3-[Bis(Trimethylsilyl)Amino]Phenylmagnesium Chloride 3-[双(三甲基甲硅烷基)氨基]苯基氯化镁

CAS 174484-84-5 MFCD00134370

化学结构图

174484-84-5
SMILES: C[Si](C)(C)N(C1=CC(=CC=C1)[Mg]Cl)[Si](C)(C)C

化学属性

Mol. Formula[(CH3)3Si]2NC6H4MgCl
Mol. Weight296.24
Density0.954 g/mL at 25 °C
Boiling Point67 °C

别名和识别编码

Chemical Name3-[Bis(Trimethylsilyl)Amino]Phenylmagnesium Chloride
MDL NumberMFCD00134370
Beilstein Registry Number7706704
PubChem Substance ID24863141
Synonym 3-[双(三甲基甲硅烷基)氨基]苯基氯化镁 溶液
Chemical Name Translation3-[双(三甲基甲硅烷基)氨基]苯基氯化镁
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分类

  • {SNA} Aryl, Chemical Synthesis, Grignard Reagents, Organometallic Reagents

安全信息

WGK Germany3
GHS Symbol
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H351 Suspected of causing cancer 怀疑致癌
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P370+P378
  • P403+P235
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
Hazard Codes F,C
Risk Statements
  • R11 Highly flammable 非常易燃
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R37 Irritating to respiratory system 刺激呼吸道
  • R14 Reacts violently with water 遇水会猛烈反应
  • R34 Causes burns 会导致灼伤
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  4. Aryl - Grignard Reagents
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  4. Aryl - Grignard Reagents
  1. Functional Group 官能团索引
  2. organomagnesium compound

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