Triethyl 2-Fluoro-2-Phosphonoacetate 2-氟-2-磷酰基乙酸三乙酯

CAS 2356-16-3 MFCD00134400

化学结构图

2356-16-3
SMILES: CCOC(=O)C(F)P(=O)(OCC)OCC

化学属性

Mol. FormulaC8H16FO5P
Mol. Weight242.18
Boiling Point339.5°C at 760 mmHg
Density1.194
Refractive index1.4240 to 1.4270
Flash Point73°C(lit.)
TSCANo

别名和识别编码

Chemical NameTriethyl 2-Fluoro-2-Phosphonoacetate
CAS Number2356-16-3
Alfabeta NameFLUOROPHOSPHONOACETICACIDTRIETHYLESTER 22---
MDL NumberMFCD00134400
Synonym Triethyl 2-fluoro-2-phosphonoacetate {LY} Triethyl 2-fluoro-2-phosphonoacetate {} {LY} Triethyl 2-fluoro-2-phosphonoacetate {} {} {LY} Triethyl 2-fluoro-2-phosphonoacetate {} {} {} {LY} Triethyl 2-fluoro-2-phosphonoacetate {} {} {} {} {LY} Triethyl 2-fluoro-2-phosphonoacetate {} {} {} {} {} {LY} Triethyl 2-fluoro-2-phosphonoacetate {} {} {} {} {} {} {LY} Triethyl 2-fluoro-2-phosphonoacetate {} {} {} {} {} {} {} {LY} Triethyl 2-fluoro-2-phosphonoacetate {} {} {} {} {} {} {} {} {LY} Triethyl 2-fluoro-2-phosphonoacetate {} {} {} {} {} {} {} {} {} {LY} Triethyl 2-fluoro-2-phosphonoacetate {} {} {} {} {} {} {} {} {} {} {LY} Triethyl 2-fluoro-2-phosphonoacetate {} {} {} {} {} {} {} {} {} {} {} {LY} Triethyl 2-fluoro-2-phosphonoacetate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triethyl 2-fluoro-2-phosphonoacetate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triethyl 2-fluoro-2-phosphonoacetate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
EC Number250-023-7
Beilstein Registry Number1912161
PubChem Substance ID2734865
Reaxys-RN1912161
Chemical Name Translation2-氟-2-磷酰基乙酸三乙酯
InChIKeyFVPISMANESAJQZ-UHFFFAOYSA-N
LabNetwork Molecule IDLN00116917
InChIInChI=1S/C8H16FO5P/c1-4-12-8(10)7(9)15(11,13-5-2)14-6-3/h7H,4-6H2,1-3H3
Canonical SMILESO=C(OCC)C(F)P(OCC)(OCC)=O
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分类

  • {SNA} C-C Bond Formation, Chemical Synthesis, Horner-Wadsworth-Emmons Reagents, Olefination, Synthetic Reagents
  • {uni_hamburg} no charge; ester; racemate; 1fragment

相关文献及参考

  • Short: III/35A Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Boron-11 and Phosphorus-31 Author: Gupta, R.R.; Jain, M.; Pardasani, P.; Pardasani, R.T.; Pelter, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35A Year: 1997 ISBN: 3-540-60366-2 ISBN: 978-3-540-60366-5 Internet Resource: DOI:10.1007/b53033 RefComment: VIII, 242 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CO-ROM's.
  • Short: III/35B Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Fluorine-19 and Nitrogen-15 Author: Balasubramanian, M.; Gupta, R.R.; Jain, M.; Perumal, S. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35B Year: 1998 ISBN: 3-540-63275-1 ISBN: 978-3-540-63275-7 Internet Resource: DOI:10.1007/b55685 RefComment: VII, 242 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical s

安全信息

Warnings IRRITANT, FLAMMABLE
Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes Xi Xi,F
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitro

其他信息

  • 2-氟-2-磷酰基乙酸三乙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 F0340 2-氟-2-磷酰基乙酸三乙酯 Triethyl 2-Fluoro-2-phosphonoacetate 5G 420元 2014/06/02 F0340 2-氟-2-磷酰基乙酸三乙酯 Triethyl 2-Fluoro-2-phosphonoacetate 1G 120元 2010/06/21 375560050 2-氟-2-磷酰基乙酸三乙酯 Triethyl 2-fluoro-2-phosphonoacetate 96% 5 GR 1609元
  • F:10-21
  • TCI Shanghai:2-氟-2-磷酰基乙酸三乙酯 Triethyl 2-Fluoro-2-phosphonoacetate,>;95.0%(GC)(2356-16-3)
  • Sigma Aldrich:2356-16-3(sigmaaldrich)
  • Hazard Note:Irritant
  • Acros Organics:Triethyl 2-fluoro-2-phosphonoacetate, 96%(2356-16-3)
  • MOL 文件:2356-16-3.mol
  • Alfa Aesar:2-氟代膦-2-酰乙酸三乙脂,96% Triethyl 2-fluoro-2-phosphonoacetate, 96%(2356-16-3)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Phosphonates/Phosphinates - Phosphorus Compounds
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Horner-Wadsworth-Emmons Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Horner-Wadsworth-Emmons Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Wittig & Horner-Emmons Reaction
  1. Functional Group 官能团索引
  2. phosphonic acid derivative
  1. Functional Group 官能团索引
  2. phosphonic acid ester

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