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分类

• {SNA} Bioelectronics, Homopolymers, Methyl (CH3) Terminated PDMS, Micro/NanoElectronics, Microfluidics, PDMS, PDMS Elastomers/Resins, PDMS and Silicone Polymers, Polymer Science, Polymers, Polysiloxanes, Self Assembly and Lithography, Silicones, Stamps for Nanoprint Lithography & Microcontact Printing, 材料科学
• {SNA} Homopolymers,
• {SA} Materials Science, Polymer Science, Polymers, Polysiloxanes, Silicones
• {SNA} Bioelectronics, Homopolymers, Methyl (CH3) Terminated PDMS, Micro/NanoElectronics, Microfluidics, PDMS,

相关文献及参考

• Amine N-oxides can be reduced in the presence of Ti(O-i-Pr)4 or Pd(0): Synlett, 349 (2002).
• Convenient reducing agent with a wide variety of applications, for example:
• For a review of PMHS, see: J. Chem. Soc., Perkin 1, 3381 (1999).
• Low-cost alternative to Triethyl­silane, A10320, in a one-pot aromatic acylation-reduction technique allowing alkylation of the aromatic ring without the polysubstitution and rearrangements associated with Friedel-Crafts alkylations. Acylation in the presence of AlCl3 is followed by in situ reduction with PMHS: J. Chem. Soc., Perkin 1, 1705 (1989).
• Low-cost, safer alternative to Triethoxysilane, B22063, for reduction of phosphine oxides to phosphines, catalyzed by Ti(O-i-Pr)4. The products may be reacted in situ with alkyl halides to give a convenient one-pot conversion of phosphine oxides to phosphonium salts: Tetrahedron Lett., 35, 625 (1994).
• Pd(0)-catalyzed hydrogenolysis of alkyl and aryl halides: J. Org. Chem., 51, 734 (1986). Pd(0)-catalyzed reductive cyclization of 1,6- and 1,7-enynes to give exomethylene cyclopentanes and cyclohexanes: J. Am. Chem. Soc., 109, 3161 (1987).
• Reduction of esters to alcohols, catalyzed by a combination of titanocene dichloride and either n-BuLi or EtMgBr: J. Org. Chem., 59, 4323 (1994). Alternatively, in combination with Ti(O-i-Pr)4 reduces a variety of esters, generally in high yield: J. Org. Chem., 60, 7884 (1995); Synlett, 831 (1994). For one-step reductive amination of carbonyl compounds in similar fashion, see: Synlett, 1655 (2000). Reduction of esters, carboxylic acids, ketones and aldehydes can also be accomplished conveniently with TBAF as a catalyst: Synlett, 989 (1997). For asymmetric reduction of ketones catalyzed by chiral quaternary fluorides, see: Tetrahedron Lett., 38, 5857 (1997).

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其他信息

• 聚甲基聚硅氧烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 175091000 聚甲基聚硅氧烷 Polymethylhydrosiloxane 100 GR 418元 2010/06/21 175095000 聚甲基聚硅氧烷 Polymethylhydrosiloxane 500 GR 1563元
• 不溶于水。溶于大多数常见有机溶剂，可能会发生反应。不能用做卤烃溶媒，因为可能在催化或加热时发生卤化氢交换反应
• 下游产品:硅油 --> 乳化硅油
• 敏感性:Moisture Sensitive