Indium 铟

CAS 7440-74-6 MFCD00134048

化学结构图

7440-74-6
SMILES: [In]

化学属性

Mol. FormulaIn
Mol. Weight114.82
Density7.3 g/mL at 25 °C(lit.)
Melting Point156.6 °C
Vapor Pressure<;0.01 mmHg ( 25 °C)
TSCAYes
Boiling Point2000 °C at 760 mmHg
Flash Point2072°C
Solubilityinsoluble
Appearance wire

别名和识别编码

Chemical NameIndium
CAS Number7440-74-6
EC Number231-180-0
MDL NumberMFCD00134048
PubChem Substance ID5359967
Synonym Indium {LY} Indium {} {LY} Indium {} {} {LY} Indium {} {} {} {LY} Indium {} {} {} {} {LY} Indium {} {} {} {} {} {LY} Indium {} {} {} {} {} {} {LY} Indium {} {} {} {} {} {} {} {LY} Indium {} {} {} {} {} {} {} {} {LY} Indium {} {} {} {} {} {} {} {} {} {LY} Indium {} {} {} {} {} {} {} {} {} {} {LY} Indium {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Indium {} {} {} {} {} {} {} {} {} {} {} {} {LY} Indium {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Indium {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Indium {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Indium {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Indium {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Indium {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Indium
Merck Number14,4947
Chemical Name Translation
Wiswesser Line NotationIN
LabNetwork Molecule IDLN03290140
InChIInChI=1S/In
Canonical SMILES[In]
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {SNA} High-Purity Metal Foils, In, Indium, Materials Science, Metal and Ceramic Science, Metals, Micro/NanoElectronics, Physical Vapor Deposition (PVD), Ultra-High Purity Materials, Vapor Deposition Precursors
  • {SNA} High-Purity Metal Foils,
  • {SNA} Indium
  • {SNA} Indium, Metal and Ceramic Science, Metals,

产品应用

  • 主要用作包覆层(或制成合金)以增强金属材料的耐腐蚀性,并广泛用作电子器件。合金涂层作反射器。铟合金用作反应堆控制棒等。磷化铟锑化铟等都是半导体材料。

相关文献及参考

  • Allyl iodides or bromides form allylindium reagents which undergo Reformatsky or Barbier type reactions with aldehydes under mild conditions to give homoallylic alcohols. Due to their low basicity, these reagents can be effective even in the presence of labile hydrogens without protection: J. Org. Chem., 53, 1831 (1988). Hence, allylation reactions can also be carried out successfully in water: Tetrahedron Lett., 32, 7017 (1991); J. Chem. Soc., Chem. Commun., 747 (1992); Org. Synth., 77, 107 (1999). Indium is the most effective metal for promoting Barbier-type allylations in water. For review of aqueous Barbier-Grignard type reactions. see: Tetrahedron, 52, 5643 (1996), and of water-promoted reactions, including Barbier, see: Synthesis, 741 (1994).
  • Bromoacetonitrile readily forms an organoindium reagent which adds to carbonyl groups to give ß-hydroxy nitriles: Bull. Chem. Soc. Jpn., 67, 1126 (1994). Reaction of electron-deficient alkenes with active methylene dibromides in the presence of indium leads to cyclopropyl compounds; aldehydes similarly give epoxides: J. Chem. Soc., Chem. Commun., 1286 (1989). ɑ-Chlorocarbonyl compounds give allylic epoxides: J. Chem. Soc., Perkin 1, 946 (2001).
  • For reviews of the use of indium in organic synthesis, see: Synlett, 1087 (1995); 1331 (1999); Eur. J. Org. Chem., 2347 (2000); J. Ch
  • Has also been found to be an versatile, selective reducing agent, e.g. for azides to amines: Tetrahedon Lett., 40, 3937 (1999), imines to amines, quinolines and isoquinolines to the tetrahydro derivatives, indoles to indolines, oximes and nitro compounds to amines: J. Chem. Soc., Perkin 1, 955 (2001).
  • Merck: 14,4947

