survey of the chemical abstracts up to 2005. The calculated values of diamagnetic susceptibility of organic compounds in the present subvolume II/27B are presented along with their experimental values. They have been calculated with the use of structural parameters in structural formula by using different theoretical methods available in the literature.
  • Short: IV/8A Title: Enthalpies of Fusion and Transition of Organic Compounds Author: Zhang, Z.-Y.; Frenkel, M.; March, K.N.; Wilhoit, R.C. Editor: Marsh, K.N. Source: Landolt-Börnstein, New Series Volume: IV/8A Year: 1995 Keyword: organic compounds; enthaly of fusion; melting point; phase transition ISBN: 3-540-58854-X ISBN: 978-3-540-58854-2 Internet Resource: DOI:10.1007/b55145 RefComment: VIII, 588 pages.

安全信息

Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
Storage condition Moisture Sensitive 2-8°C
WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
Signal word Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xn

其他信息

  • Sigma Aldrich:595-30-2(sigmaaldrich)
  • F:10-21
  • DL-樟脑酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 108211000 DL-樟脑酸 DL-Camphoric anhydride 98% 100 GR 1215元 2010/05/25 B23401 (±)-樟脑酸酐,98% (+/-)-Camphoric anhydride, 98% 50g 762元 2010/05/25 B23401 (±)-樟脑酸酐,98% (+/-)-Camphoric anhydride, 98% 25g 449元
  • Alfa Aesar:(±)-樟脑酸酐,98% (+/-)-Camphoric anhydride, 98%(595-30-2)
  • Sigma Aldrich:76-32-4(sigmaaldrich)
  • MOL 文件:595-30-2.mol
  • Acros Organics:DL-樟脑酸 DL-Camphoric anhydride, 98%(595-30-2)
  • MOL 文件:76-32-4.mol
  • 敏感性:Moisture Sensitive

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carboxylic Acid Anhydrides 羧酸酐
  1. Functional Group 官能团索引
  2. carboxylic acid anhydride

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