B-Bromo-9-borabicyclo[3.3.1]nonane

CAS 22086-45-9 MFCD00074773

化学结构图

22086-45-9
SMILES: BrB1[C@@H]2CCC[C@H]1CCC2 |&1:2,6|

化学属性

Mol. FormulaC8H14BBr
Mol. Weight200.91
Density1.315
Flash Point-17 ºC

别名和识别编码

Chemical NameB-Bromo-9-borabicyclo[3.3.1]nonane
Synonym B-bromo-9-BBN 9-Borabicyclo[3.3.1]nonane, 9-bromo- C8H14BBr 9-溴-9-硼杂双环[3.3.1]壬烷 溶液 B-Bromo-9-BBN
MDL NumberMFCD00074773
PubChem Substance ID24853575
CAS Number22086-45-9
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分类

  • {uni_hamburg} no charge; other heterocycle; carbocycle; alicycle; large ring; fused rings; 6ring; 8ring; 1fragment
  • {SNA} C-X Bond Formation (Halogen), Chemical Synthesis, Haloboration, Synthetic Reagents

相关文献及参考

  • Short: III/35A Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Boron-11 and Phosphorus-31 Author: Gupta, R.R.; Jain, M.; Pardasani, P.; Pardasani, R.T.; Pelter, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35A Year: 1997 ISBN: 3-540-60366-2 ISBN: 978-3-540-60366-5 Internet Resource: DOI:10.1007/b53033 RefComment: VIII, 242 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CO-ROM's.

安全信息

Hazard Codes F;C
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R17 Spontaneously flammable in air 在空气中能够自燃
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
UN Number 2845

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-X Bond Formation (Halogen) 卤代烃
  4. Haloboration - C-X Bond Formation (Halogen)

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