Benzyltrimethylammonium Dichloroiodate 苄基三甲基二氯碘酸铵
CAS 114971-52-7 MFCD00075259
化学结构图
SMILES: C[N+](C)(C)Cc1ccccc1.Cl[I-]Cl
化学属性
| Mol. Formula | C10H16Cl2IN |
|---|---|
| Mol. Weight | 348 |
| Melting Point | 125.0 to 128.0 deg-C |
| TSCA | No |
别名和识别编码
| Chemical Name | Benzyltrimethylammonium Dichloroiodate |
|---|---|
| CAS Number | 114971-52-7 |
| Synonym | BTMA-ICl2 苄基三甲基二氯碘化铵 BENZYLTRIMETHYLAMMONIUM DICHLOROIODIDE {SNA} Benzyltrimethylammonium dichloroiodide, BTMA-ICl2 N,N,N-Trimethylbenzenemethanaminium Dichloroiodate BENZYLTRIMETHYLAMMONIUM DICHLOROIODATE Benzenemethanaminium, N,N,N-trimethyl-, dichloroiodate(1-) TRIMETHYLBENZYLAMMONIUM DICHLOROIODATE TRIMETHYL BENZYLAMMONIUM DICHLORO IODIDE BTMA-ICL2 苄基三甲基二氯碘酸铵 |
| MDL Number | MFCD00075259 |
| PubChem Substance ID | 87564505 |
| Beilstein Registry Number | 4611949 |
| Chemical Name Translation | 苄基三甲基二氯碘酸铵 |
| Reaxys-RN | 4611949 |
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分类
- Amines
- {SNA} Ammonium Salts, C-X Bond Formation (Halogen), Chemical Synthesis, Others, Phase Transfer Catalysts, Synthetic Reagents
- Aromatics
- {SNA} Ammonium Salts, C-X Bond Formation (Halogen), Chemical Synthesis, Other Halogen Reagents for C-X Bond Formation, Phase Transfer Catalysts, Synthetic Reagents
产品应用
- Benzyltrimethylammonium dichloroiodate is used in the mechanism of oxidation.
相关文献及参考
- Sankhla, R., et al.: J. Chem. Res., 0465 (2002),
- Srinivasan, N., et al.: Tetrahedron, 30, 419 (1974),
- Under mild conditions in the presence of MeOH, iodinates phenols: Chem. Lett., 2109 (1987), or arylamines: Bull. Chem. Soc. Jpn., 61, 597 (1988); J. Med. Chem., 35, 2231 (1992), also trans-chloroiodinates alkenes: Bull Chem. Soc. Jpn., 63, 3033 (1990), and ɑ-chlorinates acetophenones: Synthesis, 545 (1988); 212 (1990). In the presence of ZnCl2, iodinates aromatic ethers: Chem. Lett., 795 (1988), alkylarenes, acetanilides, or thiophenes: Bull. Chem. Soc. Jpn., 62, 439, 1349 (1989); 64, 2566 (1991), respectively.
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P350
- P302+P352+P332+P313+P362+P364
- P305+P351+P338
- P305+P351+P338+P337+P313
- P332+P313
- P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
其他信息
- 苄基三甲基二氯碘酸铵价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1604 苄基三甲基二氯碘酸铵 Benzyltrimethylammonium Dichloroiodate 25G 1750元 2014/06/02 B1604 苄基三甲基二氯碘酸铵 Benzyltrimethylammonium Dichloroiodate 5G 520元 2010/06/21 268601000 苄基三甲基二氯碘酸铵 Benzyltrimethylammonium dichloroiodate 99% 100 GR 5809元
- MOL 文件:114971-52-7.mol
- F:3
- Sigma Aldrich:114971-52-7(sigmaaldrich)
- TCI Shanghai:苄基三甲基二氯碘酸铵 Benzyltrimethylammonium Dichloroiodate,>;95.0%(T)(114971-52-7)
- 敏感性:Light Sensitive & Hygroscopic
- Alfa Aesar:苄基三甲基二氯碘酸铵,95% Benzyltrimethylammonium dichloroiodate, 95%(114971-52-7)
- Acros Organics:Benzyltrimethylammonium dichloroiodate, 99%(114971-52-7)
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