Mancozeb 代森锰锌

CAS 8018-01-7 MFCD00078616

化学结构图

8018-01-7
SMILES: NC(=S)SCCSC(N)=S.[Mn].[Zn]

化学属性

Mol. FormulaC4H6MnN2S4.C4H6N2S4Zn
Mol. Weight541.03
Flash Point138 °C
Appearance 灰黄色粉末。熔融前分解。实际上不溶于水和大多数有机溶剂。在通常贮存条件下稳定，但在潮湿和酸性条件下，温度升高就会分解。
Melting Point192-194°C

别名和识别编码

Chemical NameMancozeb
Synonym MANCOZEB Tritogol MZ Dithane M 45 ((1,2-Ethanediylbis(carbamodithioato)))manganese mixture with ((1,2-ethandiylbis(carbamodithioate)))zinc Thane M45 Kascade 亚乙基双(二硫代氨基甲酸)锰锌 Agrox 16D Manzate 200 Marzidan ZINC AND MANGANESE ETHYLENE-BISDITHIOCARBAMATE COORDINATION PRODUCT Mancozeb [1,2-亚乙基-双(二硫代氨基甲酸)]锰锌盐 MANCOZEB STANDARD CRITTOX Fore 锌猛乃浦 Mancomix Penncozeb MANEX II Green-daisen M Dithane SPC Maneb-zineb-mischkomplex Dithane ultra TRIDEX(R) FUNGICIDE Karamate Nemispor Mancofol Zimaneb Maneb-zinc Zineb-maneb mixt. 亚乙基双(二硫代氨基甲酸锰) + 亚乙基双(二硫代氨基甲酸锌) Mancozi DITHANE(R) Carbamic acid, ethylenebis(dithio-, manganese zinc complex MICENE Novozir MN 80 MANZATE(R) 代森锰锌可湿性粉剂(50%) Dithane S 60 Carmazine ｛[1,2-亚乙基-双(二硫代氨基甲酸)](2-)｝锰锌盐 MANCO Tanzeo M45 Marzin MANGANESE-ZINC ETHYLENEBIS(DITHIOCARBAMATE) DITHANE Manzeb PENNCOZEB(R) TRIMANOC(R) VONDOZEB FORE(R) 叶斑青 Manoseb Manzin 80 Ziman-Dithane PENNFLUID(R) AIMCOZEB Mangan-zink-aethylendiamin-bis-dithio-carbamat Othane M 45 F 2966 Maneb-zineb-komplex MANZEB 代森锰锌 Zimanat
MDL NumberMFCD00078616
CAS Number8018-01-7
Chemical Name Translation代森锰锌
Merck Number13,5738
PubChem Substance ID13307026
InChIInChI=1S/2C4H8N2S4.Mn.Zn/c2*7-3(8)5-1-2-6-4(9)10;;/h2*1-2H2,(H2,5,7,8)(H2,6,9,10);;/q;;2*+2/p-4
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分类

  • Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Chromatography, Dithiocarbamates, Environmental Standards, Fungicides, H-M, M, MA - MD, Pesticides, Pesticides & Metabolites
  • {SNA} All Fungicides, Analytical Standards, Dithiocarbamates, Fungicides, H-M, 农残和代谢标准品, 分析/色谱, 按照字母排序
  • {SNA} Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Chromatography, Dithiocarbamates,

相关文献及参考

  • Merck 14 ,5716

安全信息

RTECSZB3200000
GHS Symbol
WGK Germany1
Precautionary statements
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P308+P313
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P333+P313
Signal word Warning
Hazard statements
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害
Hazard Codes Xn,N Xi
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Packing GroupIII
Hazard Class9
Storage condition APPROX 4°C
UN Number UN 2210
Safety Statements
  • S46 If swallowed, seek medical advice immediately and show this container or label 食入时，立即求医并出示容器/标签；
  • S8 Keep container dry 保持容器干燥；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Risk Statements
  • R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R50 Very toxic to aquatic organisms 对水生生物极毒
  • R37 Irritating to respiratory system 刺激呼吸道
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 17700 mg/kg/60W-I
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Skin and Appendages - tumors
REFERENCE :
   CALEDQ Cancer Letters (Shannon, Ireland).  (Elsevier Scientific Pub. Ireland
   Ltd., POB 85, Limerick, Ireland)  V.1-    1975- Volume(issue)/page/year:
   53,191,1990

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 5 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd,
   eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year:
   A251,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >10 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd,
   eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year:
   A251,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >5 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PEMNDP Pesticide Manual.  (The British Crop Protection Council, 20 Bridport
   Rd., Thornton Heath CR4 7QG, UK)  V.1-    1968-  Volume(issue)/page/year:
   9,530,1991

