Methyl Trifluoropyruvate 三氟丙酮酸甲酯
CAS 13089-11-7 MFCD00114936
化学结构图
SMILES: COC(=O)C(=O)C(F)(F)F
化学属性
| Mol. Formula | CF3COCO2CH3 |
|---|---|
| Mol. Weight | 156 |
| Boiling Point | 86°C(lit.) |
| Density | 1.529 |
| Refractive index | 1.3300 to 1.3330 |
| Flash Point | 26°C(lit.) |
| TSCA | No |
别名和识别编码
| Chemical Name | Methyl Trifluoropyruvate |
|---|---|
| CAS Number | 13089-11-7 |
| Alfabeta Name | METHYLTRIFLUOROPYRUVATE |
| MDL Number | MFCD00114936 |
| PubChem Substance ID | 2734931 |
| EC Number | 000-000-0 |
| Beilstein Registry Number | 1863490 |
| Reaxys-RN | 1863490 |
| Synonym | Trifluoropyruvic acid methyl ester 三氟丙酮酸甲酯 三氟棕榈酸甲酯 |
| Chemical Name Translation | 三氟丙酮酸甲酯 |
| LabNetwork Molecule ID | LN00116724 |
| InChI | InChI=1S/C4H3F3O3/c1-10-3(9)2(8)4(5,6)7/h1H3 |
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分类
- Building Blocks, C2 to C5, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks
- {SNA} Building Blocks, C2 to C5, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks
相关文献及参考
- Aromatic compounds, in the presence of 5 mol% Indium(III) trifluoromethanesulfonate, 40131as a Lewis acid catalyst, undergo a Friedel-Crafts reaction in water to give the ɑ-aryl-ɑ-hydroxy-2,2,2-trifluoropropionic ester: Synlett, 555 (2004). Several other metal triflates or triflic acid itself were less effective. Activated aromatics, e.g. indoles, undergo rapid Friedel-Crafts alkylation under solvent- and catalyst-free condtions: Tetrahedron Lett., 47, 2511 (2006).
安全信息
- H226 Flammable liquid and vapour 易燃液体和蒸气
GHS Symbol
- R10 Flammable 易燃
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P332+P313
- P302+P352+P332+P313+P362+P364
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P302+P352+P332+P313+
- P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
- P305+P351+P338+P337+P313
- P233 Keep container tightly closed. ?保持容器密闭。
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P241+P242+P243
- P403+P235
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