Pyrethrum extract 除虫菊提取物

CAS 8003-34-7 MFCD00078611

化学结构图

8003-34-7
SMILES: C=C/C=C/CC1=C(C)C(OC(=O)[C@@H]2C(/C=C(\C)C(=O)OC)C2(C)C)CC1=O.C=C/C=C/CC1=C(C)[C@@H](OC(=O)[C@@H]2C(C=C(C)C)C2(C)C)CC1=O

化学属性

Mol. FormulaC43H56O8
Mol. Weight700.90
Refractive indexn20/D 1.45
Flash Point75 ºC
Solubility不溶于水，溶于多数有机溶剂。

别名和识别编码

Chemical NamePyrethrum Extract (Technical Grade)
MDL NumberMFCD00078611
CAS Number8003-34-7
EC Number232-319-8
Synonym pyrethre Prentox pyrethrum extract 除虫菊提取物 pyrethriniorii pyrenone Firmotox Pyrethrin I or II 除虫菊 insectpowder Jasmolin I or II pyrethrines Buhach firmotox PYRETHRINS dalmatianinsectpowder dalmationinsectflowers CHECKOUT jasmoliniorii Insect powder Pyrethrum prentoxpyrethrumextract persianinsectpowder cineriniorii PYRETHRUM 除虫菊酯类 Cinerin I or II Dalmation insect flowers buhach insecticides,pyrethrins Chrysanthemum cinerareaefolium 除虫菊酯 WOPROTHRUM Trieste flowers PYRETHRUM-EXTRACT Pyrocide chrysanthemumcinerareaefolium Pyrethrins Pyronyl Pyrenone Pyrethrum (insecticide)
Chemical Name Translation除虫菊提取物
Wiswesser Line NotationL5V BUTJ B2U2U1 C1 DOV- BL3TJ A1 A1 C1U2
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {SNA} All alphabetically sorted, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards, Insecticides, N-P, P, PU - PZ, Pesticides, Pesticides & Metabolites, Pyrethroids
  • {SNA} Cell Biology, Cell Signaling and Neuroscience, Ion Channels, Monovalent Ion Channels, Other Sodium Channel Modulators, Sodium Channel Modulators, Voltage-gated Ion Channels
  • {SNA} Analytical Standards, Insecticides, N-P, Pyrethroids, 农残和代谢标准品, 分析/色谱,

安全信息

GHS Symbol
WGK Germany3
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
RTECSUR4200000
Signal word Warning
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes Xn;N Xn,N
Safety Statements
  • S13 Keep away from food, drink and animal foodstuffs 远离食品、饮料和动物饲料保存；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R50/53
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
UN Number 2810 UN 2810 6.1/PG 3
Storage condition 2-8°C 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GUCHAZ Guide to the Chemicals Used in Crop Protection.  (Information Canada,
   171 Slater St., Ottawa, Ont., Canada)  Volume(issue)/page/year: 6,442,1973

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1350 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   YKYUA6 Yakkyoku.  Pharmacy.  (Nanzando, 4-1-11, Yushima, Bunkyo-ku, Tokyo,
   Japan)  V.1-    1950-  Volume(issue)/page/year: 37,1481,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   WRPCA2 World Review of Pest Control.  (London, UK)  V.1-10, 1962-71.
   Discontinued.  Volume(issue)/page/year: 3,28,1964

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Human - child
DOSE/DURATION           : 750 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CMEP** "Clinical Memoranda on Economic Poisons," U.S. Dept. HEW, Public
   Health Service, Communicable Disease Center, Atlanta, GA, 1956
   Volume(issue)/page/year: -,1,1956

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 250 mg/kg
TOXIC

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 500 mg/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
REFERENCE :
   JTEHD6 Journal of Toxicology and Environmental Health.  (Hemisphere Pub.,
   1025 Vermont Ave., NW, Washington, DC 20005)  V.1-    1975/76-
   Volume(issue)/page/year: 10,111,1982

