(Acetylacetonato)(1,5-Cyclooctadiene)Rhodium(I) 1,5-环辛二烯(乙酰丙酮)铑(I)

CAS 12245-39-5 MFCD00075046

化学结构图

12245-39-5
SMILES: C/C(=C/C(C)=O)/O[Rh].C1CC=CCCC=C1

化学属性

Melting Point138-140 °C(lit.)
TSCANo
Mol. FormulaC13H19O2Rh
Mol. Weight310
Appearance orange xtl.
Stabilityair sensitive, store cold

别名和识别编码

Chemical Name(Acetylacetonato)(1,5-Cyclooctadiene)Rhodium(I)
Synonym Rh(acac)(COD) 1,5-环辛二烯(乙酰丙酮)铑(I) (1,5-Cyclooctadiene)(2,4-pentanedionato)rhodium Acetylacetonate-1,5-cyclooctadiene rhodium (Acetylacetonato)(1,5-cyclooctadiene)rhodium(I) Rhodium, ((1,2,5,6-eta)-1,5-cyclooctadiene)(2,4-pentanedionato-O,O')- 乙酰丙酮(1,5-环辛二烯)铑
PubChem Substance ID329760794
Chemical Name Translation1,5-环辛二烯(乙酰丙酮)铑(I)
MDL NumberMFCD00075046
CAS Number12245-39-5
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhodium Catalysts
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhodium
  • {SNA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Micro/NanoElectronics, Rhodium, Vapor Deposition Precursors, 材料科学

相关文献及参考

  • FT-IR 2 (3), 4529:A / FT-NMR 1 (3), 754:B / RegBook 1 (2), 3091:B / Structure Index 1 , 489:E:7

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P305+P351+P338
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
RTECSVI9292000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Air Sensitive 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 34 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CBINA8 Chemico-Biological Interactions.  (Elsevier Scientific Pub. Ireland
   Ltd., POB 85, Limerick, Ireland)  V.1-    1969-  Volume(issue)/page/year:
   45,1,1983

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Rhodium 铑
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Vapor Deposition Precursors - Micro/NanoElectronics
  4. CVD and ALD Precursors by Metal - Vapor Deposition Precursors
  5. Vapor Deposition Precursors for Rhodium Thin Films
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Rhenium
  1. Catalysts
  2. Rhodium

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