(1R,4S,5R,6R)-5,6-Bis(Diphenylphosphaneyl)Bicyclo[2.2.1]Hept-2-Ene (1R,4S,5R,6R)-5,6-二(二苯基膦基)双环[2.2.1]庚-2-烯

CAS 71042-55-2 MFCD00085365

化学结构图

71042-55-2
SMILES: C1[C@H]2C=C[C@@H]1[C@H]([C@@H]2P(C1C=CC=CC=1)C1C=CC=CC=1)P(C1C=CC=CC=1)C1C=CC=CC=1

化学属性

Mol. FormulaC31H28P2
Mol. Weight462.51
Appearance white xtl.
Stabilityair sensitive
Melting Point116-119°C

别名和识别编码

Chemical Name(1R,4S,5R,6R)-5,6-Bis(Diphenylphosphaneyl)Bicyclo[2.2.1]Hept-2-Ene
Synonym (-)-Norphos
MDL NumberMFCD00085365
PubChem Substance ID125307423
Beilstein Registry Number5306484
CAS Number71042-55-2
Reaxys-RN5306484
Chemical Name Translation(1R,4S,5R,6R)-5,6-二(二苯基膦基)双环[2.2.1]庚-2-烯
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分类

  • {SA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Other Chiral Ligands

安全信息

GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
WGK Germany3
Signal word Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Storage condition 0-10 0-10°C

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Other Chiral Ligands - Chiral Catalysts, Ligands, and Reagents
  1. NORPHOS
  2. Phosphorus
  1. Phosphine
  2. Phosphorus
  1. Ligands
  2. Phosphorus

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