[RuCl(p-cymene)((S)-binap)]Cl 氯代[(S)-(-)-2,2-二(二苯基膦)-1,1-联萘](P-伞花素)氯化钌(II)

CAS 130004-33-0 MFCD00134456

化学结构图

130004-33-0
SMILES:

化学属性

Mol. Formula[C54H46ClP2Ru]+Cl-
Mol. Weight928.87
Appearance orange pwdr.
Stabilityair sensitive
Melting Point>100 °C

别名和识别编码

Chemical Name[RuCl(p-cymene)((S)-binap)]Cl
Synonym (S)-RuCl[(p-cymene(BINAP)]Cl {LY} (S)-RuCl[(p-cymene(BINAP)]Cl {} {LY} (S)-RuCl[(p-cymene(BINAP)]Cl {} {} {LY} (S)-RuCl[(p-cymene(BINAP)]Cl {} {} {} {LY} (S)-RuCl[(p-cymene(BINAP)]Cl {} {} {} {} {LY} (S)-RuCl[(p-cymene(BINAP)]Cl {} {} {} {} {} {LY} (S)-RuCl[(p-cymene(BINAP)]Cl {} {} {} {} {} {} {LY} (S)-RuCl[(p-cymene(BINAP)]Cl {} {} {} {} {} {} {} {LY} (S)-RuCl[(p-cymene(BINAP)]Cl {} {} {} {} {} {} {} {} {LY} (S)-RuCl[(p-cymene(BINAP)]Cl {} {} {} {} {} {} {} {} {} {LY} (S)-RuCl[(p-cymene(BINAP)]Cl {} {} {} {} {} {} {} {} {} {} {LY} (S)-RuCl[(p-cymene(BINAP)]Cl {} {} {} {} {} {} {} {} {} {} {} {LY} (S)-RuCl[(p-cymene(BINAP)]Cl {} {} {} {} {} {} {} {} {} {} {} {} {LY} (S)-RuCl[(p-cymene(BINAP)]Cl {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (S)-RuCl[(p-cymene(BINAP)]Cl {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (S)-RuCl[(p-cymene(BINAP)]Cl {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (S)-RuCl[(p-cymene(BINAP)]Cl {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00134456
CAS Number145926-28-9
Chemical Name Translation氯代[(S)-(-)-2,2-二(二苯基膦)-1,1-联萘](P-伞花素)氯化钌(II)
PubChem Substance ID253662307
Canonical SMILESCl[Ru+]1[P](C2=CC=CC=C2)(C3=CC=CC=C3)C(C=C4)=[C@]([C@]5=C(C=CC=C6)C6=CC=C5[P](C7=CC=CC=C7)1C8=CC=CC=C8)C9=C4C=CC=C9.C[C@H]%10CC[C@@H](C(C)C)CC%10.[Cl-]
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分类

  • {SNA} Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
  • Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes

相关文献及参考

安全信息

WGK Germany3
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
GHS Symbol
Precautionary statements
  • P308+P311
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P405 Store locked up. 上锁保管。
  • P308+P313
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H340 May cause genetic defects 可能导致遗传性缺陷
Hazard Codes Xi
Signal word
Safety Statements
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. BINAPs - Privileged Ligands and Complexes
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes
  1. Functional Group 官能团索引
  2. phosphine
  1. BINAP
  2. Ruthenium
  1. BINAP
  2. 96-6951 Takasago BINAP Ru Cymene Catalyst Kit
  1. Catalysts
  2. 96-6951 Takasago BINAP Ru Cymene Catalyst Kit
  1. Catalysts
  2. Ruthenium
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. 医药合成催化剂

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