Ethyl Trifluoropyruvate 三氟丙酮酸乙酯

CAS 13081-18-0 MFCD00114935

化学结构图

13081-18-0
SMILES: CCOC(=O)C(=O)C(F)(F)F

化学属性

Mol. FormulaC5H5F3O3
Mol. Weight170
Boiling Point42
Refractive index1.3380 to 1.3420
Density1.283
Flash Point31°C(lit.)
TSCANo

别名和识别编码

Chemical NameEthyl Trifluoropyruvate
CAS Number13081-18-0
Alfabeta NameETHYLTRIFLUOROPYRUVATE
MDL NumberMFCD00114935
Synonym Ethyl 2-Oxo-3,3,3-trifluoropropanoate Ethyl 3,3,3-Trifluoropyruvate Ethyl 3,3,3-Trifluoro-2-oxopropanoate Ethyl Trifluoropyruvate Trifluoropyruvic acid ethyl ester
PubChem Substance ID87577197
Reaxys-RN2087388
EC Number000-000-0
Beilstein Registry Number2087388
Chemical Name Translation三氟丙酮酸乙酯
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分类

  • {SA} Building Blocks, C2 to C5, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks
  • Building Blocks, C2 to C5, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks

产品应用

  • Trifluoropyruvic Acid Ethyl Ester is used as a reagent in the preparation of potential biologically active compounds such as in the highly enantioselective organocatalytic hydroxyalkylation of indoles

相关文献及参考

  • Toeroek, B. et al.: Angew. Chem. Int. Ed., 44, 3086 (2005); Wolf, C. et al.: Adv. Synth. Cat., 353, 760 (2011);

安全信息

Warnings IRRITANT, FLAMMABLE
GHS Symbol
WGK Germany3
Hazard Codes Xn
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P332+P313
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P305+P351+P338+P337+P313
  • P303+P361+P353
Signal word
Storage condition 0-10 冷库。 0-10°C
UN Number 3272
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R10 Flammable 易燃
  • R22 Harmful if swallowed 吞咽有害
Safety Statements
Packing GroupIII
Hazard Class3

系列性分类


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