N-(2-Pyridinylmethyl)-2-pyridinemethanamine N-(2-吡啶基甲基)-2-吡啶甲胺

CAS 1539-42-0 MFCD00129044

化学结构图

1539-42-0
SMILES: c1ccc(CNCc2ccccn2)nc1

化学属性

Mol. FormulaC12H13N3
Mol. Weight199.257
Density1.107
Boiling Point322°C at 760 mmHg
Refractive index1.5740 to 1.5780
Flash Point194 °F
Appearance 浅黄色液体。沸点：197℃(760mmHg)，82～85℃(12mmHg)，密度 (20/4°C):1.0490，闪点：90℃，折光率N D 20 :1.542～1.546，与水以任意比例混溶,易溶于甲醇、乙醇、氯仿等有机溶剂。
Melting Point20°C
SolubilityPartly Miscible with wter.

别名和识别编码

Chemical NameN-(2-Pyridinylmethyl)-2-pyridinemethanamine
MDL NumberMFCD00129044
CAS Number1539-42-0
EC Number216-266-8
Beilstein Registry Number476398
Synonym N-(2-Pyridinylmethyl)-2-pyridinemethanamine {LY} N-(2-Pyridinylmethyl)-2-pyridinemethanamine dipicolylamine {} {LY} N-(2-Pyridinylmethyl)-2-pyridinemethanamine {} {} {LY} N-(2-Pyridinylmethyl)-2-pyridinemethanamine {} {} {} {LY} N-(2-Pyridinylmethyl)-2-pyridinemethanamine {} {} {} {} {LY} N-(2-Pyridinylmethyl)-2-pyridinemethanamine {} {} {} {} {} {LY} N-(2-Pyridinylmethyl)-2-pyridinemethanamine {} {} {} {} {} {} {LY} N-(2-Pyridinylmethyl)-2-pyridinemethanamine {} {} {} {} {} {} {} {LY} N-(2-Pyridinylmethyl)-2-pyridinemethanamine {} {} {} {} {} {} {} {} {LY} N-(2-Pyridinylmethyl)-2-pyridinemethanamine {} {} {} {} {} {} {} {} {} {LY} N-(2-Pyridinylmethyl)-2-pyridinemethanamine {} {} {} {} {} {} {} {} {} {} {LY} N-(2-Pyridinylmethyl)-2-pyridinemethanamine {} {} {} {} {} {} {} {} {} {} {} {LY} N-(2-Pyridinylmethyl)-2-pyridinemethanamine {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-(2-Pyridinylmethyl)-2-pyridinemethanamine {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID73759
Reaxys-RN476398
Chemical Name TranslationN-(2-吡啶基甲基)-2-吡啶甲胺
InChIKeyKXZQYLBVMZGIKC-UHFFFAOYSA-N
LabNetwork Molecule IDLN00191286
InChIInChI=1S/C12H13N3/c1-3-7-14-11(5-1)9-13-10-12-6-2-4-8-15-12/h1-8,13H,9-10H2
Canonical SMILESC1(CNCC2=NC=CC=C2)=NC=CC=C1
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分类

  • {SNA} Building Blocks, C12, Chemical Synthesis, Heterocyclic Building Blocks, Pyridines

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P316
  • P302+P350
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P316
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P361+P364
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H310 Fatal in contact with skin 皮肤接触致命
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes C Xi
Packing GroupIII
Hazard Class8
UN Number UN 2735 8/PG 2
RTECSUS1840000
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitro

其他信息

  • TCI Shanghai:2-氨甲基吡啶 2-Picolylamine,>;98.0%(GC)(3731-51-9)
  • 储运特性:库房通风低温干燥
  • 海关编码:29333999
  • 图谱信息:2-氨甲基吡啶(3731-51-9)核磁图( 13 CNMR) 2-氨甲基吡啶(3731-51-9)核磁图( 1 HNMR) 2-氨甲基吡啶(3731-51-9)红外图谱(IR1) 2-氨甲基吡啶(3731-51-9)质谱(MS)
  • MOL 文件:3731-51-9.mol
  • Acros Organics:2-(氨甲基)吡啶 2-(Aminomethyl)pyridine, 99%(3731-51-9)
  • 上游原料:乙酸 --> 氢氧化铵 --> 碳酸氢钠 --> 镍 --> 4-氰基吡啶 --> 2-氰基吡啶
  • 毒性分级:中毒
  • 下游产品:氟卡尼
  • 用途一:有机合成、药物合成
  • 类别:有毒物品
  • Sigma Aldrich:3731-51-9(sigmaaldrich)
  • Hazard Note:Corrosive
  • 灭火剂:干粉、泡沫、砂土、二氧化碳, 雾状水
  • MSDS 信息:2-Picolylamine(3731-51-9).msds
  • 急性毒性:静脉-小鼠LD50: 340 毫克/公斤; 口服-野鸟LD50: 562 毫克/公斤
  • Alfa Aesar:2-(氨甲基)吡啶,99% 2-(Aminomethyl)pyridine, 99%(3731-51-9)
  • 可燃性危险特性:可燃;燃烧产生有毒氮氧化物烟雾
  • 2-氨甲基吡啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A1161 2-氨甲基吡啶 2-Picolylamine 25G 349元 2014/06/02 A1161 2-氨甲基吡啶 2-Picolylamine 250G 1990元 2010/06/21 104070250 2-氨甲基吡啶 2-(Aminomethyl)pyridine 99% 25 ML 649元

系列性分类

  1. C12 - Pyridines
  1. C6 to C7 - Pyridines

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