Temephos 双硫磷

CAS 3383-96-8 MFCD00128034

化学结构图

3383-96-8
SMILES: COP(=S)(OC)Oc1ccc(Sc2ccc(OP(=S)(OC)OC)cc2)cc1

化学属性

Mol. FormulaC16H20O6P2S3
Mol. Weight466.48
Melting Point30-31°C
Solubility0.003 G/100 ML
Density1.4

别名和识别编码

Chemical NameTemephos
Synonym {un {Chem { O,O'-Thiodi-p-phenylenbis(O,O'-dimethylthiophosphorsäureester) nephis Abathion Ab temephos ABAPHOS(R) CL 52160 Nephis 1G O,O,O',O'-Tetramethyl O,O'-(thiodi-4,1-phenylene) phosphorothioate; Phosphorothioic acid O,O'-(thiodi-4,1-phenylene) O,O,O',O'-tetramethyl ester Phosphorothioic acid, O,O'-(thiodi-4,1-phenylene) O,O,O',O'-tetramethyl ester Abate 1-SG, 2-CG, 4-E, 5CG ABATE (TM 替美磷 SWEBATE(R) temefos 4,4'-双(O,O-二甲基硫代磷酰氧基)苯硫醚 TEMEPHOS O,O,O',O'-tetramethyl O,O'-thiodi-p-phenylene bis(phosphorothioate) AC 52160 O,O,O',O'-TETRAMETHYL- 替美福司 O,O,O',O'-Tetramethyl O,O'-(thiodi-4,1-phenylene) phosphorothioate Abaphos Ecopro 1707 difenphos Phosphorothioic acid, O,O-dimethyl ester, O,O-diester with 4,4'-thiodiphenol 硫甲双磷 NIMITEX(R) Experime O,O,O',O'-tetramethyl O,O'-(thiodi-4,1-phenylene) phosphorothioate O,O,O',O'-tetramethyl O,O'-thiodi-p-phenylene phosphorothioate {Chemicalb TETRAFENPHOS phosphorothioic acid, O,O'-(thiodi-p-phenylene) O,O,O',O'-tetramethyl ester O,O,O',O'-TETRAMETHYL-O,O'-(THIODI-P-PHENYLENE)DIPHOSPHOROTHIOA biothion 减少,废除,除去 phosphorothioic acid o,o'-(thiodi-4,1-phenylene) o,o,o',o'-tetramethyl ester Difenthos EI 52160 OMS 7 硫甲双磷;4,4'-双(O,O-二甲基硫代磷酰氧基)苯硫醚 abate ABATHION(R) 4，4′-双(O，O-二甲基硫代磷酸酯)二苯硫醚
CAS Number3383-96-8
PubChem Substance ID5392
EC Number222-191-1
Beilstein Registry Number1896901
MDL NumberMFCD00128034
Chemical Name Translation双硫磷
Merck Number13,9214
Wiswesser Line Notation1OPS&O1&OR DSR DOPS&O1&O1
InChIInChI=1S/C16H20O6P2S3/c1-17-23(25,18-2)21-13-5-9-15(10-6-13)27-16-11-7-14(8-12-16)22-24(26,19-3)20-4/h5-12H,1-4H3
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分类

  • {SNA} All alphabetically sorted, Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards, Insecticides, Organophorous, Pesticides & Metabolites,
  • A, A-B, AA to AL, Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Antibiotics, Antibiotics A to Z, Antibiotics A-F, Chromatography, Environmental Standards, Insecticides, Organophorous, Pesticides, Pesticides & Metabolites
  • {SNA} Analytical Standards, Chromatography, Environmental St

相关文献及参考

  • Short: EINECS
  • Short: IV/8A
  • Merck: 14,9135

安全信息

GHS Symbol
WGK Germany3
Hazard Codes Xn Xn,N
Hazard statements
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H302 Harmful if swallowed 吞食有害
  • H311 Toxic in contact with skin 皮肤接触中毒
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
RTECSTF6890000
Precautionary statements
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
Signal word Danger
Safety Statements
  • S37 Wear suitable gloves 戴适当手套；
  • S22 Do not breathe dust 不要吸入粉尘；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R51/53
UN Number 3077 UN 3077
Storage condition 储存温度 2-8°C 2-8°C 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - quail
DOSE/DURATION           : 75 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AECTCV Archives of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   07

{h

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Bird - chicken
DOSE/DURATION           : >1 gm/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
REFERENCE :
   AEHLAU Archives of Environmental Health.  (Heldref Pub., 4000 Albemarle St.,
   NW, Washington, DC 20016)  V.1-    1960-  Volume(issue)/page/year:
   14,283,1967

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 313 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   VETNAL Veterinariya.  Veterinary Science.  (V/O Mezhdunarodnaya Kniga,
   113095 Moscow, USSR) V.1-    1924-  Volume(issue)/page/year: 60(11),63,1984

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GUCHAZ Guide to the Chemicals Used in Crop Protection.  (Information Canada,
   171 Slater St., Ottawa, Ont., Canada)  Volume(issue)/page/year: 6,493,1973

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPO

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE                    : 2132 mg/kg
SEX/DURATION            : female 6-18 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD-A134-545

其他信息

  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • 类别:农药
  • MOL 文件:3383-96-8.mol
  • 灭火剂:干粉、泡沫、砂土
  • 毒性分级:高毒
  • 职业标准:TLV-TWA 10 毫克/ 立方米
  • 外观性质:纯品为白色结晶，工业品为深褐色粘稠性液体。
  • MSDS 信息:双硫磷(3383-96-8).msds
  • Sigma Aldrich:3383-96-8(sigmaaldrich)
  • 可燃性危险特性:燃烧产生有毒硫氧化物和磷氧化物气体
  • 急性毒性:口服- 大鼠 LD50: 1000 毫克/ 公斤; 口服- 小鼠 LD50: 223 毫克/ 公斤

系列性分类

  1. Life Science 生命科学
  2. Antibiotics 抗生素
  3. Antibiotics A to Z - Antibiotics
  4. Antibiotics A-F - Antibiotics A to Z
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides & Metabolites - Environmental Standards
  6. Pesticides - Pesticides & Metabolites
  7. Insecticides - Pesticides
  8. Organophorous - Insecticides
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides & Metabolites - Environmental Standards
  6. Alpha sort - Pesticides & Metabolites
  7. Q-Z - Alpha sort
  1. Functional Group 官能团索引
  2. thiophosphoric acid ester

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