TYPE OF TEST            : Gene conversion and mitotic recombination
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 50 ppm
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB85-193761

TYPE OF TEST            : Mutation in mic

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 2500 ug/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 116,341,1983

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Human Fibroblast
DOSE/DURATION           : 10 mg/L
REFERENCE :
   NTIS** National Technical Information Service.  (Spring

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 476 mg/kg/40W (Intermittent)
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 116,341,1983

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Mold - Aspergillus nidulans
DOSE/DURATION           : 12 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 176,29,1987

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 4 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 116,341,1983

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 1320 mg/kg
SEX/DURATION            : female 11 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - craniofacial
   (including nose and tongue)
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
   Reproductive - Specific Developmental Abnormalities - homeostasis
REFERENCE :
   TJADAB Teratology, The International Journal of Abnormal Development. (Alan
   R. Liss, Inc., 41 E. 11th St., New York, NY 10003)  V.1-    1968-
   Volume(issue)/page/year: 14,171,1976

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 2500 mg/kg
SEX/DURATION            : male 5 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Fertility - pre-implantation mortality (e.g. reduction in
   number of implants per female; total number of implants per corpora lutea)
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
REFERENCE :
   KHZDAN Khigiena i Zdraveopazvane.  Hygiene and Sanitation.  (Hemus, Blvd.
   Russki 6, Sofia, Bulgaria) V.9-    1966-  Volume(issue)/page/year:
   27,524,1984

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 500 mg/m3/6H
SEX/DURATION            : female 6-10 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(i

其他信息

  • 用途一:为高效、低毒、广谱保护性杀菌剂，用于小麦、玉米、水果等作物的杀菌防病
  • 用途四:该品为广谱的叶面保护用杀菌剂，广泛用于果树；蔬菜以及大田作物，可防治多种重要的叶部真菌病害，例如麦类锈病，玉米大斑病，马铃薯疫霉病，果树黑星病，炭疽病等。其用量为1.4-1.9kg（有效成分）/hm2。由于它用途广；药效好，已成为非内吸性的保护杀菌剂中的重要品种。与内吸性杀菌剂轮换使用或混用，可有一定的销路。
  • 上游原料:氢氧化铵 --> 氨 --> 氯化锌 --> 二硫化碳 --> 乙二胺 --> 硫酸锌 --> 碳酸锰 --> 硫酸锰 --> 七水硫酸锌 --> 硫酸锰 --> 代森锰 --> 硝酸锌 --> 代森钠
  • 中毒症状:恶心、呕吐、腹痛、腹泻，头痛、头晕、乏力，严重者可导致呼吸和循环功能衰竭加快，血压下降，呼吸抑制等。
  • 用途三:该品为广谱的叶面保护用杀菌剂，广泛用于果树、蔬菜以及大田作物，可防治多种重要的叶部真菌病害，例如麦类锈病，玉米大斑病，马铃薯疫霉病，果树黑星病，炭疽病等。其用量为1.4-1.9kg（有效成分）/hm2。由于它用途广、药效好，已成为非内吸性的保护杀菌剂中的重要品种。与内吸性杀菌剂轮换使用或混用，可有一定的销路。
  • 注意事项:(1)该药不能与铜及强碱性农药混用，在喷过铜、汞、碱性药剂后要间隔一周后才能喷此药 (2)在茶树上的间隔期为半个月
  • 下游产品:代森锰 --> 代森锰锌可湿性粉剂 --> 腈菌·锰锌可湿性粉剂 --> 锰锌·烯酰可湿性粉剂
  • 用途二:属广谱性杀菌剂，用于防治农作物因真菌引起的各种病害
  • Sigma Aldrich:8018-01-7(sigmaaldrich)
  • MSDS 信息:Mancozeb(8018-01-7).msds
  • 方法一:将代森钠与浓氯化锰液等量反应，制得浆状代森锰液。然后，将代森锰与硝酸锌或硫酸锌溶液反应，喷雾干燥得到产品。原料消耗定额：乙二胺（98%）310kg/t、二硫化碳（99%）870kg/t、氢氧化钠（30%）420kg/t、硫酸锰（98%）1020kg/t、硫酸锌（96%）80kg/t。
  • MOL 文件:8018-01-7.mol
  • 急救治疗:[1]误食者立即催吐、洗胃、导泻。 [2]对症治疗。 [3]忌油类食物，禁酒。

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides & Metabolites - Environmental Standards
  6. Alpha sort - Pesticides & Metabolites
  7. H-M - Alpha sort
  1. Functional Group 官能团索引
  2. thiocarbamic acid

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