3-Bromo-2-methylpropene 3-溴-2-甲基丙烯

CAS 1458-98-6 MFCD00134155

化学结构图

1458-98-6
SMILES: C=C(C)CBr

化学属性

Mol. FormulaC4H7Br
Mol. Weight135.00
Boiling Point94-95
Refractive index1.4680 to 1.4720
Density1.339
Flash Point7°C(lit.)
Appearance 无色或淡黄色透明液体,密度 1.339,沸点 94-95℃,折射率 1.472,闪点 44 oF

别名和识别编码

Chemical Name3-Bromo-2-methylpropene
CAS Number1458-98-6
Alfabeta NameBROMOMETHYLPROPENE 32---
MDL NumberMFCD00134155
Synonym Bulk Pharmaceuticals and Intermediates 2-Methyl-2-propenylbromide β-Methylallyl bromide 甲基烯丙基溴 3-Bromo-2-methyl-1-propene METHALLYL BROMIDE 2-Methyl-3-bromo-1-propene 2-methylallylbromide 1-propene, 3-bromo-2-methyl- 2-(bromomethyl)propene 3-Bromo-2-methylpropene 2-Methyl-2-propenyl bromide 3-溴-2-甲基丙烯 3-BROMO-2-METHYLPROP-1-ENE METHYLALLYL BROMIDE β-Methallyl bromide 甲基烯丙基溴 甲基烯丙溴 1-Bromo-2-methyl-2-propene 甲基烯丙溴 3-Bromo-2-methyl-1-propylene 2-methylallyl bromide Methallyl bromide; Methylallyl bromide 3-BROMO-2-METHYLPROPENE 3-bromo-2-methyl-propene propene,3-bromo-2-methyl-
PubChem Substance ID357785
EC Number250-023-7
Beilstein Registry Number1697908
Chemical Name Translation3-溴-2-甲基丙烯
Reaxys-RN1697908
LabNetwork Molecule IDLN00009263
InChIInChI=1S/C4H7Br/c1-4(2)3-5/h1,3H2,2H3
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分类

  • {uni_hamburg} no charge; 1fragment
  • {SNA} Alkenyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks

产品应用

  • 用在研究手性相转移烷基化反应中,生成(S)-α-烷基化半胱氨酸。

相关文献及参考

  • Short: II/25C
  • Short: IV/20A
  • Short: IV/8J
  • Beilstein: 1,II,182

安全信息

Warnings LACHRYMATOR, FLAMMABLE
GHS Symbol
WGK Germany3
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H302+H332
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H332 Harmful if inhaled 吸入有害
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P310
  • P308+P313
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Hazard Codes F,C,N
Safety Statements
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S29 Do not empty into drains 不要排入下水道;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Risk Statements
UN Number
Storage condition 0-10 储存温度2-8 °C 0-10°C
Packing GroupII
Hazard Class3/8

其他信息

  • MOL 文件:1458-98-6.mol
  • 用途一:用在研究手性相转移烷基化反应中,生成(S)-α-烷基化半胱氨酸。

系列性分类


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