BUTRALIN

CAS 33629-47-9 MFCD00128046

化学结构图

33629-47-9
SMILES: CCC(C)NC1C(=CC(=CC=1[N+]([O-])=O)C(C)(C)C)[N+]([O-])=O

化学属性

Mol. FormulaC14H21N3O4
Mol. Weight295.38

别名和识别编码

Chemical NameAniline, N-sec-butyl-4-tert-butyl-2,6-dinitro-
Synonym aniline, N-sec-butyl-4-tert-butyl-2,6-dinitro- ZITSAOSOL N-仲丁基-4-叔丁基-2,6-二硝基苯胺 Dibutalin amex820 TAMEX Amex 820 4-(tert-butyl)-N-sec-butyl-2,6-dinitroaniline 地乐胺,双丁乐灵 Rutralin 双丁乐灵 硝苯胺灵 Benzenamine, 4-(1,1-dimethylethyl)-N-(1-methylpropyl)-2,6-dinitro- Aniline, N-sec-butyl-4-tert-butyl-2,6-dinitro- amchema-280 N-sec-Butyl-4-tert-butyl-2,6-dinitroaniline Amchem A-280 仲丁灵/止芽素/地乐胺 a820 Butralin 4-(1,1-dimethylethyl)-n-(1-methylpropyl)-2,6-dinitro-benzenamin 72-A34 4(1,1-dimethylethyl)-N-(1-methylpropyl)-2,6-dinitro-Benzenamine Amex AMEXINE AMEX 820 4-(1,1-Dimethylethyl)-N-(1-methylpropyl)-2,6-dinitrobenzenamine 比达宁 butralin N-仲丁基-4-特丁基-2,6-二硝基苯胺 A 820 Tamex Amchem 70-25 70-314B 地乐胺 止芽素 BUTRALIN dibutalin Butraline 4-(1,1-dimethylethyl)-N-(1-methylpropyl)-2,6-dinitrobenzene-amine 丁烯酯甲酸 amex Butalin 丁乐灵 AMEX benzenamine, 4-(1,1-dimethylethyl)-N-(1-methylpropyl)-2,6-dinitro- 仲丁灵 amchem70-25
MDL NumberMFCD00128046
PubChem Substance ID24862501
Beilstein Registry Number2947948
CAS Number33629-47-9
EC Number251-607-4
Chemical Name Translation
Merck Number13,1531
Wiswesser Line Notation2Y1&MR BNW FNW DX1&1&1
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分类

  • {SNA} A-B, Analytical Standards, Dinitroaniline, 农残和代谢标准品, 分析/色谱, 按照字母排序, 灭草剂
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • A-B, Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, B, BI - BZ, Chromatography, Dinitroaniline, Environmental Standards, Herbicides, Pesticides, Pesticides & Metabolites, Plant growth regulators
  • {SNA} A-B, Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography,

相关文献及参考

  • Merck 14 ,1532
  • Short: IV/8A Title: Enthalpies of Fusion and Transition of Organic Compounds Author: Zhang, Z.-Y.; Frenkel, M.; March, K.N.; Wilhoit, R.C. Editor: Marsh, K.N. Source: Landolt-Börnstein, New Series Volume: IV/8A Year: 1995 Keyword: organic compounds; enthaly of fusion; melting point; phase transition ISBN: 3-540-58854-X ISBN: 978-3-540-58854-2 Internet Resource: DOI:10.1007/b55145 RefComment: VIII, 588 pages.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

RTECSBW9500000
GHS Symbol
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P305+P351+P338
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
Hazard statements
  • H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
Hazard Codes T,N Xn,N
WGK Germany3
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Signal word Warning
Packing GroupII
Hazard Class4.1
Storage condition 0-6°C
UN Number 1325
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
  • R36 Irritating to eyes 刺激眼睛
  • R22 Harmful if swallowed 吞咽有害
  • R50/53
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R24 Toxic in contact with skin 与皮肤接触有毒
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 50 gm/m3/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   SWSPBE Proceedings, Southern Weed Science Society. (Southern Weed Science
   Society, 309 W. Clark St., Champaign, IL 61820) V.22-  1969-
   Volume(issue)/page/year: 24,58,1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 12600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de
   Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France)
   V.1-  1947-  Volume(issue)/page/year: 32,125,1978

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   SWSPBE Proceedings, Southern Weed Science Society. (Southern Weed Science
   Society, 309 W. Clark St., Champaign, IL 61820) V.22-  1969-
   Volume(issue)/page/year: 24,58,1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FMCHA2 Farm Chemicals Handbook.  (Meister Pub., 37841 Euclid Ave.,
   Willoughy, OH 44094)  Volume(issue)/page/year: -,C55,1991

其他信息

  • MOL 文件:33629-47-9.mol
  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • 可燃性危险特性:燃烧产生有毒氮氧化物气体
  • 类别:农药
  • 注意事项:[1]使用地乐胺一般要混土，混土深度3~5cm可以提高药效。在低温季节或用药后浇水，不混土也有较好的效果。 [2茎叶处理防治菟丝子时，喷雾力求细微均匀，使菟丝子缠绕的茎尖均能接受到药剂。 [3]施药时注意安全防护
  • 用途一:属水旱两用化学除草剂
  • 产品特性:选择性苗前二硝基苯胺类除草剂，亦可用作烟草腋芽抑制剂。又名双丁乐灵、地乐胺。对高等动物低毒，对眼睛粘膜有轻度刺激作用，但对皮肤未见刺激作用。
  • 毒性分级:中毒
  • 中毒症状:对皮肤、眼睛及粘膜有轻度刺激作用。
  • 外观性质:略带芳香味的黄橙色晶体。熔点：60～61℃沸点：134～136℃闪点：36℃
  • 下游产品:仲丁灵乳油
  • 急救治疗:目前尚无解毒药，可采取吐根糖浆催吐，12岁以上为30ml，以下减半。呕吐后服活性炭，还可在炭泥中加山梨醇导泻，若病人不清醒，可插管保护呼吸道。
  • Sigma Aldrich:33629-47-9(sigmaaldrich)
  • 灭火剂:干粉、泡沫、砂土
  • 上游原料:盐酸 --> 硫酸 --> 硝酸 --> 三氯化铁 --> 六水三氯化铁
  • 用途二:播前用除草剂，也可用于烟草腋芽的抑制。
  • 急性毒性:口服- 大鼠 LD50: 2500 毫克/公斤; 吸入-大鼠 LC50: 50000 毫克/立方米/4小时
  • 用途:丁乐灵适用于大豆、花生、豌豆、甘蔗、棉花、玉米、马铃薯、旱稻、茴香、胡萝卜、芹菜等多种作物播前或播后苗前作土壤处理；番茄、青椒、茄子在移栽前作土壤处理防除稗草、马唐、狗尾草、牛盘草、苋、马齿苋、藜、龙葵、地肤等一年生禾本科杂草及部分双子叶杂草，也可苗后用其48%的乳油150~200倍液，针对性茎叶处理防治大豆菟丝子，用作烟草抑制腑芽，在烟株摘顶后，每株喷2%药液20~25毫升。架豆、豇豆、根荐小葱、韭菜、黄瓜等作物苗后、杂草出土前进行土壤处理，一般每公顷用48%地乐胺乳油3000~3750毫升，加水450升喷雾处理。

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides & Metabolites - Environmental Standards
  6. Pesticides - Pesticides & Metabolites
  7. Plant growth regulators - Pesticides

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