安全信息

GHS Symbol
WGK Germany3
Hazard Codes Xn F,Xn C,Xn,F,Xi
Hazard statements
  • H228 Flammable solid 易燃固体
  • H302 Harmful if swallowed 吞食有害
  • H302+H312+H332
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges dust mask type N95 (US), Eyeshields, Gloves
RTECSNL1050000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P302+P352
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger Warning
Safety Statements
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
Packing GroupIII
UN Number UN 3089 4.1/PG 2 UN3089 UN3264
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R11 Highly flammable 非常易燃
  • R34 Causes burns 会导致灼伤
  • R26 Very toxic by inhalation 吸入极毒
  • R25 Toxic if swallowed 吞咽有毒
  • R20 Harmful by inhalation 吸入有害
Hazard Class8
Storage condition Store at room temperature, keep dry and cool {LY} Store at room temperature, keep dry and cool {} {LY} Store at room temperature, keep dry and cool {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} { {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry an
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 10 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   28ZLA8 "Toxicity of Industrial Metals," Browning, E., London, Butterworths,
   1961  Volume(issue)/page/year: -,144,1961

其他信息

  • 急性毒性:皮下-小鼠 LDL0: 10 毫克/公斤
  • 储运特性:库房通风低温干燥; 与食品添加剂分开存放
  • Alfa Aesar:铟柱,6.35mm(0.25in)diax6.35mm(0.25in)length,99.998%(metalsbasis) Indium slug, 6.35mm (0.25in) dia x 6.35mm (0.25in) length, 99.998% (metals basis)(7440-74-6)
  • 用途五:制取ITO粉、液晶显示屏等的原料。高纯级主要用于制备III-V族化合物半导体,高纯合金、金属管基极以及锗、硅单晶的掺杂剂。用于ICP-AES、AAS、AFS、ICP-MS、离子色谱等。滴定分析用标准溶液。校准仪器和装置;评价方法;工作标准;质量保证/质量控制;其他。
  • 用途三:主要用于制轴承及提炼高纯铟,也用于电子和电镀工业
  • 类别:有毒物品
  • 毒性分级:剧毒
  • 蒸气压:<;0.01 mm Hg ( 25 °C)
  • Sigma Aldrich:7440-74-6(sigmaaldrich)
  • 用途二:用于低熔点合金和铟盐的制造
  • 下游产品:磷化铟
  • 参考质量标准:国家标准GB 8003—87 牌号 化学成分 In含量/%≥ 杂质含量/10 -6 ,≤ Fe Cu Pb Zn Sn Cd Tl Mg Al As Si S Ag Ni In-05 99.999 0.5 0.4 1.0 0.5 1.5 0.5 1.0 0.5 0.5 0.5 1.0 1.0 0.5 0.5 In-06 99.9999 0.1 0.1 0.1 - 0.3 0.05 - 0.1 - - 0.1 0.1 - -
  • 职业标准:TWA 0.1 (铟)毫克/立方米; STEL 0.3 毫克(铟)/立方米
  • 外观性质:银色柔软金属, 比铅软。
  • MSDS 信息:铟(7440-74-6).msds
  • 铟价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 51011360 铟粒 10g 170元 2011/08/23 51011480 铟丝 1.6mm 5g 607.2元 2010/06/21 318110092 铟 Indium 99.99%, foil, 0.127 mm thick 9.2 GR 3328元
  • 标准值 不确定度 单位
  • 方法一:工业生产是从铅、锌、锑、锡等生产中的各种废料和中间产物,经氧化富集、萃取、置换和电解等工艺过程制得。
  • 溶于酸,不溶于沸水及碱性溶液中,在湿空气中能形成氢氧化物薄膜。
  • MOL 文件:7440-74-6.mol
  • 用途六:主要用作包覆层(或制成合金)以增强金属材料的耐腐蚀性,并广泛用作电子器件。合金涂层作反射器。铟合金用作反应堆控制棒等。磷化铟锑化铟等都是半导体材料。
  • 可燃性危险特性:铟粉末在明火, 高热情况下易燃; 燃烧产生有毒铟氧化物烟雾
  • 灭火剂:干粉、泡沫、砂土、二氧化碳, 雾状水
  • 用途四:用于化合物半导体,高纯合金及半导体材料的掺杂剂等。
  • 用途一:主要用于制轴承及提炼高纯铟,也用于电子工业和电镀工业
  • Acros Organics:铟 Indium, foil, 0.127 mm thick, 99.99%(7440-74-6)

系列性分类


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