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• 试剂商城
• 直接询价

分类

• {Chemicalbook} 农药中间体: 杀菌剂中间体: 氨基甲酸酯类杀菌剂
• {uni_hamburg} no charge; carbonyl chloride; 1fragment
• {SNA} Acid Halides, Building Blocks, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks

相关文献及参考

• Short: II/14a Title: Molecular Constants: Diamagnetic Molecules Author: Demaison, J.; Dubrulle, A.; Hüttner, W.; Tiemann, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/14a Page: 1-788 Year: 1982 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-11365-7 ISBN: 978-3-540-11365-2 Internet Resource: DOI:10.1007/b19966 RefComment: 196 figs., XI
• Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
• Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 org

安全信息

GHS Symbol

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 12 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   37ASAA "Kirk-Othmer Encyclopedia of Chemical Technology," 3rd ed., Grayson,
   M., and D. Eckroth, eds., New York, John Wiley & Sons, Inc., 1978
   Volume(issue)/page/year: 4,758,1978

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 200 ppm/5H
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   BJIMAG British Journal of Industrial Medicine.  (British Medical Journal,
   Box 560B, Kennebunkport, ME 04046)  V.1-    1944-  Volume(issue)/page/year:
   27,1,1970

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1070 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   IHFCAY Industrial Hygiene Foundation of America, Chemical and Toxicological
   Series, Bulletin. (Pittsburgh, PA)  1947-69.  Volume(issue)/page/year:
   6,1,1967

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 178 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   37ASAA "Kirk-Othmer Encyclopedia of Chemical Technology," 3rd ed., Grayson,
   M., and D. Eckroth, eds., New York, John Wiley & Sons, Inc., 1978
   Volume(issue)/page/year: 4,758,1978

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration on

其他信息

• TCI Shanghai:氯甲酸异丙酯 Isopropyl Chloroformate,>;97.0%(T)(108-23-6)
• 方法一:其制备方法是在通光气釜内加入异丙醇，启动搅拌，然后通过光气流量计通入光气，通光气温度为30℃左右，继续通光气若干小时，接近终点时取样分析达标后停止通气，然后通氮气赶走光气和氯化氢，对光气进行破坏，取样分析得产品。反应方程式：(CH 3 ) 2 CHOH+COCl 2 →ClCOOCH(CH 3 ) 2 +HCl
• 用途二:氯甲酸异丙酯是杀菌剂乙霉威的中间体。
• 用途一:用作聚氯乙烯树脂聚合时的引发剂，也可用作农药中间体、矿石浮选剂等
• 上游原料:流量计
• 类别:有毒物品
• MOL 文件:108-23-6.mol
• 氯甲酸异丙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010349 氯甲酸异丙酯 100ml 235元 2011/08/23 C427621000 氯甲酸异丙酯（甲苯易制毒） 100ml 527元 2011/04/16 I0768 氯甲酸异丙酯(约30%的甲苯,约2mol/L) Isopropyl Chloroformate (ca. 30% in Toluene, ca. 2mol/L) 500G 791元
• 灭火剂:干粉、泡沫、二氧化碳、砂土
• 方法二:异丙醇与光气反应合成，然后经驱气、蒸馏，精制得成品。
• MSDS 信息:氯甲酸异丙酯(108-23-6).msds
• 下游产品:万霉灵 --> 氯苯胺灵
• 图谱信息:氯甲酸异丙酯(108-23-6)核磁图( 13 CNMR) 氯甲酸异丙酯(108-23-6)红外图谱(IR1) 氯甲酸异丙酯(108-23-6)核磁图( 1 HNMR) 氯甲酸异丙酯(108-23-6)质谱(MS)
• F:10-19
• Sigma Aldrich:108-23-6(sigmaaldrich)
• 储运特性:库房通风低温干燥; 与氧化剂、食品添加剂分开存放
• 可燃性危险特性:明火可燃; 高热放出有毒氯化物气体
• 毒性分级:高毒
• 职业标准:TWA 1 PPM (5 毫克/ 立方米); STEL 0.1 毫克/ 立方米
• 急性毒性:口服- 大鼠 LD50:1070 毫克/ 公斤; 口服- 小鼠 LD50: 178 毫克/ 公斤
• 外观性质:无色液体。
• 用途三:用作农药中间体，矿石浮选剂和游离基聚合反应的引发剂，如氯乙烯聚合反应的引发。