其他信息

  • 除虫菊酯中毒:除虫菊为菊科植物白花除虫菊的干燥花序，约含1%除虫菊酯，具有杀虫药效好、击倒快、低毒等优点。近年来人工合成除虫菊酯类似物，具有杀虫谱广、对人畜毒性较低、环境残留较少等优点，故称其为拟除虫菊酯类杀虫药。本类杀虫药均属神经毒剂。目前市售实用产品有20余种，我国主要应用溴氰菊酯、氰戊菊酯、氯氰菊酯、氯菊酯、胺菊酯等，均属口服吸收毒性较大的中等毒性产品。本类杀虫药中多含除虫菊酯增效剂 (P-450细胞色素抑制剂)。家庭用杀虫剂为除虫菊酯类药与其他成分的混合物。除虫菊酯虽为低毒杀虫剂，但与其他杀虫剂，如灭虫菊、普鲁本辛酚等合用，可明显增强其毒性，或延长药物的半衰期。本类杀虫剂吸入毒性强。 中毒机理：除虫菊酯可使机体神经细胞膜发生轻度去极化，增加复后电位，导致重复性后放电，影响Na+、K+通道，阻断运动电位而致发中毒。除虫菊酯增效剂能抑制和延缓除虫菊酯在机体内的代谢，增强其毒性和延长体内药物作用时间而提高药效。
  • MOL 文件:8003-34-7.mol
  • 杀虫剂:除虫菊酯是制备蚊虫香的主要原料，为菊科多年生草本植物除虫菊内所含的杀虫有效成分。主要有除虫菊酯Ⅰ和除虫菊酯Ⅱ，另外还有少量结构近似的瓜叶除虫菊酯Ⅰ、瓜叶除虫菊酯Ⅱ等。目前已人工合成多种与天然除虫菊酯类似的化合物用作杀虫剂，统称为拟除虫菊酯。除虫菊酯为黄色粘稠油状液体，有清香气味。不溶于水，可溶于多种有机溶剂。不稳定，遇碱分解失效，在强光或高温下也分解失效。主要剂型有粉剂、乳油、气雾剂、油剂、蚊香等。有强力触杀作用，杀虫谱广。残效期短。主要用于防治卫生害虫、家畜害虫等。对人畜非常安全，对植物无药害、无残留，不污染农产品和环境的植物源农药。对温血动物安全。对昆虫的毒力强度，以除虫菊酯Ⅰ最强，瓜叶除虫菊酯1次之，除虫菊酯Ⅱ再次之，瓜叶除虫菊酯Ⅱ最弱。FAO/WHO建议日容许摄入量为0.04mg/kg体重 (包括其它除虫菊酯)。大鼠口服1500mg/kg。食品中最高容许浓度：瑞典规定水果和蔬菜为1.0mg/kg(包括除虫菊酯Ⅰ)；FAO/WHO建议鱼(干)、未加工谷类为3mg/kg，干果、干蔬菜、鲜果和鲜蔬菜、花生米、核果为1mg/kg(包括其他除虫菊酯)。 图1为除虫菊素主要成分除虫菊酯Ⅰ和除虫菊酯Ⅱ的化学结构式 以上信息由Chemicalbook的晓楠编辑整理。
  • RTECS号:UR4200000
  • 外观性质:黄色粘稠液体，含有五种有效成份。
  • PackingGroup:III
  • HazardClass:6.1(b)
  • 除虫菊酯和拟除虫菊酯:除虫菊酯是干菊花的提取物，因为其在热和光条件下还是很稳定，所以主要被用于室内杀虫剂。一些杀灭头虱的洗发水也含有除虫菊酯。拟除虫菊酯是在除虫菊酯结构和生物活性基础上人工合成的，其稳定性得到了增加，主要分成类型Ⅰ和类型Ⅱ，类型Ⅱ的毒性大于类型Ⅰ。合成除虫菊酯在农业以及园艺上主要用于杀灭建筑害虫 (如白蚁)、虱子和跳蚤。除虫菊酯及合成除虫菊酯可以迅速渗透至害虫体内，使其瘫痪。氯菊酯是研究较早的一种不含氰基结构的拟除虫菊酯类杀虫剂，是菊酯类农药中第1个出现适用于防治农业害虫的光稳定性杀虫剂。

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides & Metabolites - Environmental Standards
  6. Pesticides - Pesticides & Metabolites
  7. Insecticides - Pesticides
  8. Pyrethroids - Insecticides
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. P - Alphabetic
  5. PU - PZ - P
  1. Life Science 生命科学
  2. Cell Biology 细胞生物学
  3. Cell Signaling and Neuroscience - Cell Biology
  4. Ion Channels - Cell Signaling and Neuroscience
  5. Voltage-gated Ion Channels - Ion Channels
  6. Monovalent Ion Channels - Voltage-gated Ion Channels
  7. Sodium Channel Modulators - Monovalent Ion Channels
  8. Other Sodium Channel Modulators - Sodium Channel Modulators
  1. Life Science 生命科学
  2. Cell Biology 细胞生物学
  3. Cell Signaling and Neuroscience - Cell Biology
  4. Ion Channels - Cell Signaling and Neuroscience
  5. Voltage-gated Ion Channels - Ion Channels
  6. Monovalent Ion Channels - Voltage-gated Ion Channels
  7. Sodium Channel Modulators - Monovalent Ion Channels
  8. Other Sodium Channel Modulators - Sodium Channel Modulators

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