TRIS(TERT-BUTYLDIMETHYLSILYL) PHOSPHITE 三(叔丁基二甲硅烷基)亚磷酸盐
CAS 85197-27-9 MFCD00077891
化学结构图
SMILES: C[Si](C)(OP(O[Si](C)(C)C(C)(C)C)O[Si](C)(C)C(C)(C)C)C(C)(C)C
化学属性
| Mol. Formula | C18H45O3PSi3 |
|---|---|
| Mol. Weight | 424.78 |
| Refractive index | n20/D 1.445 |
| Boiling Point | 82-84 °C/0.2 mmHg |
| Density | 0.907 g/mL at 20 °C(lit.) |
| Melting Point | 4-6 °C |
别名和识别编码
| Chemical Name | Tris(tert-butyldimethylsilyl) phosphite |
|---|---|
| CAS Number | 85197-27-9 |
| PubChem Substance ID | 57653532 |
| Beilstein Registry Number | 4437247 |
| MDL Number | MFCD00077891 |
| Chemical Name Translation | 三(叔丁基二甲硅烷基)亚磷酸盐 |
| Synonym | 三(叔丁基二甲硅烷基)亚磷酸盐 |
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分类
- Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Phosphates/Phosphites, Phosphorus Compounds
- {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Phosphates/Phosphites, Phosphorus Compounds
相关文献及参考
- 1. J.-L. Montero et al. Tetrahedron Lett. 28 , 1163, (1987)
- 2. L. Wozniak, J. Chojnowski Tetrahedron 45 , 2465, (1989)
安全信息
GHS Symbol
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- R34 Causes burns 会导致灼伤
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