1-Bromoadamantane 1-溴金刚烷

CAS 768-90-1 MFCD00074721

化学结构图

768-90-1
SMILES: BrC12CC3CC(C1)CC(C2)C3

化学属性

Mol. FormulaC10H15Br
Mol. Weight215.13
Melting Point116-118°C
TSCANo
Boiling Point240.5°C at 760 mmHg

别名和识别编码

Chemical Name1-Bromoadamantane
MDL NumberMFCD00074721
CAS Number768-90-1
Synonym 1-Bromoadamantane {LY} 1-Bromoadamantane {} {LY} 1-Bromoadamantane {} {} {LY} 1-Bromoadamantane {} {} {} {LY} 1-Bromoadamantane {} {} {} {} {LY} 1-Bromoadamantane {} {} {} {} {} {LY} 1-Bromoadamantane {} {} {} {} {} {} {LY} 1-Bromoadamantane {} {} {} {} {} {} {} {LY} 1-Bromoadamantane {} {} {} {} {} {} {} {} {LY} 1-Bromoadamantane {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} 1-Bromoadamantane {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromoadamantane {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromoadamantane {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromoadamantane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromoadamantane {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromoadamantane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromoadamantane {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID87563436
Beilstein Registry Number1098857
EC Number212-200-7
Chemical Name Translation1-溴金刚烷
Reaxys-RN1098857
InChIKeyVQHPRVYDKRESCL-UHFFFAOYSA-N
LabNetwork Molecule IDLN00192527
Canonical SMILESBrC12C[C@H]3C[C@@H](C2)C[C@@H](C1)C3
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分类

  • {SNA} Alkyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks

产品应用

  • 是用于合成一个新的organic-organic纳米复合薄膜介质

相关文献及参考

  • Reduction with Tri-n-butyl­tin hydride, A13298, generates the 1-adamantyl radical which, e.g. adds to Michael acceptors in good yield: J. Org. Chem., 53, 1285 (1988).
  • With activated Ca metal (prepared from CaBr2 and Li biphenylide), forms an organocalcium reagent which reacts with ketones to give tertiary alcohols; the preparation and reactivity of these intermediates is discussed: Org. Synth. Coll., 9, 9 (1998).
  • Undergoes Heck-type coupling with styrenes and arenes, catalyzed by Pd on carbon: Synthesis, 148 (1998).

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
GHS Symbol
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Storage condition 2-8°C {LY} 2-8°C Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°

其他信息

  • MOL 文件:768-90-1.mol
  • TCI Shanghai:1-溴金刚烷 1-Bromoadamantane,>;97.0%(GC)(768-90-1)
  • 上游原料:溴 --> 亚硫酸氢钠溶液 --> 金刚烷
  • 图谱信息:1-溴金刚烷(768-90-1)Raman光谱 1-溴金刚烷(768-90-1)质谱(MS) 1-溴金刚烷(768-90-1)红外图谱(IR1) 1-溴金刚烷(768-90-1)红外图谱(IR2) 1-溴金刚烷(768-90-1)核磁图( 13 CNMR) 1-溴金刚烷(768-90-1)核磁图( 1 HNMR)
  • 用途一:是合成盐酸金刚烷胺的中间体
  • 方法一:由金刚烷溴化而得。在干燥的搪瓷玻璃锅中，加入金刚烷，滴加溴素，慢慢升高温度至70℃左右，回流反应6h。随着1-溴金刚烷的生成，反应物的回流温度逐渐升高，最后达到100℃，反应结束后，放置过夜。再升温到45℃，滴加亚硫酸氢钠溶液除去过剩的溴。过滤，用水洗涤滤饼至中性，干燥得1-溴金刚烷。
  • Acros Organics:1-溴金刚烷 1-Bromoadamantane, 99%(768-90-1)
  • MSDS 信息:1-Bromotricyclo[3.3.1.1(3,7)]decane(768-90-1).msds
  • 1-溴金刚烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0390 1-溴金刚烷 1-Bromoadamantane 25G 315元 2014/06/02 B0390 1-溴金刚烷 1-Bromoadamantane 250G 1890元 2010/06/21 149031000 1-溴金刚烷 1-Bromoadamantane 99% 100 GR 1095元
  • Sigma Aldrich:768-90-1(sigmaaldrich)
  • 海关编码:29035990
  • 用途二:医药中间体。
  • Alfa Aesar:1-溴金刚烷,99% 1-Bromoadamantane, 99%(768-90-1)
  • 敏感性:Moisture Sensitive
  • F:8-10-23

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkyl 烷基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkenyl
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Adamantanes

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