(2S,5S)-2,5-Hexanediol (2S,5S)-2,5-己二醇

CAS 34338-96-0 MFCD00082583

化学结构图

34338-96-0
SMILES: CC(O)CCC(C)O

化学属性

Mol. FormulaCH3CH(OH)CH2CH2CH(OH)CH3
Mol. Weight118
Boiling Point71°C/1mmHg(lit.)
Melting Point52.0 to 56.0 deg-C
Flash Point101°(215°F)
TSCANo

别名和识别编码

Chemical Name(2S,5S)-2,5-Hexanediol
CAS Number34338-96-0
Synonym (2S,5S)-2,5-己二醇 [S-(R*,R*)]-
PubChem Substance ID87571325
Beilstein Registry Number1(3)2204
MDL NumberMFCD00082583
Reaxys-RN4652444
Chemical Name Translation(2S,5S)-2,5-己二醇
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Polyols
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Polyols

产品应用

  • Used in the synthesis of new phospholanes. Reagent used for asymmetric syntheses.

相关文献及参考

  • Uppenberg, J., et al.: Biochemistry, 34, 16838 (1995),
  • 1. Tetrahedron Asymmetry 2 , 569, (1991)
  • 2. J. Org. Chem. 54 , 1755, (1989)
  • 3. Marshall, J.A. Xie, S. J. Org. Chem. 60 , 7230, (1995)
  • 4. Stolle, A. et al. Tetrahedron Lett. 35 , 3521, (1994)
  • 5. Burk, M.J. et al. J. Am. Chem. Soc. 115 , 10125, (1993)
  • 6. Burk, M.J. et al. Tetrahedron Asymmetry 2 , 569, (1991)
  • 7. Pichon, M. Figadere, B. Tetrahedron Asymmetry 7 , 927, (1996)
  • 8. Matteson, D.S. Man, H.-W. J. Org. Chem. 59 , 5734, (1994)
  • 9. Ho, O.C. et al. Organometallics 14 , 2855, (1995)
  • Beil. 1 ,III,2204
  • FT-IR 2 (1), 194:B / Structure Index 1 , 17:D:5

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xn
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Alcohols - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Polyols - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Polyamines 多胺

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