[(R)-(+)-2,2’-Bis(Diphenylphosphino)-1,1’-Binaphthyl]Palladium(II) Chloride [(R)-(+)-2,2’-双(二苯基膦)-1,1’-联萘]二氯化钯

CAS 115826-95-4 MFCD00075254

化学结构图

115826-95-4
SMILES:

化学属性

Melting Point230-300 °C (decomposition)
TSCANo
Mol. FormulaC44H32Cl2P2Pd
Appearance orange microxtls.
Mol. Weight800.00
Boiling Point724.3°C at 760 mmHg

别名和识别编码

Chemical Name[(R)-(+)-2,2’-Bis(Diphenylphosphino)-1,1’-Binaphthyl]Palladium(II) Chloride
PubChem Substance ID24861055
Synonym ((R)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl)dichloropalladium {LY} ((R)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl)dichloropalladium {} {LY} ((R)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl)dichloropalladium {} {} {LY} ((R)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl)dichloropalladium {} {} {} {LY} ((R)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl)dichloropalladium {} {} {} {} {LY} ((R)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl)dichloropalladium {} {} {} {} {} {LY} ((R)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl)dichloropalladium {} {} {} {} {} {} {LY} ((R)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl)dichloropalladium {} {} {} {} {} {} {} {LY} ((R)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl)dichloropalladium {} {} {} {} {} {} {} {} {LY} ((R)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl)dichloropalladium {} {} {} {} {} {} {} {} {} {LY} ((R)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl)dichloropalladium {} {} {} {} {} {} {} {} {} {} {LY} ((R)-2,2'-Bis(diphenylpho
Chemical Name Translation[(R)-(+)-2,2’-双(二苯基膦)-1,1’-联萘]二氯化钯
MDL NumberMFCD00075254
CAS Number115826-95-4
Canonical SMILESCl[Pd]1([P](C2=CC=CC=C2)(C3=CC=CC=C3)C4=C(C5=C(C=CC=C6)C6=CC=C5[P](C7=CC=CC=C7)1C8=CC=CC=C8)C9=CC=CC=C9C=C4)Cl
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分类

  • {SNA} Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
  • Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes

相关文献及参考

  • FT-IR 2 (3), 4558:B / RegBook 1 (2), 3115:B / Structure Index 1 , 493:D:2

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H315 Causes skin irritation 会刺激皮肤
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
Hazard Codes Xn
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Moisture Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect fro

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Other Chiral Catalysts - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Palladium Catalysis 钯催化剂
  4. Homogeneous Pd Catalysts - Palladium
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. BINAPs - Privileged Ligands and Complexes
  1. Functional Group 官能团索引
  2. phosphine
  1. BINAP
  2. Palladium
  1. Catalysts
  2. Palladium

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