Phenylethynylmagnesium bromide 溴化苯基乙炔基镁
CAS 6738-06-3 MFCD00134164
化学结构图
SMILES: Br[Mg]C#Cc1ccccc1
化学属性
| Mol. Formula | C8H5MgBr |
|---|---|
| Mol. Weight | 205.33 |
| Density | 1.018 g/mL at 25 °C |
别名和识别编码
| Chemical Name | Phenylethynylmagnesium bromide |
|---|---|
| MDL Number | MFCD00134164 |
| CAS Number | 6738-06-3 |
| PubChem Substance ID | 5116188 |
| Chemical Name Translation | 溴化苯基乙炔基镁 |
| Synonym | 溴化苯基乙炔基镁 溶液 |
| LabNetwork Molecule ID | LN02151294 |
| InChI | InChI=1S/C8H5.BrH.Mg/c1-2-8-6-4-3-5-7-8;;/h3-7H;1H;/q-1;;+2/p-1 |
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分类
- {SNA} Alkynyl, Chemical Synthesis, Grignard Reagents, Organometallic Reagents
安全信息
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P222 Do not allow contact with air. 不要与空气接触。
- P231 Handle under inert gas. 在惰性气体中操作。
- P231+P232
- P233 Keep container tightly closed. ?保持容器密闭。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331
- P302+P335+P334
- P302+P361+P354
- P304+P340
- P305+P351+P338
- P305+P354+P338
- P316
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P370+P378
- P402+P404
- P405 Store locked up. 上锁保管。
- P422 Store contents under… 存储目录在…之下。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
- H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H351 Suspected of causing cancer 怀疑致癌
GHS Symbol
- R11 Highly flammable 非常易燃
- R14 Reacts violently with water 遇水会猛烈反应
- R17 Spontaneously flammable in air 在空气中能够自燃
- R19 May form explosive peroxides 可能生成易爆的过氧化物质
- R37 Irritating to respiratory system 刺激呼吸道
- R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
- R34 Causes burns 会导致灼伤
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