(+)-Chloroformyloxy-p-Menthane (+)-氯甲酸薄荷酯
CAS 7635-54-3 MFCD00134483
化学结构图
SMILES: CC(C)[C@H]1CC[C@H](C)C[C@@H]1OC(=O)Cl
化学属性
| Mol. Formula | C11H19ClO2 |
|---|---|
| Mol. Weight | 218.72 g/mol |
| Refractive index | 1.4580 to 1.4600 |
| Boiling Point | 108-109 °C/11 mmHg(lit.) |
| Density | 1.031 g/mL at 25 °C(lit.) |
| Flash Point | 70°C(lit.) |
| Stability | 对湿度敏感 |
别名和识别编码
| Chemical Name | (+)-Chloroformyloxy-p-Menthane |
|---|---|
| CAS Number | 7635-54-3 |
| PubChem Substance ID | 87573180 |
| Beilstein Registry Number | 2414685 |
| MDL Number | MFCD00134483 |
| Reaxys-RN | 2414685 |
| Synonym | (+)-(1S)-MENTHYL CHLOROFORMATE (+)-CHLOROFORMYLOXY-P-MENTHANE (+)-MENTHYL CHLOROFORMATE (+)-MENTHYL CHLOROFORMATE (97% EE/GLC) (+)-MENTHYL CHLOROFORMATE 97% (+)-Menthyl Chloroformate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { |
| Chemical Name Translation | (+)-氯甲酸薄荷酯 |
| LabNetwork Molecule ID | LN01743139 |
| InChI | InChI=1S/C11H19ClO2/c1-7(2)9-5-4-8(3)6-10(9)14-11(12)13/h7-10H,4-6H2,1-3H3/t8-,9+,10-/m0/s1 |
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分类
- {SNA} Acid Halides, Analytical Reagents, Analytical/Chromatography, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Resolution Reagents, Chiral Resolving Reagents, Derivatization Reagents, Derivatization Reagents HPLC, Organic Building Blocks, UV-VIS
- {SNA} Acid Halides, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Resolution Reagents, Chiral Resolving Reagents, Derivatization Reagents, Derivatization Reagents HPLC, Organic Building Blocks, UV-VIS, 分析/色谱, 分析试剂
- Acid Halides, Analytical Rea
相关文献及参考
- 1. Tetrahedron Lett. 26 , 5433, (1985)
- FT-NMR 1 (1), 1207:A / RegBook 1 (1), 863:E / Structure Index 1 , 132:B:8
安全信息
GHS Symbol
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H331 Toxic if inhaled 吸入中毒
- H227 Combustible liquid 可燃液体
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P304+P340+P310
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P303+
- P234 Keep only in original container. 只保留在原来的容器中。
- P403+P233
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P301+P330+P331+P310
- P303+P361+P353
- P284 Wear respiratory protection.? 佩戴呼吸保护装置。
- P370+P378
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P305+P351+P338
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
- P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
- R34 Causes burns 会导致灼伤
- R23 Toxic by inhalation 吸入有毒
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S25 Avoid contact with eyes 避免眼睛接触；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
其他信息
- MOL 文件:7635-54-3.mol
- TCI Shanghai:(+)-氯甲酸薄荷酯 (+)-Menthyl Chloroformate,>;97.0%(T)(7635-54-3)
- Sigma Aldrich:7635-54-3(sigmaaldrich)
- 氯甲酸薄荷酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M1221 氯甲酸(+)-薄荷酯 (+)-Menthyl Chloroformate 5ML 615元 2014/06/02 M1221 氯甲酸(+)-薄荷酯 (+)-Menthyl Chloroformate 25ML 1950元 2010/06/21 314510250 氯甲酸薄荷酯 (+)-Menthyl chloroformate 97% 25 ML 2106元
- F:10-19-21
- 下游产品:异丙威 --> 禾草敌 --> 头孢替安 --> 碳酸丙烯酯 --> 仲丁威 --> 灭除威 --> 1-乙氧羰基吡咯烷-3-酮
- Acros Organics:氯甲酸薄荷酯 (+)-Menthyl chloroformate, 97%(7635-54-3)
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