Tetrabutylammonium Bifluoride 四正丁基二氟化铵氢氟酸盐

CAS 23868-34-0 MFCD00077877

化学结构图

23868-34-0
SMILES: [F-].F.CCCC[N+](CCCC)(CCCC)CCCC

化学属性

Mol. Formula(CH3CH2CH2CH2)4N(HF2)
Mol. Weight281
Refractive indexn20/D 1.442

别名和识别编码

Chemical NameTetrabutylammonium Bifluoride
Synonym 四正丁基二氟化铵氢氟酸盐 溶液 TBABF Tetrabutylammonium difluoride 四丁基二氟化铵
MDL NumberMFCD00077877
PubChem Substance ID87577066
Beilstein Registry Number4729304
CAS Number23868-34-0
Chemical Name Translation四正丁基二氟化铵氢氟酸盐
Reaxys-RN4729304
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分类

  • {SNA} Ammonium Salts, Chemical Synthesis, Fluorination, Fluorination Reagents, Phase Transfer Catalysts, Synthetic Reagents
  • {SNA} Ammonium Salts, Chemical Synthesis, Phase Transfer Catalysts, Synthetic Reagents

安全信息

GHS Symbol
Precautionary statements
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P305+P351+P338
  • P301+P330+P331
  • P405 Store locked up. 上锁保管。
  • P304+P340
  • P303+P361+P353
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P301+P330+P331+P310
  • P305+P351+P338+P310
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H351 Suspected of causing cancer 怀疑致癌
WGK Germany3
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
Hazard Codes F,C C
Risk Statements
  • R11 Highly flammable 非常易燃
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R34 Causes burns 会导致灼伤
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
Packing GroupII
UN Number 1759 1760
Hazard Class8

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Fluorination Reagents 含氟试剂
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Phase Transfer Catalysts 相转移催化剂
  4. Ammonium Salts - Phase Transfer Catalysts
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Phase Transfer Catalysts 相转移催化剂
  4. Ammonium Salts - Phase Transfer Catalysts
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Halogenation
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Quaternary Ammonium Compounds 季铵化合物

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