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Phenylethynylmagnesium Bromide 苯基乙炔基溴化镁
CAS 6738-06-3 MFCD00134164
化学结构图
SMILES: Br[Mg]C#Cc1ccccc1
化学属性
Mol. Formula
C8H5MgBr
Mol. Weight
205.33
Density
1.018 g/mL at 25 °C
别名和识别编码
Chemical Name
Phenylethynylmagnesium Bromide
MDL Number
MFCD00134164
CAS Number
6738-06-3
PubChem Substance ID
5116188
Chemical Name Translation
苯基乙炔基溴化镁
Synonym
溴化苯基乙炔基镁 溶液
LabNetwork Molecule ID
LN02151294
InChI
InChI=1S/C8H5.BrH.Mg/c1-2-8-6-4-3-5-7-8;;/h3-7H;1H;/q-1;;+2/p-1
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分类
{SNA} Alkynyl, Chemical Synthesis, Grignard Reagents, Organometallic Reagents
安全信息
WGK Germany3
Precautionary statements
P210
Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P222
Do not allow contact with air. 不要与空气接触。
P231
Handle under inert gas. 在惰性气体中操作。
P231+P232
P233
Keep container tightly closed. ?保持容器密闭。
P260
Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261
Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264
Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P280
Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P330+P331
P302+P335+P334
P302+P361+P354
P304+P340
P305+P351+P338
P305+P354+P338
P316
P321
Specific treatment (see … on this label). 具体治疗(见本标签上的)。
P363
Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P370+P378
P402+P404
P405
Store locked up. 上锁保管。
P422
Store contents under… 存储目录在…之下。
P501
Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
S26
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
S36/37/39
Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
S45
In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
S16
Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
Hazard statements
H225
Highly flammable liquid and vapour 高度易燃液体和蒸气
H250
Catches fire spontaneously if exposed to air 暴露于空气自发着火
H261
In contact with water releases flammable gas 与水接触时释放可燃气体。
H314
Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H335
May cause respiratory irritation 可能导致呼吸道刺激
H351
Suspected of causing cancer 怀疑致癌
GHS Symbol
Hazard Codes F,C
Risk Statements
R11
Highly flammable 非常易燃
R14
Reacts violently with water 遇水会猛烈反应
R17
Spontaneously flammable in air 在空气中能够自燃
R19
May form explosive peroxides 可能生成易爆的过氧化物质
R37
Irritating to respiratory system 刺激呼吸道
R40
Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
R34
Causes burns 会导致灼伤
系列性分类
Chemical Synthesis 化学合成
Organometallic Reagents 金属有机试剂
Grignard Reagents 格氏试剂
Chemical Synthesis 化学合成
Organometallic Reagents 金属有机试剂
Grignard Reagents 格氏试剂
Alkynyl - Grignard Reagents
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